Exploring uses of two-phase mixtures as a way to store peak solar energy for off-peak usage is a novel approach that has been gaining attention in recent years to address the issues tied to solid fuel dependence. This research explores a “solar salt” mixture (40%wt KNO3 and 60%wt NaNO3) in an aluminum enclosure under two test conditions: conduction enhancement and no conduction enhancement. The central aim is to develop an understanding of thermal distributions and melt developments as the system moves from room temperature to 300 oC. Thermal pattern development is explored by experimentally observing a 2-D temperature field at 8 co-planar points, comprised of 3 radial positions with complementary circumferential measurements, using thermocouples. The instrument array is traversed to three different axial positions where collected data is compared with results from a numerical solver. Results find three important details. First, the melt pattern of the fin experiments show quicker rates of melting after the onset of melt at the bottom of the enclosure. Second, the spatial effects of the instrumentation influence the presence of thermal phenomena. Lastly, approximations of the salts behavior using numerical simulations are supported in identifying phases of melt development.

In response to the extensive energy demands on national and global levels, concentrated solar power (CSP) plants are designed to harness and convert solar energy to electricity. For such green energy application, robust, reliable and durable materials for CSP constructions are required. The corrosion resistance is among many parameters to consider in these thermalelectrical stations such as for pipes and storage tanks in CSP. In this investigation, the corrosion behavior of AISI 304 stainless steel (18 wt. % Cr, 8 wt. % Ni) with the heat transfer fluid, also known as solar salt, has been examined. The ternary eutectic salt mixture with the composition, 53 wt. % KNO3, 40 wt. % NaNO2, and 7 wt. % NaNO3, that melts at 142°C, has a potential use in CSP as a heat transfer fluid. The solar salt was prepared for this corrosion study from reagent grades of high purity nitrites and nitrates. Samples of AISI 304 stainless steel were sectioned from a sheet stock of the alloy and exposed to solar salt at 530°C in air at 1 atmospheric pressure. After test intervals of 250, 500, and 750 hours in total immersion condition, AISI 304 stainless steel samples have developed a scale of corrosion products made up of multiple oxides. X-ray diffraction and scanning electron microscopy with X-ray energy-dispersive spectroscopy were employed to examine the extent of corrosion and identify the corrosion products. Transmission electron microscopy was used to verify the corrosion products identity via electron diffraction patterns. Oxides of iron were found to be the primary corrosion products in the presence of the molten alkali nitrates-nitrite salt mixture because of the dissolution of the protective chromium oxide (Cr2O3) scale formed on AISI 304 stainless steel coupons. The corrosion scale was uniform in thickness and made up of sodium iron oxide (NaFeO2), iron oxide, hematite (Fe2O3), and chromium-iron oxide (Cr,Fe)2O3 solid solution. The latter was iv found near the AISI 304 stainless steel. This indicates that the scale formed, particularly on the upper layers with presence of sodium iron oxide and iron oxide, hematite, is protective, and forms an effective barrier against penetration of fused solar salt. At the alloy interface with the bulk corrosion scale, the corrosion process induced a compositional modification in the grains located at the interface. There are iron rich and iron depleted grains at the interface if compared to the nominal iron content of the alloy. The mode of attack is identified as uniform at the test temperature of 530°C, showing a parabolic behavior with a parabolic rate constant (Kp) equals to (m2 /sec). By extrapolation, annual corrosion rate is estimated to reach 0.784 mils per year. Corrosion behavior of AISI 304 stainless steel is discussed in terms of thermodynamics and reaction paths.

[Truncated abstract. Formulae and special characters in this field can only be approximated. See PDF version for accurate reproduction.] Solar salt producers use solar energy to evaporate seawater as it flows through a series of ponds. The Shark Bay Salt solar ponds, at Useless Inlet in Western Australia, vary in salinity from that of seawater to four times seawater, over the pond sequence. Water column photosynthesis and biomass decreased markedly with increasing salinity along the pond sequence, while benthic productivity increased as cyanobacterial mats developed. Correspondingly, net productivity shifted from autotrophy to heterotrophy in the water column and from heterotrophy to autotrophy in the benthos. Both shifts occurred at intermediate salinity in the pond sequence, where there was low production in both the water column and benthos. Within individual ponds, productivity, algal biomass and physico-chemical conditions were relatively constant over the year of study. Transitions between benthic and planktonic production along the pond sequence were driven mostly by direct responses to salinity stress, as well as the formation of a gypsum crust on the pond floors at higher salinity (>120 g kg-1). This transition is similar to that which occurs in saline lakes undergoing anthropogenic salinisation and identifies critical salinities for the restoration of these lakes.