The aim of this study was to investigate synthesis of lithium borides by mechanochemical synthesis from oxides. Lithium borides have promising properties in the area of high energy additives and hydrogen storage. Lithium oxide (Li2O), boron oxide (B2O3) and Mg were used to synthesize lithium borides. Experiments were conducted in a planetary ball mill under argon atmosphere. Analyses of the products were done by X-ray diffraction and scanning electron microscopy. Trilithium tetradecaboride (Li3B14) peaks were observed in the product powder. Removal of other phases that were formed during experiments was done by leaching in HCl/water solution. Leaching in 0.5 M HCl/water solution for 10 minutes was found to be sufficient to remove / iron (Fe) and magnesium oxide (MgO). Effects of ball milling parameters such as milling speed, ball to powder ratio, milling duration were investigated and milling for 20 hours with 300 rpm and 30:1 ball to powder ratio was found to be the optimum conditions. Syntheses of other lithium borides (LiB4, Li2B6, LiB13) were also experimented with the same milling parameters. Formation of LiB4, Li2B6 and LiB13 was not observed in the product powders. However, the results of LiB4 and LiB13 production experiments showed also Li3B14 peaks in the product. Li2B6 synthesis experiments resulted in Li2B9 peaks in the product powders.

Transportation cost is an important item in total operating cost of an open pit mining operations. In some projects, the transportation cost may reach to 60 % of total operating cost. Turkish Coal Enterprises (TKi) delivers the demanded coal to all cities of Turkey within the context of Prime Ministry Social Solidarity and Aid Fund. The project duration, demanded coal amount whether the coal is needed as packed or unpacked form are determined by local governors. In this study, a model is developed through software, called NAKMAL for the estimation of TKi&rsquo / s coal transportation cost. Transportation cost model is coded using Visual Studio.NET 2005. This model is designed in modular structure and composed of 19 modules. Excavation and transportation in a mine is an important part of the model. Model considers all the highway, railway and transportation by ship alternatives, as well as the packing operation. This model is being used in evaluation of bids by the decision of TKi&rsquo / s board of executive committee.

High Pressure Torsion (HPT) is one of the most widely used severe plastic deformation methods which enable to obtain a crack free ultra-fine grained bulk material with improved mechanical properties like increased strength and toughness. In the process, a disc shaped sample is pressed between two anvils and deformed via surface friction forces by rotating one of the anvils. The aim of this study is to nondestructively characterize the variations in the deformation uniformity of the severely deformed steel disks. Two sets of low carbon steel samples were obtained by applying the unconstrained and constrained HPT process up to 6 turns. Magnetic Barkhausen Noise (MBN) method was used in order to evaluate the samples in a nondestructive manner via a commercial device. The results of the MBN measurements were verified with those of conventional methods such as / x-ray diffraction (XRD), metallographic examination and hardness measurements. The initial stages of HPT revealed the effects of conventional plastic deformation on MBN / however with further straining, grain size refinement prevailed and caused increase in MBN signals.

