Green roofs are increasingly being employed as a sustainability feature of buildings. The sustainability approach in building designs requires reducing energy consumption and adopting low carbon energy sources without compromising the increasing expectations of comfort and health levels. Given the wide range of building designs, climates and green roof types, it is desirable to evaluate at the design stage the energy saving impact and other potential benefits from the application of green roofs. Currently, the abilities of building simulation programs to simulate the influences of green roofs are limited. For example, they have limitations in representing dynamic inter-layer interactions and moisture infiltration mechanisms. This research aims to develop a new model for the simulation of green roofs based on the control volume approach and to integrate the model within a whole building energy simulation program. The green roof elements consist of special layers such as plants and soil for which the control volume approach is capable of capturing their special characteristics with regards to the thermal and moisture exchanges. The model has been integrated within the ESP-r whole building energy simulation program. Within the ESP-r, the new green roof model alters the boundary condition of a roof surface on which green roof is constructed. The model development is carried out by a series of steps which include a careful selection of governing equations that describe the thermal and moisture balances in various layers of green roof, the numerical implementation for a simultaneous solution of the governing equations for the whole green roof, algorithm and code development and finally developing the interface with ESP-r. After successful integration, the model results were validated on an experimental test cell, which consists of an approximately 2 m2 planted medium on an insulated box with facilities for thermal, moisture and drainage measurements. The results for the thermal validation were promising with the significant boundary temperature values within a root mean square deviation (RMSD) in the vicinity of 0.5 K, whereas the moisture validation results are found to depend on initial conditions, the lower layers showing an RMSD of approximately 0.05 m3/m3 and the top layer nearly 0.12 [m3/m3]. The model is also able to predict the slowing down of water run-off. A methodology for collecting soil and plant properties which are required to be used along with the program has also been described. Based on the current state of the model and also considering the new developments in green roofs, some suggestions are proposed at the end of the thesis as a continuation of this research.

The design demands on water and sanitation engineers are rapidly changing. The global population is set to rise from 7 billion to 10 billion by 2083. Urbanisation in developing regions is increasing at such a rate that a predicted 56% of the global population will live in an urban setting by 2025. Compounding these problems, the global water and energy crises are impacting the Global North and South alike. High-rate anaerobic digestion offers a low-cost, low-energy treatment alternative to the energy intensive aerobic technologies used today. Widespread implementation however is hindered by the lack of capacity to engineer high-rate anaerobic digestion for the treatment of complex wastes such as sewage. This thesis utilises the Expanded Granular Sludge Bed bioreactor (EGSB) as a model system in which to study the ecology, physiology and performance of high-rate anaerobic digestion of complex wastes. The impacts of a range of engineered parameters including reactor geometry, wastewater type, operating temperature and organic loading rate are systematically investigated using lab-scale EGSB bioreactors. Next generation sequencing of 16S amplicons is utilised as a means of monitoring microbial ecology. Microbial community physiology is monitored by means of specific methanogenic activity testing and a range of physical and chemical methods are applied to assess reactor performance. Finally, the limit state approach is trialled as a method for testing the EGSB and is proposed as a standard method for biotechnology testing enabling improved process control at full-scale. The arising data is assessed both qualitatively and quantitatively. Lab-scale reactor design is demonstrated to significantly influence the spatial distribution of the underlying ecology and community physiology in lab-scale reactors, a vital finding for both researchers and full-scale plant operators responsible for monitoring EGSB reactors. Recurrent trends in the data indicate that hydrogenotrophic methanogenesis dominates in high-rate anaerobic digestion at both full- and lab-scale when subject to engineered or operational stresses including low-temperature and variable feeding regimes. This is of relevance for those seeking to define new directions in fundamental understanding of syntrophic and competitive relations in methanogenic communities and also to design engineers in determining operating parameters for full-scale digesters. The adoption of the limit state approach enabled identification of biological indicators providing early warning of failure under high-solids loading, a vital insight for those currently working empirically towards the development of new biotechnologies at lab-scale.

