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Due to climate changes and an increasing global temperature, the maritime transport sector has taken upon a mission to reduce their share of greenhouse gas emissions by 50% until 2050. Combustion engines used in ships mainly run on carbon-based fuels, but to achieve the reduction of emissions it is crucial to investigate the possibility of alternative fuels. Ammonia is an alternative fuel with a carbon free chemical composition that shows big potential, with several initiatives to put ammonia driven ship engines on the market in the near future. For ships to be able to run on ammonia fuel, the engine materials have to withstand the corrosive effect of ammonia whilst still ensuring that the motor runs properly. In this study, two piston ring materials are investigated with regards to long-term effects of exposure to ammonia solution. The piston ring materials investigated were comprised of a cast iron substrate covered with either a chromium ceramic coating or a with a cermet coating, the latter also coated with an aluminium-bronze based running in layer on top. The materials were submerged in 25% ammonia solution for different time intervals up to 12 weeks, with a solution change every fourth week. After exposure to ammonia, the materials were tribologically tested in a reciprocal sliding test rig. The surfaces, both inside and outside of the wear tracks, were analysed with SEM and EDS, as well as with CSI. The chromium ceramic coating did not seem to get affected by, or interact chemically, with the ammonia solution. Exposing the material to ammonia did not seemingly affect the tribological properties. However, two different behaviours were observed when analysing the cermet coated samples with a running-in layer of aluminium-bronze. These samples reacted with the ammonia solution in two different ways, resulting in the series being split into two. In both cases precipitates were formed, but the colour changes of the solutions differed for the series. The coatings were also worn differently, as in one case a flattening effect was observed throughout all time intervals, whereas in the other case the worn volume and track depth seemed to increase with exposure to ammonia solution.

This thesis reports the effects of ultrashort laser pulse irradiation of various materials. The morphology after irradiation was examined using several microscopy techniques. Emphasis was placed on the identification of crystallographic changes and the analysis of laser-induced periodic surface structures. Grooves were machined in silicon by translating the target under the focused laser beam. The resulting depths were measured as a function of pulse energy, translation speed, and number of consecutive passes, for 800 and 400nm wavelength irradiation. The wall morphology and a corrugation along the bottom of the grooves were characterized. Various polarization configurations relative to the translation direction were compared. Such characterizations are relevant for the practical application of femtosecond laser micromachining. Silicon and gallium phosphide exhibited periodic structures after irradiation using photon energies less than the bandgap energy, with periods as small as ~20% of the irradiation wavelength. The significantly sub-wavelength periodic structures had a shallow profile on silicon, appearing as fine lines or grids of protrusions and depressions. On gallium phosphide, the surface evolved into planar-like structures with a large aspect ratio, possessing crystalline centers coated with amorphous material. These investigations, along with additional experiments, would help identify the precise physical origins of the short-period structures. On silicon and germanium, the target crystal orientation was shown to affect the formation of certain morphological features. For multiple-pulse irradiation, the (100) and (111) surface orientations exhibited significantly different tendencies for large conical structure formation. A thin layer of defected material coated the conical structures, with some defects present within the periodic structures. The different crystalline orientations did not affect periodic structuring. Cross-sectional transmission electron microscopy of silicon after irradiation by single pulses revealed amorphous material and dislocations in the bulk for sufficiently high pulse fluences. On a sample consisting of a metal layer on thermally-grown oxide on silicon, a range of pulse fluences was found which removed the metal layer without observed thinning of the oxide layer. Within this fluence range, above a particular fluence substantial defects were formed in the underlying silicon. Although ultrashort pulse irradiation of materials is frequently