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archives@tulane.edu / The electronic, spin, phonon and magnetic behavior govern the electrodynamics of solid materials. The different compositions and symmetries mix all the degrees of freedom leading to varieties of interesting phenomena such as metal-to-insulator transition, nonreciprocal directional dichroism and topological states. The study of the behavior of electrons, spins and phonons is crucial to reveal the physics behind the mysterious phenomena. The nature of terahertz time domain spectroscopy (THz TDS) which has low photon energy and contains phase information makes this technique very powerful to probe the physics of spins, electrons, phonons and magnons where the resonance energy is in the THz range. The multiferroic materials are studied by using THz-TDS with strong dc magnetic field. Multiferroic material is one of complex materials that simultaneously contain ferroelectricity and magnetism. Many fascinating physical phenomena are discovered in multiferroics, including magneto-dielectric effect and nonreciprocal directional dichroism. The magneto-dielectric effect, change in dielectric function in applied magnetic field, is studied in multiferroic CaBaCo4O7. We analyze the dynamics of phonons to clarify the individual phonon contribution to the magneto-dielectric effect. We observe giant nonreciprocal directional dichroism in the multiferroic material FeZnMo3O8, which is defined as the difference in absorption coefficient for linearly polarized light waves travelling in the opposite direction. A spin excitation is determined as the origin of nonreciprocal effect in the multiferroic FeZnMo3O8 by using THz-TDS. The nonreciprocal effect from magneto-chiral dichroism is also observed in BaCoSiO4 crystal where the material simultaneously possesses the chiral structure and magnetization. The polarimetry of transmitted THz light through BaCoSiO4 is carefully analyzed. We attribute the change in polarization in the zero magnetic field to the chirality of the structure. Nonlinearity of semiconductor InSb due to intense THz electric field is investigated quantitatively by using THz-TDS. The effective mass approximation breaks down when the intense THz pulse is applied to the semiconductor. We develop a predictive model that replaces the effective mass with a realistic band structure and retains the Drude parameters, the electron density and scattering rate, to accurately calculate the experimental observations (saturable absorption and amplitude-dependent refractive index) in InSb. / 1 / Shukai Yu

Thesis (Ph.D.)--University of Delaware, 2006. / Principal faculty advisor: James Kolodzey, Electrical and Computer Engineering. Includes bibliographical references.

Thesis (M.E.E.)--University of Delaware, 2006. / Principal faculty advisor: James Kolodzey, Electrical and Computer Engineering. Includes bibliographical references.

Thesis (M.S. in Physics)--Naval Postgraduate School, December 2008. / Thesis Advisor(s): Borden, Brett. "December 2008." Description based on title screen as viewed on January 29, 2009. Includes bibliographical references (p. 83-84). Also available in print.

Thesis (M.S.E.C.E.)--University of Delaware, 2007. / Principal faculty advisor: Keith W. Goossen, Dept. of Electrical and Computer Engineering. Includes bibliographical references.

Finally, based on theoretical calculations and experiments, we present a development model (DDRA model) to describe the interaction between the protein and its solvent molecule. The parameters derived from this model provide good fits to the experimentally determined complex dielectric constant, making it of the model valuable benchmarks for other theoretical treatments of bio-molecular system. / Secondly, we focus our aims on investigating protein molecules due to the possibility of being able to explain the mechanism of molecular interactions more clearly. Two lands of labeled immunoglobulin G were investigated using a reflective THz-IDS system. The dielectric properties were sensitive to the conjugation of the antibody. Additionally, terahertz spectroscopy is able to evaluate the depth of the hydrogen shell and shows that the hydrogen-bonded networks of charged protein solutions play an important role in determining the dielectric. / The bio-molecular interaction has been one of the most challenging subjects to probe due to its complexity. In the thesis, we have been attempting to answer fundamental questions about bio-molecular interactions in the terahertz (THz) region from the macroscopic to microscopic level. Terahertz radiation (defined as 0.1--10 THz) can excite intermolecular interactions such as the librational and vibrational modes. These attributes make it feasible to probe the dynamic characteristics of the bio-molecular system. Furthermore, it is worth investigating whether terahertz technology could potentially be used as a novel tool in the biomedical diagnosis field in the near future. / Thirdly, using a transmission THz-TDS system we investigated a biomarker protein and observed distinct spectral differences at various temperatures. This work demonstrates that terahertz spectroscopy can be used to evaluate the anharmonicity of the vibrational potential. By comparing the absorption spectra of the THz-TDS and Synchrotron results it is possible to deduce the approximate localization of the vibrational modes within the molecular chain. / We develop a controlled study to investigate the effects of formalin fixing on the THz properties of two different tissue types. The optical properties are measured using THz reflection spectroscopy. The results present how the fixing process can affect image contrast in THz images of biological samples. / Sun, Yiwen. / Advisers: Emma MacPherson; Yuan-ting Zhang. / Source: Dissertation Abstracts International, Volume: 73-03, Section: B, page: . / Thesis (Ph.D.)--Chinese University of Hong Kong, 2010. / Includes bibliographical references (leaves 120-140). / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Electronic reproduction. [Ann Arbor, MI] : ProQuest Information and Learning, [201-] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstract also in Chinese.