The project aim was to investigate the potential of a large scale, inexpensive, solar thermal façade in the UK climate. Profiled steel cladding was utilised as a solar absorber, with the channels used to form a series of parallel ducts when covered by a glass surface. Air was considered to flow through the ducts in two modes; forced or buoyant convection. The factors affecting air flow were investigated in a laboratory experiment. The factors affecting solar heat transfer to the air were investigated using prototypes in field conditions. Three models for forced convection and two for buoyant were found in the literature. These were developed and compared against the experimental results to establish appropriate design models. The design models were used to optimise the duct geometry for three desirable outputs; mass flow, temperature output or power output. Optimal duct geometry was found to depend on the flow mode assumed. In addition, the optimal geometry also depended on the required output. Thus it was determined that an optimal hybrid system which could switch modes as required, could not be configured; the function and utility of the system must be decided at the design stage and not reconfigured afterwards. The annual performance of a building-scale south facing façade fitted with such a system (optimised for power output) was modelled for forced and buoyant convection modes. It was found that both flow modes had the potential to generate significant amounts of heat energy which could be used, for instance, to preheat ventilation air. The buoyant system also showed the potential for the generation of significant natural ventilation. However the forced convection system would have the advantage of being more controllable, have a better seasonal distribution of performance and have a greater potential for higher air exit temperatures to be achieved in winter.

Building construction industry has significant impact on sustainability. The construction, operation and maintenance of buildings account for approximately 50% of global energy usage and anthropogenic greenhouse gas (GHG) emissions. In recent years, the embodied energy and carbon are identified increasingly important in terms of sustainability throughout building life cycle. Incorporation of sustainable development in building structural design becomes undoubtedly crucial. The effective building design requires smart and holistic tools that can process multi-objective and inter-connected domain knowledge to provide genuine sustainable buildings. With the advancement of information and communication technologies, various methods and techniques have been applied to accomplish the multiple objectives of sustainable development in building design. One of the most successful approaches is building information modelling (BIM), which requires further enhancement of interoperability. The emergence of Semantic Web technology provides more opportunity to improve the information modelling, knowledge management and system integration. The research presented in this thesis investigates how ontology and Semantic Web rules can be used in a knowledge-based holistic system, in order to integrate information about structural design and sustainability, and facilitate decision-making in design process by recommending appropriate solutions for different use cases. A research prototype namely OntoSCS incorporating OWL ontology and SWRL rules has been developed and tested in typical structural design cases. The holistic approach considers five inter-connected dimensions of sustainability, including structural feasibility, embodied energy and carbon, cost, durability and safety. In addition, the selection of structural material supplier and criteria in sustainability assessment are taken into account as well. This research concludes that the Semantic Web technology can be applied to structural design at early stage to provide multi-criteria optimised solution. The methodology and framework employed in this study can be further adapted as a generic multi-criteria and holistic decision support system for other domains in construction sector.

The concerns of global warming are guiding most industries and commercial properties towards addressing their energy usage. In large buildings where air conditioning is required, there is often a need for “chillers” to control the temperature of the building. This process is not environmentally friendly and expensive in terms of energy used and maintenance issues. The alternative is to cool buildings using natural resources such as induced wind drafts and water extraction from rivers and canal. The latter has not been used with optimum effectiveness because the prediction procedures are not sufficiently developed to satisfy environmental legislation. The mathematical approaches are unrealistic and extremely conservative in their analysis and this causes many valid proposals to be rejected. This research is aimed at addressing that situation. It will provide a valid interactive 3-dimensional analysis procedure that will better evaluate the potential of using any British Waterways canal or similar water source for cooling purposes. After water has been used for cooling it is returned to the canal in a heated state as a thermal plume. It is the boundaries of the plume that must be predicted with reasonable accuracy so that environmental legislation is not infringed and livestock is not jeopardised. It is equally important to ensure the analysis is not over sensitive so as to result in rejection of valid proposals. Earlier work studied heat distribution but did not consider the thermal discharge into still and shallow water, as in a British Waterways canal. The studies below investigate several canal sites to evaluate a variety of situations where the discharge plume differs. Criteria including discharge direction, volume of water, temperature differences, speed of discharge and depth of discharge pipe all play a part in the formation of the plume. As such it is possible to develop an understanding of how the thermal plume merges into the still water and how the heat is diffused into the general body of water. In conjunction with site measurements a laboratory experimental scale model tank was built to replicate the real canal site. This allowed data to be varied and measured more readily. Two different types of discharge have been the subject of this research - the first being when the discharge pipe is located at the surface of the receiving water, the second being when it is submerged deeply below the surface. In all cases the temperature and velocity are measured at various points and at a variety of depths to provide a three dimensional plot across the mixing zone. In addition to the mathematical analysis, thermal imaging was used to predict the heat diffusion profiles on the surface of the receiving water in both the canal site and the model tank. CFD software is also used to evaluate the distribution of temperature and velocity within the mixing zone. The mathematical analysis produced an equation to predict the heat diffusion profile in surface discharge. And a number of equations were produced to model the plume path line in submerged discharge- relating to temperature and velocity dilution along and across the path lines. The relative effects of the bed and free surface proximity appeared significantly in the equations. A 3-dimensional model of the size of the plume is presented to demonstrate the results. The procedure followed in this study will enable the Environment Agency personnel to assess the waste heat utilization with greater thoroughness and within a shorter period.

