In literature Trefftz method normally has geometric (exponential) convergence. Recently many scholars have found that spectral method in some cases can converge faster than exponential, which is called super-geometric convergence. Since Trefftz method can be regarded as a kind of spectral method, we expect it might possess super-geometric convergence too. In this thesis, we classify all types of super-geometric convergence and compare their speeds. We develop a method to decide the convergent type of given error data. Finally we can observe in many numerical experiments the super-geometric convergence of Trefftz method to solve Helmholtz boundary value problems.