Used tires have the potential for becoming popular in pollution control media used in stormwater applications including pervious pavement sub bases, green roof growth media, and upflow filters. Using tire crumb to decrease nutrients can minimize impacts on ecology while reducing the human footprint left by used tires. However, if tire crumb is not examined for toxicity, the ecological balance could unknowingly be disrupted. This research tested the acute toxicity of tire crumb in aquatic systems by finding the Lethal Concentration for 50% kill (LC50). Using an extreme tire crumb load, P. promelas (fathead minnow) were exposed to leachates created with tire crumb and several different types of water including distilled water, tap water, and detention pond water. For distilled and tap water, the addition of tire crumb increased the survival of P. promelas. For detention pond water, the addition of tire crumb decreased the survival of P. promelas, though only enough to find an LC50 for detention pond water influenced immediately by stormwater runoff. An LC50 was found when 100 percent tire crumb filtrate is prepared with 25 grams of tire crumb per liter of detention pond water collected directly after a storm. The LC50 found is resultant of a tire crumb load significantly higher than what can be expected in the environment. Based on this research, tire crumb is considered non-threatening to aquatic fish and safe to use with detention pond water.

The presence of nitrates and phosphorus in ground water is a worldwide problem. A septic tank with drainfield that is conventionally designed does not typically remove nitrogen in the form of nitrates. The main risks are in "Blue baby" syndrome and suspected carcinogenic effect of nitrates on humans and the nutrient enrichment of receiving waters. In some areas nitrate and phosphorus removal are essentially required. Thus the information in this report concentrates on using media in the drainfield for the removal of nitrogen and phosphorus. Extensive work has been conducted in the past few decades in order to find suitable media for denitrification with high selectivity towards nitrogen. Column experiments were conducted at the University of Central Florida to simulate the actual septic tank drainfield using mixes of fine sand. In one of the columns Sawdust and Tire Crumb were added to the Sand (STS) and in the other column Paper and Tire Crumb were added to the Sand (STP). Tire crumb was added as a carbon source required for better denitrification and for sorption. The columns were dosed daily using regular septic tank effluent and it was a continuous batch system. Samples were taken after a hydraulic retention time (HRT) of 24 hours and comparisons were made of the effluent with the influent to show percentage removal of nitrogen (nitrates, ammonia and total nitrogen), phosphorus (ortho-phosphorus and total phosphorus) and BOD. STS and STP columns showed more than 90% removal for all parameters (nitrates, ammonia, total nitrogen, ortho-phosphorus, total phosphorus, BOD). The results indicate that the investigated media blend (Black and GoldTM Nugget Mix) has the potential for successful application in full scale operations. It is recommended that Black and GoldTM Nugget Mix be used to achieve the required removal of the nutrients.

To maintain the quality of receiving water bodies, it is desirable to remove total phosphorus (TP) in stormwater runoff. Many media filtration technologies have been developed to achieve TP and soluble reactive phosphorus (SRP) removal. Efficient media adsorption is essential to insure control of stormwater phosphorus inputs to the receiving water body. This project develops and analyzes a functionalized Biosorption Media (BAM) to remove phosphorus species from stormwater runoff. One goal of this project is to find the BAM values for coefficients such as maximum adsorption capacity (QM: 4.35E-05) for the media through SRP isotherm equilibrium experiments using the Langmuir and Freundlich models. In addition, an upflow column experiment was also performed to study BAM nutrient removal from stormwater runoff. Finally, the information from the isotherm and the column experiments are used to estimate the life expectancy or quantity required of the media, and to define the effectiveness of BAM in phosphorus removal. The result of this study shows that BAM is a feasible stormwater treatment that can remove 60% SRP and > 40% TP at temperature between 21-23°C. The media is adequately modeled by both the Langmuir and the Freundlich models over the concentration range of interest in stormwater.

