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This thesis explores the behaviour of metal cyanide complexes under oxidative acid conditions in ion exchange systems, with the objective of developing an ion exchange based process for the treatment of gold cyanidation tailings. The novel cyanide detoxification process developed from this study employs strong base ion exchange resins to extract cyanide from tailings. Variations in the stability of cyanide complexes are exploited to concentrate, recover, or destroy cyanide species loaded on the resin, through the use of an oxidative acid eluent containing H2O2 and H2SO4. This eluent removes all base metal cyanide complexes from strong base resins, while regenerating the resin. The spent eluent, containing the base metals recovered from the tailings, can be used as a source of such base metals. Copper can be recovered separately from other base metals if necessary. Low levels of precious metals present in the tailings are accumulated on the resin as the ion exchange bed is cycled between loading and elution stages. They can be recovered economically, so as to offset the cost of the tailings detoxification. Cyanide is initially concentrated as an alkaline solution, which can be detoxified within the process or recovered for recycling. This process was successfully tested at pilot scale by treating approximately 14,000 m3 of cyanide contaminated tailings solution, over 14 loading/elution cycles on a standard strong base ion exchange resin bed. This treatment reduced the total cyanide concentration of the contaminated solution from approximately 50 mg/L to an average of 1.5 mg/L. The reagent cost was approximately ADD 0.50 per m3 of treated liquor. When the resin was repeatedly loaded with mixed metal cyanide species and eluted with the oxidative acid eluent, a gradual deterioration of the ion exchange resin performance was noted. The reduction of net operating capacity of the columns due to resin deterioration was in the order of 1-3% per loading/elution cycle. The oxidation of resin catalysed by copper, the precipitation of metal hexacyanoferrates on the resin and the oxidation of Au(CN)2- to Au(CN)4- were identified as possible factors giving rise to the reduction of resin loading capacity.

Thesis (M.S.)--University of Arizona, 1982. / Abstract. Includes bibliographical references (leaves 135-139). Includes bibliographical references (leaves 175-187).

Thesis (M.S.)--University of Missouri, School of Mines and Metallurgy, 1910. / The entire thesis text is included in file. Typescript. Illustrated by author. Title from title screen of thesis/dissertation PDF file (viewed March 26, 2009)

Thesis (B.S.)--University of Missouri, School of Mines and Metallurgy, 1914. / The entire thesis text is included in file. Typescript. Illustrated by authors. Title from title screen of thesis/dissertation PDF file (viewed April 9, 2009)

Thesis (Ph. D.)--University of Texas at El Paso, 2008. / Title from title screen. Vita. CD-ROM. Includes bibliographical references. Also available online.

Thesis (Ph. D.)--University of Oregon, 1999. / Vita. Includes bibliographical references (leaves 309-315).

Thesis (Ph. D.)--University of Oregon, 1999. / Typescript. Includes vita and abstract. Includes bibliographical references (leaves 309-315). Also available for download via the World Wide Web; free to University of Oregon users. Address: http://wwwlib.umi.com/cr/uoregon/fullcit?p9947972.

Thesis (M. Sc.)--University of Alberta, 2010. / Title from pdf file main screen (viewed on June 18, 2010). A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Master of Science in Microbiology and Biotechnology, Department of Biological Sciences, University of Alberta. Includes bibliographical references.

Thesis (M. Sc.)--University of Alberta, 2010. / Title from pdf file main screen (viewed on July 15, 2010). A thesis submitted to the Faculty of Graduate Studies and Research in partial fulfillment of the requirements for the degree of Master of Science in Geotechnical Engineering, Department of Civil and Environmental Engineering, University of Alberta. Includes bibliographical references.