In recent years discoloured water has become a matter of growing concern to water resource managers. Discoloured water is a major source of consumer complaints and is expensive in capital and recurrent costs. The treatment of water discolouration is believed to be associated with a number of health issues, such as Alzheimer's disease. In particular, discoloured water, upon chlorination, is believed to produce carcinogens. The principal aim of this research has been to consider and manage water colour within an entire reservoir catchment system; Thornton Moor Reservoir, the study area, has experienced some of the highest values of colour in the Yorkshire Water Region, and has been an area of significant concern and cost to Yorkshire Water Services. Apparently homogenous subcatchments can produce marked differences in the colour of runoff data. This research has involved an investigation into the relationship between the subcatchment tributary water colour and catchment morphology. The relationships established were used to generate a predictive model for water colour such that areas of high water colour could be identified without intensive sampling. The initial phase of this study considered the transfer network involved in bringing the colour from the catchment to the reservoir. This has involved an analysis of the spatial and temporal variation of water discolouration within the catchment. The consistency of the spatial variation of water colour between the tributaries has been utilised to develop a management protocol which is presently being implemented at Thornton Moor in order to minimise the level of discolouration, whilst maintaining water supplies. Edwards (1987), describes the reservoir as the second line of defence in the protection of water supplies in direct supply reservoirs. No research to date has considered the role of the reservoir in the storage, transmission and release of discoloured water. Empirical evidence at Thornton Moor Reservoir suggests that for the majority of the year, the reservoir operates as a buffer to colour; however at certain times of the year it appears actively to increase the colour entering the treatment works. In considering the entire catchment system, it has been possible to develop a transferable staged approach to catchment management.

No description available.

There is a requirement in the European Union to divert organic wastes from landfill because of the risk of methane emissions. One alternative is anaerobic digestion of organic wastes, such as food waste, to stabilise them whilst at the same time recovering the energy from them. One problem with this approach is that the high nitrogen content of food waste may lead to ammonia inhibition. A solution to this has been found for mesophilic digestion but had not been attempted in thermophilic digestion where ammonia toxicity is known to be more acute. The work was carried out in laboratory-scale semi-continuous digesters operated over long time periods to provide maximum opportunity for acclimatisation, and in duplicate to give an indication of reproducibility. A series of experimental runs were undertaken at thermophilic temperatures to assess the influence of trace element (TE) addition on the digestion process. These were carried out at organic loading rates (OLR) of 2, 3 and 4 g volatile solids (VS) l-1 day-1 against unsupplemented controls at OLR 2 g VS l-1 day-1. Although TE addition could offset the accumulation of VFA which occurred in response to an increasing concentration of total ammonical nitrogen (TAN), it could not prevent this. The high alkalinity resulting from ammonia, however, allowed the digesters to continue to produce methane until VFA had accumulated to high concentrations before eventual failure due to a rapid drop in pH. To determine the threshold inhibitory ammonia concentration in thermophilic digestion, one pair of digesters was run on synthetic low nitrogen food waste (low-N food waste) at an OLR 2 g VS l-1 day-1 and compared to a control pair running on domestic food waste at the same loading. All four digesters received TE supplementation. The digesters fed with low-N food waste showed consistently stable performance with pH ~7.4, IA/PA ratio ~0.4-0.5, SMP 0.39 l CH4 g-1 VS, 52-55% CH4, total VFA <500 mg l-1 and 88% VS destruction whereas the controls showed signs of failure after 112 days and irreversible VFA accumulation at a TAN concentration >3.5 g N l-1. One of the low N digesters was supplemented with urea slowly and one by a shock dose: both showed signs of VFA accumulation at TAN >2.5 gl-1 and, again, an irreversible trend in propionic acid build-up when TAN >4 g N l-1. Long term operation showed meta-stable conditions when the digesters were operated at TAN between 2.5 - 3.5g l-1 with oscillations in VFA (especially propionic acid) concentration. Mesophilic digestion at 37oC with TE addition showed very stable performance with pH ~8, IA/PA ≤ 0.3, SMP ~0.48 l CH4 g-1 VS, 55-60% CH4, total VFA < 300 mg l-1 and VS destruction ~75-78% with a final total ammonia nitrogen (TAN) concentration of 4.5 g N l-1. As the temperature in digesters was raised from 35 to 43 oC in 1oC steps a change in performance was noted when the temperature reached 40 oC. Above this temperature VFA concentrations rose above 4000 mg l-1 and biogas and methane production fluctuated. It is probable that the higher temperature increased the concentration of free ammonia nitrogen (FAN) to ~800 g N l-1 at the measured TAN concentration ~5.5-6.0 g N l-1 and this was sufficient be inhibitory even with TE dosing. Fluorescent in situ hybridisation (FISH) was used to identify the methanogenic populations in some of the trials over selected time periods. This showed changes in population structure both in relation to temperature (mesophilic or thermophilic) and also in response to increasing concentrations of TAN. At high TAN concentrations Methanomicrobiales was the dominant methanogenic group and under mesophilic conditions this proved to be extremely ammonia tolerant. A 14C radio-labelling assay confirmed the dominant pathway to methane formation was by the hydrogenotrophic route which reflected the known metabolic pathway of this methanogen. It was concluded that thermophilic digestion of source segregated domestic food waste would lead to instability and failure of the process unless measures were introduced to reduce the TAN concentration to < 3.5 g N l-1, and preferably to < 2.5 g N l-1. Keywords: Anaerobic digestion, food waste, biogas, VFA accumulation, ammonia inhibition, Fluorescent in situ Hybridisation (FISH).

