The objective of this thesis was to identify the mechanisms associated with the recurrence of rock-slope instability along the R518 and R523 roads in Limpopo. Advanced geotechnical methods and ASTER imagery were used for the purpose while a predictive rockfall hazard rating matrix chart and rock slope stability charts for unsaturated sensitive clay soil and rock slopes were to be developed. The influence of extreme rainfall on the slope stability of the sensitive clay soil was also evaluated. To achieve the above, field observations, geological mapping, kinematic analysis, and limit equilibrium were performed. The latter involved toppling, transitional and rotational analyses. Numerical simulation was finally resorted to. The following software packages were employed: SWEDGE, SLIDE, RocData, RocFall, DIPS, RocPlane, and Phase 2. The simulation outputs were analyzed in conjunction with ASTER images. The advanced remote sensing data paved the way for landslide susceptibility analysis. From all the above, rockfall hazard prediction charts and slope stability prediction charts were developed. Several factors were also shown by numerical simulation to influence slope instability in the area of study, i.e. sites along the R518 and R523 roads in the Thulamela Municipality. The most important factors are extreme rainfall, steep slopes, geological features and water streams in the region, and improper road construction. Owing to the complexity of the failure mechanisms in the study area, it was concluded that both slope stability prediction charts and rock hazard matrix charts are very useful. They indeed enable one to characterize slope instability in sensitive clay soils as well as rockfall hazards in the study area. It is however recommended that future work is undertaken to explore the use of sophisticated and scientific methods. This is instrumental in the development of predictive tools for rock deformation and displacement in landslide events. / Electrical and Mining Engineering / D. Phil. (Mining Engineering)