The aim of this study was to produce partially reinforced aluminum metal matrix composite components by insertion casting technique and to determine the effects of silicon content, fiber vol% and infiltration temperature on the mechanical properties of inserts, which were the local reinforcement parts of the components. Silicon content of alloys was selected as 7 wt% and 10 wt%. The reinforcement material, i.e. Saffil fiber preforms, had three different fiber vol% of 20, 25 and 30 vol% respectively. The infiltration temperatures of composite specimens were fixed as 750 &deg / C and 800 &deg / C. In the first part of the thesis, physical and mechanical properties of composite specimens were determined according to the parameters of silicon content of the matrix alloy, infiltration temperature and vol% of the reinforcement phase. X-ray diffraction examination of fibers resulted as the fibers mainly composed of deltaalumina fibers and scanning electron microscopy analyses showed that fibers had planar isotropic condition for infiltration. Microstructural examination of composite specimens showed that appropriate fiber/matrix interface was created together with small amount of micro-porosities. Bending tests of the composites showed that as fiber vol% increases flexural strength of the composite increases. The highest strength obtained was 880.52 MPa from AlSi10Mg0.8 matrix alloy reinforced with 30 vol% Saffil fibers and infiltrated at 750 &deg / C. Hardness values were also increased by addition of Saffil fibers and the highest value was obtained as 191 HB from vertical to the fiber orientation of AlSi10Mg0.8 matrix alloy reinforced with 30 vol% Saffil fibers. Density measurement revealed that microporosities existed in the microstructure and the highest difference between the theoretical values and experimental values were observed in the composites of 30 vol% Saffil fiber reinforced ones for both AlSi7Mg0.8 and AlSi10Mg0.8 matrix alloys. In the second part of the experiments, insertion casting operation was performed. At casting temperature of 750 &deg / C, a good interface/component interface was obtained. Image analyses were also showed that there had been no significant fiber damage between the insert and the component.

Increasing use of aluminum alloys in the automotive industry increases the importance of the production of sheet aluminum. To provide cost effective sheet aluminum to the industry, twin-roll casting (TRC) is becoming more important compared to DC casting. Demand for usage of different aluminum alloys in sheet form introduces some difficulties that should be considered during their applications. The main problem encountered during the welding of aluminum alloys is hot cracking. The aim of this study is to understand the difference in hot cracking susceptibility of two twin roll cast (TRC) aluminum-magnesium alloys (5754 and 5049 alloys) during welding. Varestraint test method was used to evaluate the effect of welding parameters, strain levels, filler alloys and mid-plane segregation on hot cracking susceptibilities. Hot cracking susceptibility of both 5049(Al-2wt%Mg) and 5754(Al-3wt%Mg) alloys increased with increasing strain level. Also, it was observed that hot cracking susceptibility was higher for the alloy having higher magnesium content. Thermal analysis results verified that hot cracking susceptibility indeed can be related to the v solidification range. As is suggested in the solidification range approach, the results of the present study confirm that the extent of solidification and liquation cracking depend on the magnitude of solidification range and the strain imposed during welding. Hot cracking susceptibility of 5754(Al-3wt%Mg) alloy has shown slightly decreasing behavior with addition of 5356 filler alloy. On the other hand, addition of 5183 filler alloy has increased solidification cracking susceptibility of two base alloys. The fracture surfaces of liquation and solidification cracks were investigated by scanning electron microscope with EDS. Liquation crack surfaces of the 5754(Al-3wt%Mg) alloy were found to have high Mg and Si content. For the 5754(Al-3wt%Mg) alloy, a quench test was designed to observe the effect of mid-plane segregation zone. It was observed that there was a eutectic reaction resulting in formation of liquid phase below solidus temperature of 5754(Al-3wt%Mg) alloy. Moreover, internal cracks have formed at the mid-plane segregation zone after Varestraint test. Results show that 5049(Al-2wt%Mg) alloy should be chosen compared to 5754(Al-3wt%Mg) alloy for welding. Moreover, low line energy should be applied and filler alloys with high magnesium content should be used during welding to decrease hot cracking tendency of welds.

The Germencik Omerbeyli geothermal field is considered to be one of the most important geothermal fields in Turkey. A numerical modeling study was carried out to simulate the response of the field to different production/injection scenarios. The reservoir performance evaluation was based on the numerical simulation of the reservoir behavior using the simulation code TOUGH2. The numerical simulation model includes a total area of 85.8 km2 and extends from the surface at +330 m msl (mean sea level) to a depth of -4581 m msl. Through a trial and error process, the natural state model was satisfactorily matched with the initial temperature and pressure data measured at the wells. The natural state model was further calibrated using the long term flow test (LTFT) data conducted in 2006, including OB-6 and OB-9 as flowing wells and OB-8 as an injection well. The model was then used to predict reservoir performance under different production/injection scenarios over the next 30 years. Forecast runs showed that the pressure declines almost equally in all areas, consistent with the high permeability and connectivity of the reservoir, which had been established from the LTFT.