considered to be 'damage-free', attention should be paid to sub-surface modifications not evident from surface imaging. For the drilling of holes in copper foils, the pulse duration did not strongly affect the final morphology for durations under several picoseconds. A photodiode below the foil during drilling recorded transmitted light, indicating the number of pulses required for penetration under a variety of conditions, and characterizing hole evolution during drilling. Periodic surface structuring on the walls of holes depended on the irradiation atmosphere, pulse duration, and laser polarization. These measurements provide insight into the physical processes of material modification, and for the selection of irradiation parameters in practical applications. / Thesis / Doctor of Philosophy (PhD)

Die Arktis erwärmt sich mehr als 3x so schnell wie der globale Durchschnitt, was zu Permafrostdegradation führt. Permafrostdegradation führt zu einer Absenkung des Bodens mit erheblichen Veränderungen der Landoberfläche (VdL), die tiefgreifende ökologische Folgen haben und Infrastruktur-Stabilität bedrohen. Fernerkundungsdaten ermöglichen die Erkundung von VdL und Störungen in weiten Regionen. Erste Anzeichen von Permafrostdegradation zu detektieren, bleibt jedoch eine Herausforderung auf Grund ihrer kleinen räumlichen Skalen und hohen zeitlichen Variabilität. Die zunehmende Verfügbarkeit hochauflösender Bilddaten erfordert zudem nachhaltige Ansätze für deren effiziente Verarbeitung. Auch ist es wichtig, die Anfälligkeit von Infrastruktur im Kontext dieser VdL und die potenziellen ökologischen Folgen im Falle eines Infrastruktur-Versagens zu verstehen. Meine Dissertation widmete sich diesen Herausforderungen am Beispiel Alaskas (U.S.A.). Die drei Studien hatten folgende Ziele: (i) Erkennung und Quantifizierung von VdL, im Kontext von Permafrostdegradation, unter Nutzung hochauflösender Fernerkundungsdaten und Bewertung ihrer Bedrohung für Infrastruktur und (ii) Identifizierung von Infrastrukturelementen mit entscheidender Bedeutung für die Bevölkerung Alaskas, um deren Anfälligkeit für Permafrostdegradation einschätzen zu können. Das Ergebnis sind (i) zwei skalierbare, weitgehend automatisierte, leicht zugängliche methodische Rahmen, die erfolgreich VdL und Erosionsprozesse an Seeufern erkennen und quantifizieren. Außerdem erstellte ich (ii) ein umfassendes Inventar kritischer Infrastruktur und vom Menschen beeinflusster Gebiete, das über industrielle und wirtschaftliche Bedeutung hinausgeht. Dieses Inventar beruht auf der Integration verschiedener Quellen, wodurch eine eingehende Analyse der Anfälligkeit der Infrastruktur für Permafrostdegradation und ökologischen Folgen möglich wird, die im Falle eines Versagens der Infrastruktur entstehen können. / The Arctic is warming more than 3x faster than the global average, leading to permafrost degradation. When permafrost thaws, it results in ground subsidence and causes substantial land surface changes, which have profound ecological consequences and pose a threat to infrastructure stability. Remote sensing data allows us to explore land surface changes and disturbances across regions, yet early detection of permafrost degradation remains challenging due to its small-scale occurrence and high temporal variability. Further, the increasing availability of high-resolution imagery requires a sustainable framework to efficiently process these data. Also, it is essential to understand the vulnerability of infrastructure in context of these land surface changes and the potential ecological consequences that may arise in the event of infrastructure failure. In my thesis, I addressed these challenges focusing on the U.S. state of Alaska. I conducted three studies with the objectives to (i) detecting and quantifying the trajectories of land surface changes attributed to permafrost degradation using very high-resolution remote sensing data and assessing their threat to infrastructure, and (ii) identifying infrastructure elements critical to the Alaskan population to allow an estimation of their vulnerability to permafrost degradation. As a result of my research, I developed (i) two scalable, widely automated and easily accessible frameworks that successfully detect and quantify land surface displacements and shoreline erosion processes attributed to permafrost degradation. Additionally, (ii) I have compiled a comprehensive inventory of critical infrastructure and human-impacted areas, extending beyond economic and industrial importance. I created this inventory by integrating different data sources, allowing for an in-depth analysis of infrastructure vulnerability to permafrost degradation and the ecological consequences that may arise in the event of infrastructure failure.