In recent years the nutrient levels of the Upper Floridan aquifer have been increasing (USGS, 2008). An example of this is found in Ocala, Florida where Silver Springs nitrate concentrations have risen from 0.5 mg/L in the 1960 s to approximately 1.0 mg/L in 2003 (Phelps, 2004). Because stormwater is a contributor to surficial and groundwater aquifer recharge, there is an increasing need for methods that decrease nitrogen and phosphorus levels. A laboratory column study was conducted to simulate a retention pond with saturated soil conditions. The objectives of the column studies reported in this thesis were to investigate the capabilities of a natural soil and soil augmentations to remove nitrogen and phosphorus for a range of concentrations at three different temperatures. An analytical attempt to model the columns through low order reaction kinetics and derive the corresponding temperature conversion constant to relate the rate constants is also presented. The Media Mixes were selected through a process of research, preliminary batch testing and then implemented in column studies. Three columns measuring three feet in length and 6 inches outer diameter were packed with a control and two media mixes. Media Mix 1 consisted of 50% fine sand, 30% tire crumb, 20% sawdust by weight and Media Mix 2 consisted of 50% fine sand, 25% sawdust, 15% tire crumb, 10% limestone by weight. The control column was packed with natural soil from Hunter s Trace retention pond located in Ocala, Florida. The reaction rates for nitrate are best modeled as first order for Media Mix 1, and zero order for the Control and Media Mix 2. The reaction rates for orthophosphate are best modeled as zero order, second order and first order for the Control, Media Mix 1, and Media Mix 2 respectively. The best overall media for both nitrate and orthophosphate removal from this study would be Media Mix 1. Media Mix 2 does have the highest average orthophosphate removal of all the mixes for all of the temperatures; however Media Mix 1 outperforms Mix 2 for the other two temperatures. The best column for Nitrate removal is the Media Mix 1 column. The temperature conversion factors for nitrate were found to be 1.11, 1.1, and 1.01 for Media Mix 1, the Control and Media Mix 2 respectively. The temperature conversion factors for orthophosphate were found to be 1.02, 0.99, and 0.95. As well as temperature conversion factors, the activation energies and frequency factors for the Arrhenius Equation were investigated. Average values corresponding to each column, species, and temperature would be inaccurate due to the large variation in calculated values.

The Florida Showcase Green Envirohome (FSGE) incorporates many green technologies. FSGE is built to meet or exceed 12 green building guidelines and obtain 8 green building certificates. The two-story 3292 ft2 home is a "Near Zero-Loss Home", "Near Zero-Energy Home", "Near Zero-Runoff Home", and "Near Zero-Maintenance Home". It is spawned from the consumer-driven necessity to build a home resistant to hurricanes, tornadoes, floods, fire, mold, termites, impacts, and even earthquakes given up to 500% increase in insurance premiums in natural disaster zones, the dwindling flexibility and coverage of insurance policies, and rising energy, water and maintenance costs (FSGE 2008). The FSGE captures its stormwater runoff from the green roof, metal roof and wood decking area and routes it to the sustainable water cistern. Graywater from the home (after being disinfected using ozone) is also routed to the sustainable water cistern. This water stored in the sustainable water cistern is used for irrigation of the green roof, ground level landscape, and for toilet flushing water. This study was done in two phases. During phase one, only stormwater runoff from the green roof, metal roof and wood decking area is routed to the sustainable water cistern. Then, during phase two, the water from the graywater system is added to the sustainable water cistern. The sustainable water cistern quality is analyzed during both phases to determine if the water is acceptable for irrigation and also if it is suitable for use as toilet flushing water. The water quality of the sustainable cistern is acceptable for irrigation. The intent of the home is to not pollute the environment, so as much nutrients as possible should be removed from the wastewater before it is discharged into the groundwater. Thus, the FSGE design is to evaluate a new on-site sewage treatment and disposal (OSTD) system which consists of a sorption media labeled as Bold and GoldTM filtration media. The Bold and GoldTM filtration media is a mixture of tire crumb and other materials. This new OSTD system has sampling ports through the system to monitor the wastewater quality as it passes through. Also, the effluent wastewater quality is compared to that of a conventional system on the campus of the University of Central Florida. The cost-benefit optimization model focused on designing a residential home which incorporated a green roof, cistern and graywater systems. This model had two forms, the base model and the grey linear model. The base model used current average cost of construction of materials and installation. The grey model used an interval for the cost of construction materials and green roof energy savings. Both models included a probabilistic term to describe the rainfall amount. The cost and energy operation of a typical Florida home was used as a case study for these models. Also, some of the parameters of the model were varied to determine their effect on the results. The modeling showed that the FSGE 4500 gallon cistern design was cost effective in providing irrigation water. Also, the green roof area could have been smaller to be cost effective, because the green roof cost is relatively much higher than the cost of a regular roof.

