Surface mining of the Athabasca Oil Sands of Canada is occurring at an unparalleled rate resulting in large scale disturbances over vast areas. Soil water availability for plants is one of the key issues faced when reclaiming the landscape. A factor which limits the soil water availability is soil water repellency (SWR). Soil water repellency is found on both natural and disturbed sites in this region and can cause reduced infiltration, reduced soil water storage, enhanced runoff, increased preferential flow, and reduced ecosystem productivity. Effective characterization of SWR, determination of the causes of SWR and understanding how it affects soil pores and water flow are important for environmental management. The main objective of this study is to examine the effect of SWR and fungal hydrophobicity on soil water dynamics in Athabasca Oil Sands. This was accomplished by determining the relationship between the measurement of severity and persistence of SWR and the critical water content (CWC) where SWR is greatest between different soils in the region. Examining how the water conducting porosity and soil pores are affected by SWR. Developing methods to quantify fungal strains that cause SWR and testing of these fungal strains for their ability to alter the SWR and infiltration into soil. Results show that a high severity (Contact angle) of repellency does not necessarily denote long persistence (Water Drop Penetration Time) or high CWC in soils from the region. A high severity of SWR in larger diameter pores decreased the water conducting porosity due to the larger pore contribution to the total liquid flux. The modified microscopy approach and the alcohol percentage test (APT) resulted in improved characterization of fungal hydrophobicity. Fungal strains were classified as hydrophilic, hydrophobic and chrono-amphililic based on their surface properties from these measurements. The surface property of selected fungi strains can alter the SWR in both a repellent and wettable soil and can also change the water infiltration rate. This research highlights the importance of characterization of SWR, the effects on water flow, and how fungal hydrophobicity can alter the SWR and infiltration. This will aid in improving our understanding of SWR and improve remediation efforts on water repellent soils in the Athabasca Oil Sands region.

The Lockheed Fire burned 31 km2 (7,660 acres) of the Scotts Creek watershed in August 2009. 4.5 km2 (1,100 acres) of California Polytechnic State University’s educational and research facility at Swanton Pacific Ranch. The burned region presented an opportunity for studying the hydrologic response of burned soils in the Santa Cruz Mountains where there is insufficient post-fire studies regarding fire-effects on watershed processes such as infiltration and near-surface runoff. Soil infiltration and soil water repellency were evaluated with rainfall simulations, Mini-disk Infiltrometer (MDI) and water drop penetration time tests (WDPT) at sites represented by variations in burn severity, soils, and vegetation types throughout the Scotts Creek watershed each year for 5 years following the burn. Mixed-effects modeling was utilized on the 3 datasets to evaluate if changes could be detected in infiltration rates and water repellency following the fire. Rainfall simulations and WDPT tests showed that the fire did not have a statistically-significant impact on infiltration rates or soil water repellency, whereas the MDI tests detected a statistically-significant impact on post-fire infiltration. While the MDI results showed that fire had a significant impact on the hydrologic response over time, questions arose regarding challenges associated with sampling suggesting the method may not be pursued on steep slopes with high surface rock fragments or in the presence of large soil macropores. It is recognized that additional understanding would be gained from having multiple replications at each site every year and tests could be conducted on a subwatershed scale to account for the naturally occurring variability of larger watersheds.

Dynamic soil water repellency is an important soil phenomenon in the vadose zone as it is now recognised that most soils in the world are likely to express some degree of reduced wettability and/or long term hydrophobicity. Fractional wettability and contact angles are, however, rarely discussed or quantified for natural systems. This is particularly the case in the presence of dynamic contact angles. Soil water repellency remains a persistent impediment and challenge to accurate conceptual and numerical models of flow and storage in the vadose zone. This dissertation addresses the opportunity and pressing need for contributions that develop better quantifiable definitions, descriptions, and understanding of soil water repellency. Using materials collected from post wildfire sites, this work employs water and ethanol to identify, isolate, and quantify contact angle dynamics and fractional wettability effects during infiltration. Varied concentrations of water and ethanol solutions were applied to soils and observed through X-ray microtomography, tension infiltration experiments, and moisture content measurements in the laboratory and field. Several analyses from lab and field investigations showed that applications of ethanol and specifically, water-ethanol aqueous solutions provide unique additional insights into proportions of media that remain non-wettable and how those proportions affect overall hydrologic processes, which are not readily observable through water infiltrations alone. Observations include the wetting up of microporous structures, reduced storage, and changes in unsaturated hydraulic conductivities. Challenges which develop as a consequence of variable fluid properties including changes to operational pore assemblages, slow down of wetting fronts, and non-uniqueness relative to infiltration responses are addressed. Important insights and contributions were developed through this approach and water-ethanol mixtures are valuable tools for developing greater quantification and mechanistic data to better inform our models and understanding of dynamic soil water repellency. / Dissertation / Doctor of Philosophy (PhD) / Quantifying fluid behaviours in soils is important for a host of environmental, social, and economic reasons. Over the last 25+ years, one soil phenomenon has garnered increased attention because it interferes with our ability to carry out this work. Soils that are or become water repellent develop all over the world and where hydrophobic or non-wetting substances can enter soil and remain in pore spaces or as coatings on particles. To assist in the tracking and management of its complex effects on water storage and infiltration, the goals of this work were to develop fundamental insights into the manifestation and effects of this variable soil property on key hydrologic properties and processes. This work tests a new conceptual model for understanding these systems through both field and laboratory work and using a number of different technologies. These include X-ray microtomography (μXCT), tension infiltrometry, and more regularly applied techniques which are sensitive to changes in repellency. The works shows how combining fractional wettability and contact angle dynamics generates a stereoscopic conceptual framework which facilitates increased capacity for quantifying and understanding of soil systems expressing dynamic soil water repellency.