Due to legislative pressures and the recent ban of trybutyl tin, alternative environmentally acceptable ship hull antifouling systems are required. This thesis uses a multidisciplinary approach to combine two disparate areas of research namely marine biology and surface engineering, to develop a novel natural product (NP) based antifouling system. The overall objective of this thesis is to transfer a natural marine biological defence mechanism into an engineered antifouling coating system. By combining natural product extraction and incorporation into a trial coating an extensive test programme was able to investigate the antifouling performance and address the issues of bringing this active area of research to the next technological readiness level. By using a stepwise approach to the development of the engineered solution, a suite of techniques were used to fully characterise a NP based system. The biological and surface engineering techniques adapted and developed are described here and their future use to evaluate a novel NP based antifoulant system is critically assessed. After an extensive literature review, an ethanol extract from the red seaweed Chondrus crispus was selected as the natural product source. NP specimens were harvested locally and also purchased as industrially processed dried algae. The industrially processed algae showed good antifoulant activity ( ≤ 25 μg mL-1) in laboratory bioassays and had a greater efficacy than the locally harvested samples highlighting its potential as an economically viable solution. The direct incorporation of the NP into a commercial control depletion polymer binder, allowed for the rapid development of characterisation techniques to evaluate the effects this had on the performance of the NP-binder matrix. The feasibility of a range of electrochemical techniques to measure corrosion potential, impedance, resistance and water uptake in the NP coating was critically assessed. A combination of open-circuit potential and electrochemical impedance spectroscopy provided a unique and rapid means to non-destructively measure the contribution of incorporated NPs to the degradation and water uptake of the binder film. Studies of biofilm growth were used to successfully measure community viability and structure using fluorescent staining and differential interference contrast microscopy. These techniques were found to be very informative on Southampton water marine biofilm community structure and were cross correlated by fourier transform infrared measurements. Resistance to biofouling was determined through field trials, an important testing platform for an antifouling system, and specifically trials which test the entire coated system including any primers and substrate preparation requirements. An initial NP antifouling performance greater than the booster biocide (Chlorothalonil) control was documented for one field trial over a period of the first 6 weeks. A key aspect was to determine the potential efficacy of NPs and their viability in a coating system. To achieve this, a range of standard and non-standard techniques were used to assess this novel combination of crude NP extract and commercial binder system. This work has shown that a limited antifoulant activity is achievable. By evaluating the effect of a NP on both the fouling community and a binder system this unique approach helps define key techniques to assess future NP antifoulants and identifies the optimisation required to increase their functionality.

The possibility of acetone shock loadings to phenol acclimated systems resulting in sequential substrate utilization and increased effluent phenol concentrations was evaluated. Phenol acclimated batch and continuous-flow systems, developed with seed from a municipal wastewater treatment plant, were shock loaded with acetone, bacto-peptone, and domestic primary effluent. Phenol and acetone utilization rates were then monitored using direct injection gas-liquid chromatography. The results of the investigation indicated that, under the described experimental conditions, qualitative shock loading of phenol acclimated/utilizing cultures had no significant effect on effluent phenol concentrations. Variations of system pH, however, were found to have extreme effects. / Master of Science