Scrap tyres provide numerous advantages from the viewpoint of civil engineering practices. Scrap tyres are light weight, have high vibration absorption, high elastic compressibility, high hydraulic conductivity, and temperature isolation potential. Scrap tyres have a thermal resistivity that is about seven times higher than soil; they produce low earth pressure and absorb vibrations. Many new techniques have emerged with time to utilize these advantageous characteristics for practical purposes in civil engineering. Though current reuse and recovery of scrap tyres has reduced the amount of landfills, but still there is a need for developing additional practices for the reuse of scrap tyres. Moreover, most of present practices do not use its vibration absorption capacity efficiently. To use the scrap tyres as individual material or mixed with soil in civil engineering applications, the systematic understanding of static and dynamic properties of sand-rubber mixtures (SRM) are of prime importance. In the present study an attempt has been made to characterize the SRM to use them as low-cost isolation material for low-to-medium rise buildings. Proposal of this isolation system using SRM is addressed in this study in four parts; in the first part, the estimation of shear strength and volumetric characteristics of the SRM were carried out. A total of seven different rubber sizes (six sizes of granulated rubber; 2 - 1 mm; 4.75 - 2 mm; 5.6 - 4.75 mm; 8 - 5.6 mm; 8 - 9.5 mm; 12.5 - 9.5 mm and one size of tyre chips; 20 - 12.5 mm) were considered for characterizing the SRM, and the rubber size which has higher shear strength characteristics is identified as optimum size for further studies. Second part deals with the effect of reinforcement on SRM with higher rubber content (50% and 75% rubber by volume). In the third part, dynamic properties of selected SRM combination with and without reinforcement were generated from experimental studies. In the last part, the numerical analysis was carried out using finite element program Strand7 to find out optimum dimension of proposed isolation scheme and reduction of spectral accelerations. In addition, the laboratory model tests were also carried out on square footing supported on unreinforced and reinforced SRM. The relative performances of reinforcement on settlement characteristics of SRM for 50% and 75% SRM have been compared with unreinforced SRM. Engineering behaviour of SRM has been studied by considering different rubber sizes and compositions by carrying out large scale direct shear test and Unconsolidated Undrained (UU) triaxial test. The shear strength characteristics such as peak shear stress, cohesion, friction angle, secant/elastic modulus, volumetric strain, failure and ultimate strength, ductility/brittleness index, and energy absorption capacity of sand and SRM were determined. The optimum percentage rubber content based on maximum shear strength and energy absorption capacity has been arrived. The granulated rubber size (12.5 - 9.5 mm) and percentage ratio, 30% by volume is found to be optimum size and content, which gives the maximum energy absorption capacity and lower brittleness index values compared to other rubber sizes. This chapter also describes the applicability of concept of Response Surface Methodology (RSM) to identify an approximate response surface model from experimental investigations on the engineering properties of sand and SRM. The experimental data were quantitatively analyzed by multiple regression models by correlating response variables with input variables in this study. To consume more tyres in SRM, rubber mix of 50 % and 75 % mixes are studied and these SRM results in lower shear strength and higher volume change when compared to 30 % SRM. To improve shear strength and reduce compressibility, geosynthetic reinforcement study has been carried out for 50% and 75% rubber by volume. Here geotextile, geogrid and geonets were used as reinforcement and number of layers and spacing between layers were varied. Finally type of reinforcement, number of layers and optimum spacing are arrived for the optimum rubber size of 12.5 - 9.5 mm for reinforced SRM. This study found that 4 layers with equal spacing of geotextile for 50 % SRM and geonet for 75 % SRM shows better strength when compared to other combinations. Further dynamic properties such as shear modulus and damping values at different strain level are estimated for red soil, sand, 30 % SRM and unreinforced and reinforced 50 % and 75 % SRM by carrying out resonant column tests and cyclic triaxial tests. The normalized shear modulus and damping ratio curves have been developed for these materials. The experimental results indicate that, shear modulus increases for 30% rubber by volume when compared to sand, thereafter the shear modulus values decreased with a further increase in rubber content in SRM. Whereas the damping ratio increases with increasing rubber content in SRM. For sand and SRM, with an increase in confining pressure shear modulus increases and damping ratio decreases. Based on the comprehensive set of experimental results, a modified hyperbolic model has been proposed. These properties are further used in the numerical analysis to find out the effectiveness of SRM as isolation material. Numerical dynamic analysis has been carried out on a 2-D finite element model of the soil-foundation-structure system. The building model has been generated considering the typical G+2 building resting on 20 m thick soil followed by rock depth and foundation is placed at 2.0 m below ground level. The beams and columns in the superstructure are modeled using 2-D frame elements. The soil column has been modeled using 4-noded 2-D plane strain plate elements. Considering the transmitting boundary condition, viscous dampers are implemented at the base of the computational soil domain in order to mitigate the reflective effects of waves. The Newmark family method (average acceleration method) has been used to calculate the displacement, velocity and acceleration vectors. Comprehensive numerical simulations have been carried out on the soil-foundation-structure system by varying rubber content in SRM (30%, 50% and 75% granulated rubber by volume), depth and thickness of SRM around footing and considering two input earthquake acceleration time history. It was found that earthquake vibrations are considerably reduced for SRM with higher rubber content. The optimum dimension of SRM giving maximum reduction in shaking level is found to be 3B below the footing and 0.75B (where B is the width of footing) on the side of the footing. Generally, the shaking levels at different floor can be reduced by 30-50%, with the use of 75% SRM. The results also indicated that the effectiveness of proposed system would depend on the characteristics of ground motion. To study the bearing capacity of square footing on SRM, laboratory model tests were carried out on square footing supported on unreinforced and reinforced SRM. The SRM combination which have been used for numerical studies are used in this model studies to know the bearing capacity and settlement characteristics. The optimum dimension of SRM around footing has been constructed. Model tests results show that, the bearing capacity decreases and settlement increases steadily with the increase in rubber content in SRM. Addition of reinforcement to SRM significantly improved the bearing capacity and reduced settlement characteristics. Reinforced SRM may be used as an effective low cost isolation scheme to reduce earthquake vibrations.