Asphaltite is petroleum originated substance and formed by metamorphism. Turkey has 82 million tons of asphaltite reserves in Sirnak and Silopi region of Southeastern part of Anatolia. The proximate analysis of Sirnak Karatepe asphaltite sample indicated that the ash and sulfur content were 46.86 % and 5.56 %, respectively. In this study, Sirnak Karatepe asphaltite sample was concentrated by gravity separation and flotation methods. The aim of this research was to decrease the ash and sulfur content below 20% and 2%, respectively, which are the requirements of Sirnak Municipality. Gravity based cleaning equipments such as multi gravity separator, shaking table and Falcon concentrator gave no satisfactory results in terms of ash and sulfur removal. The products with lowest ash content were obtained with Falcon concentrator after two stage cleaning of -100 micrometer feed. Flotation parameters of Karatepe asphaltite were also examined during the study. As a result of multi-stage flotation with stage addition of Collector Accoal 9630 and depressant Na2SiO3 , ash content of asphaltite was decreased to 17.59 % with 15.31 % combustible recovery. Even though the ash content specification met by flotation, the sulfur content of cleaned asphaltite (6.68 % S) was more than the sulfur limit of Sirnak Municipality.

In this study, residual stresses introduced via application of shot peening on the raceways of bearing rings and their effect on the fatigue life was investigated experimentally. For improvement of residual compressive stress state, shot peening operation with different parameters was utilized. Residual stress measurements were conducted via X-ray diffraction technique. Optimization of residual stress state during the production of ball bearings is the main target of this study. Process parameters for shot peening and super-finishing were studied for determination of the parameters that induce the most favorable residual stress state. The fatigue life of ball bearings were determined by life cycle tests and tabulated to show the results of the study. The results of the thesis are believed to help for optimization of residual stress distribution and improvement of service life of ball bearings.

ABSTRACT PRODUCTION OF HEAVY-MEDIA-QUALITY MAGNETITE CONCENTRATE FROM KESiKK&Ouml / PR&Uuml / IRON ORE TAILINGS G&uuml / ng&ouml / r, Kazim M. Sc. Department of Mining Engineering Supervisor: Prof. Dr. M. &Uuml / mit Atalay May 2010, 91 pages The aim of this research was to investigate the possibility of the production of a magnetite concentrate which is suitable for preparation of heavy media from iron ore tailings of G&uuml / ncem Mining Company magnetic separation facility. During the study, three different tailings named as low grade, medium grade and high grade with 5.91 % Fe3O4, 19.06 % Fe3O4 and 37.06 % Fe3O4, respectively, were used. Mineralogical analyses of test samples showed that magnetite and hematite were the major ore minerals while pyrite and chalcopyrite were found in trace amounts. Actimolite, tremolite, epidote, chlorite, quartz, calcite, and dolomite were the gangue minerals. The effects of feed particle size and applied magnetic field intensity on the Fe3O4 grade and recovery of concentrate were examined throughout magnetic concentration tests. The highest grade magnetite concentrate with 79.98% Fe3O4 content was obtained with 65.42% recovery from 100% -75 micron size feed at 1000 Gauss magnetic field intensity from high grade tailing.

Shot peening is a cold-working process by which residual compressive stresses are being induced in the surface region to increase the fatigue strength and the resistance to stress-corrosion cracking. This study covers non-destructive measurement of surface residual stresses in the shot-peened steel components by a micro-magnetic technique, named as Magnetic Barkhausen Noise (MBN) method. For this purpose, various low alloy steel specimens were prepared by a controlled shot peening process with different intensity, impact angle and coverage values. The measurements showed that a clear relationship exists between residual stresses and the MBN signals. Residual stress values determined by MBN technique were also verified by X-ray diffraction measurements.