Thesis (MSc)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: Recent progress in laser and semiconductor technology has allowed for far easier generation and measuring of coherent terahertz radiation, a previously difficult region in the radiation spectrum to coherently generate. Time based terahertz spectroscopy is a rather unique form of spectroscopy. Not only is it time based, but the electric field is measured instead of the intensity. This allows for the measurement of the complex refractive index. From this one can obtain certain details of the structure and environment of the sample being studied. A terahertz time-domain spectroscopy setup was constructed during this project. This setup used low temperature grown GaAs photoconductive antennae, with multiple antenna size options available for both the receiving and transmitting antennae. After the construction and alignment of this setup, the antennae were characterized. Lastly measurements were performed on the background, sugar and silicon to demonstrate the capabilities of the system. It was found that the measured terahertz electric field amplitude increased with the intensity of the pump pulse and that the amplitude of the measured terahertz electric field was dependent on the polarization of the pump pulse. As the size of the antenna was increased so too did the amplitude of the measured electric field and conversely the bandwidth of the measured terahertz electric field decreased with the increase of antenna size. This held true for both the transmitting and receiving antennae. / AFRIKAANSE OPSOMMING: Danksê onlangse tegnologiese onwikkelings in lasers en halfgeleier het dit veel makliker geraak om terahertz straling te genereer wat fase samehangendheid toon. Voor hierdie ontwikkelings was straling in hierdie spektrale gebied moeilik om te genereer op ’n wyse wat fase samehangendheid toon. Tyd verwante terahertz spektroskopie is taamlik uniek, aangesien die metings in tyd geneem word en die elektriese veld amplitude word pleks van die intensiteit gemeet. Een van die voordele van hierdie metode is dat dit toelaat vir die meeting van die komplekse brekingsindeks van monsters. Dit is moontlik om van die komplekse brekingsindeks strukturele en omgewings eienskappe van die monster af te lei. Gedurende die projek was ’n tyd verwante terahertz spektroskopie sisteem gebou wat gebaseer was op lae temperatuur gegroeide GaAs foto-geleidende antennas. Die sisteem bevat vier antennas van verskillende groottes aan beide die sender en ontvanger kant. Die antennas was gekarakteriseer na die bou en belyning van die terahertz sisteem en meetings was gedoen op die agtergrond, suiker en silikon om die sisteem se vermoë te demonstreer. Dit was gevind dat die amplitude van die gemete terahertz elektriese veld groter geraak het soos die intensiteit van die pomp puls verhoog was en dat die die amplitude van die gemete terahertz electriese veld afhanklik was van die polarisasie van die pomp puls. Die amplitude van van die gemete terahertz elektriese veld het gegroei met die grootte van die antenna, maar hoe groter die antenna geraak het, hoe kleiner was die bandwydte van die gemete terahertz elektriese veld. Hierdie was die geval vir beide die sender en ontvanger antennas.

This thesis presents experimental results on two complex oxide systems: Cu_1-xZn_xO and La_0.7Sr_0.3MnO₃:ZnO. The dynamic magnetoelectric response of these materials is obtained using terahertz time-domain spectroscopy, supported by Fourier-transform infrared spectroscopy, Raman spectroscopy and X-ray diffraction. Evidence for an electromagnon in the multiferroic phase of CuO is presented for the first time. This high temperature (213-230K) electromagnon is linked to intersublattice exchange between two Cu sublattices. The temperature dependence of a magnon in the collinear antiferromagnetic phase is indicative of biquadratic exchange. Broadening of the multiferroic phase on substitution of copper with zinc is reported along with a 25% depression of the Néel temperature due to spin dilution. Phonons and magnons broaden and shift in energy on alloying. However, the electromagnon is relatively insensitive, increasing in energy without widening. This indicates that electromagnons and dynamic magnetoelectric coupling can be mantained even in disordered spin systems. Strong spin-phonon coupling is present in both magnetically ordered phases as shown by the anomalous behavior of the A³<sub style='position: relative; left: -.5em;'>u</sub> phonon at T_N1 and a Raman-active mode associated with a magnetic modulation of a zone-folded acoustic phonon. Dynamic 1THz magnetoresistance is found to be significantly larger than static magnetoresistance in La_0.7Sr_0.3MnO₃:ZnO vertically-aligned nanocolumns on LaAlO₃ substrates. The metal-insulator transition temperature is determined to be 300 K. Temperature dependent static and dynamic resistivity and magnetoresistance are discussed in terms of strain and grain boundary effects. Negative photoconductivity is observed and the dynamic response analysed.

In recent years Terahertz (THz) time domain spectroscopy has emerged as a promising new technology with potential applications in a variety of fields, including industrial manufacturing, security screening and medical imaging. Pulsed THz systems are uniquely suited for non-destructive evaluation (NDE) of the sub-surface layers of dielectric packaging and coating materials, because they provide high dynamic range over a wide bandwidth in the far infrared portion of the electromagnetic spectrum. Often the dielectric materials of the packaging and/or surface coating layers exhibit relatively low loss and abrupt changes in the refractive index at the layer boundaries can be observed as a train of THz pulses in A-scan data. However, many practical applications of THz NDE will require fast signal acquisition to efficiently scan and evaluate many samples. The conventional processing approach shown in much of the published work in the field of THz NDE does not perform well in low signal-to-noise ratio (SNR) conditions. In addition, many samples of interest contain thin film layers and the THz pulses reflecting from the boundaries overlap on top of one another. Thus, it is not always possible to calculate the thickness of thin films from conventional time difference of arrival (TDOA) measurements. In this dissertation physics-based signal processing methods that have been historically used for radar/sonar signal processing are adapted and applied for THz NDE of layered media. Results are demonstrated with measured data from a pulsed THz system in the Northwest Electromagnetic and Acoustics Research Laboratory (NEAR-Lab) at Portland State University (PSU). This research is expected to provide an important link for THz researchers to access and apply the robust methods that have been developed over several decades for other applications. Two key contributions of this work are: 1. Development of a matched filter approach for THz NDE of thick layered media based on the maximum likelihood estimator (MLE). 2. Development of a matched field processing (MFP) approach for THz NDE of thin-film layered media, based on techniques in the underwater acoustics literature.