In this study a series of novel Fe-based materials derived from a bulk metallic glass-forming composition was investigated to improve the ductility of this high-strength glassy alloy. The interplay between the factors chemistry, structure and resulting mechanical properties was analyzed in detail. It has been recognized that subtle modifications of the chemical composition (carbon addition) lead to appreciable changes in the phase formation, which occurs upon solidification (from a single-phase structure to composite materials). As a consequence, significant differences in the mechanical response of the particular samples have been observed. The materials developed here were fabricated by centrifugal casting. To explore the structure features of the as-cast cylinders, manifold experimental techniques (X-ray diffraction, optical, as well as electron microscopy) were employed. The occurrence of the numerous reflections on the X-ray diffraction patterns has confirmed the crystalline nature of the studied Fe-based alloy systems. The subsequent extensive research on their deformation behavior (Vickers hardness and room temperature compression tests) has revealed that, although the glass-forming ability of the investigated compositions is not high enough to obtain a glassy phase as a product of casting, excellent mechanical characteristics (high strength - comparable to that of the reference bulk metallic glass (BMG) - associated with good ductility) were achieved for the “composite-like” alloys. In contrast, the single phase cylinders, subjected to compressive loading, manifested an amazing capacity for plastic deformation – no failure occurred. The fracture motives developed during deformation of the “composite-structured” samples were studied by scanning electron microscopy. The main emphasis has been put on understanding the mechanisms of crack propagation. Owing to the structural complexity of the deformed samples, it was crucial to elucidate the properties of the individual compounds. Based on the obtained results it was concluded that the coexistence of a soft f.c.c. γ-Fe phase in combination with a hard complex matrix is responsible for the outstanding mechanical response of the tested composites. While the soft particles of an austenite contribute to the ductility (they hinder the crack propagation and hence, cause unequivocal strain-hardening), the hard constituents of the matrix phase yield the strength.

In this study a series of novel Fe-based materials derived from a bulk metallic glass-forming composition was investigated to improve the ductility of this high-strength glassy alloy. The interplay between the factors chemistry, structure and resulting mechanical properties was analyzed in detail. It has been recognized that subtle modifications of the chemical composition (carbon addition) lead to appreciable changes in the phase formation, which occurs upon solidification (from a single-phase structure to composite materials). As a consequence, significant differences in the mechanical response of the particular samples have been observed. The materials developed here were fabricated by centrifugal casting. To explore the structure features of the as-cast cylinders, manifold experimental techniques (X-ray diffraction, optical, as well as electron microscopy) were employed. The occurrence of the numerous reflections on the X-ray diffraction patterns has confirmed the crystalline nature of the studied Fe-based alloy systems. The subsequent extensive research on their deformation behavior (Vickers hardness and room temperature compression tests) has revealed that, although the glass-forming ability of the investigated compositions is not high enough to obtain a glassy phase as a product of casting, excellent mechanical characteristics (high strength - comparable to that of the reference bulk metallic glass (BMG) - associated with good ductility) were achieved for the “composite-like” alloys. In contrast, the single phase cylinders, subjected to compressive loading, manifested an amazing capacity for plastic deformation – no failure occurred. The fracture motives developed during deformation of the “composite-structured” samples were studied by scanning electron microscopy. The main emphasis has been put on understanding the mechanisms of crack propagation. Owing to the structural complexity of the deformed samples, it was crucial to elucidate the properties of the individual compounds. Based on the obtained results it was concluded that the coexistence of a soft f.c.c. γ-Fe phase in combination with a hard complex matrix is responsible for the outstanding mechanical response of the tested composites. While the soft particles of an austenite contribute to the ductility (they hinder the crack propagation and hence, cause unequivocal strain-hardening), the hard constituents of the matrix phase yield the strength.