Synthetic polymers are one of the most significant pollutants in the aquatic environment, because of abilities such as buoyancy and extreme persistency. Serious effects are expected from so-called microplastics (particle size <5 mm) that are reported in rivers, lakes as well as the ocean and that accumulate in sediments worldwide. In this thesis the abundance of microplastics in river shore sediments in the Rhine-Main area of Germany was studied. Therefore, a new method was developed that is based on a sodium chloride density separation with subsequent destruction of natural debris, and identification of the plastic particles by microscopy or Fourier transform infrared spectroscopy (FTIR). Using the improved density separation, microplastics were separated from river shore sediments of 12 sites originating from the river Rhine, the river Main, and the stream Schwarzbach. Large amounts of microplastic particles of up to 1 g kg-1 or up to 4000 particles kg-1 were detected in the shore sediments. The identification by FTIR showed that polyethylene, polypropylene, and polystyrene were the most abundant polymer types in the sediments, covering over 75% of all plastics identified. Transport of microplastics from tributaries to main streams was indicated by the detection of identical pellets in the River Rhine and in the Main mouth. Comparable concentrations detected by sampling one site over a period of two years suggest a constant pollution of the river shore sediments with microplastics. For deeper insights into the sorption process of organic contaminants to synthetic polymers in freshwater systems, batch experiments in synthetic freshwater were conducted to determine sorption kinetics and sorption isotherms for four selected glass state polymers (polycarbonate, poly(methyl methacrylate), polystyrene, and polyvinyl chloride) and six different model substances (carbamazepine, hexachlorocyclohexane (β/γ), 17α-ethynilestradiol, chlorpyrifos, and o,p-dichlorodiphenyltrichlorethane). Sorption to the polymer particles was observed for all contaminants increasing with the KOW values of the contaminants. Because of losses of contaminants in control samples, sorption reaction models could be applied to four out of six contaminants, and isotherms were calculated for three contaminants. Furthermore, influences of the different polymer types used were observed in the experiments. Finally, microplastics separated from sediments were extracted and analyzed by GC/MS and LC-MS/MS using target screening methods and non-target approaches. Different pesticides were identified in the polymer particles, suggesting that microplastics can act as a sink for hydrophobic contaminants. Moreover, several plastic additives such as phthalates or chlorinated flame retardants were identified. For this reason, it is very likely that microplastics act as a direct source for these chemicals in aquatic systems. The results of this thesis stress the urgency for the mitigation of the plastic particles in the aquatic environment.

The Red River Delta in Vietnam is one of the regions whose quaternary aquifers are polluted by arsenic. Chronic toxification by arsenic can cause severe illnesses such as cancer, skin lesions, developmental defects, cardiovascular and neurological diseas-es, and diabetes. In this study, a food processing craft village in the Red River Delta was investigated regarding the potential risk faced by the population due to arsenic. The potential sources of arsenic are the groundwater, the crops grown in the sur-roundings, and animal products from local husbandry. However, the occurrence of arsenic in nature is variable, and its bioavailability and toxicity depend very much on its specification: trivalent compounds are more toxic and often more mobile than pen-tavalent compounds, while inorganic species are generally more toxic than organic ones. Local conditions, such as the redox potential, strongly influence its specification and thus potential bioavailability. The introduction to this work elucidates the key factors which potentially cause human exposure to arsenic: the geological setting of the study area, land and water use pat-terns, and the current state of research regarding the mobilization, bioavailability and plant uptake of arsenic. Although the study area is located in a region where the groundwater is known to be moderately contaminated by arsenic, the level of arsenic in the groundwater in the village had not previously been determined. In this study, water use in the village was examined by a survey among the farmers and by water analyses, which are present-ed in the following chapters. Four main water sources (rain, river, tube well and a pub-lic municipal waterworks) are used for the different daily activities; the highest risk to human health was found to be the bore well water, which is pumped from the shallow Holocene aquifer. The water from the bore wells is commonly used for cleaning and washing as well as to feed the animals and for food processing. Products like noodles and rice wine were examined as well as local pork and poultry. Vegetables from the gardens and rice plants from the surrounding paddy fields were sampled and ana-lyzed. All plants were found to have accumulated arsenic, leafy vegetables showing the highest arsenic concentrations. The results are discussed and compared, and conclusions are drawn in the last part. The reducing conditions in the paddy fields are likely to have a strong influence on arsenic uptake in rice plants and on transport to the aquifer. The installation of a wastewater treatment plant under the research project INHAND, which was funded by the BMBF German Ministry of Education and Research, led to lower arsenic concen-trations in the groundwater. Soaring industrialization, the growing population, and the consumers’ changing behav-ior will widely affect land and water use and hence the potential mobilization of arse-nic. In order to mitigate further human exposure to arsenic, wastewater needs to be treated and the reducing conditions in the rice fields need to be decreased by means of enhanced cultivation methods.