Air quality was influenced by many factors, in South Taiwan, air pollutants transportation caused by monsoon or sea-land breeze that may caused high air pollution events. Air pollutant generated by human activity on daytime, then transported and accumulated at sea region by land breeze during the nighttime. Unfortunately, air pollutants that accumulated over sea on night may transport back to land by sea breeze on daytime. Besides, monsoon may carry air pollutants from other regions to South Taiwan and caused high air quality event. Till now, air quality influenced by sea-land breeze and monsoon were not verified in South Taiwan. This study investigated the temporal variation and spatial distribution of air pollutants in the atmosphere around the coastal region of South Taiwan. Ambient air pollutants were simultaneously monitored both inland and offshore. Inland monitoring was conducted at two sites associated with fourteen national air quality monitoring stations, while offshore monitoring was conducted at two sites both in an island and on the boat. A protocol of ambient air quality monitoring was conducted for forty-eight hours. Gaseous air pollutants (i.e. CO, SO2, NOX, THC, and O3) were continuously monitored instrumentally. Data obtained from both inland and offshore monitoring were applied to plot the concentration contour by a software SURFER. Hourly variation of air pollutant concentrations was further used to study the influences of sea-land breezes on the transportation of air pollutants around the coastal region of South Taiwan for different seasons. In August and November, 2006 and May, 2007, sea-land breeze was observed during sampling period and sea breeze arise from 9:00 A.M. to 24:00 P.M. The average wind velocity was 1~4 m/s during the sampling period. In January and March, 2007, prevail wind direction was north direction and northeast direction (270o~30o), that was influenced by northeast monsoon during the sampling period. The average wind velocity was 2~4 m/s. The results showed that distribution of air pollutants, including O3, NOX, THC, and CO influenced by sea-land breezes, particularly for ozone. Air pollutants transported to sea region during the nighttime, and transported back at daytime. This phenomenon cause air pollutants accumulated between Kao-Ping and sea region. In general, NOX generated by transportation and industrial process, thus high concentration of NOX appeared during traffic congestion period and at industry region, mainly Kaohsiung city and Linyuang industrial region. However, sea-land breeze effect upon transportation of air pollutants wasn¡¦t obvious for SO2. High SO2 concentration appeared at Linyuang industrial region and Siaogang at daytime, and transported to region along the coast. During northeastern monsoon season, northeast winds obstructed by Central Mountain Range cause air pollutants accumulated at Kao-Ping region. High NOX concentration appeared at Kaohsiung City and Linyuang industrial region. SO2 accumulated at Siaogang and Linyuang during the nighttime might be caused by high atmospheric pressure system and blew air pollutants to Linbian. CO was accumulated at Siaogang at daytime and transported to Donggang, while THC was accumulated at Donggang whole day.