京都大学 / 新制・課程博士 / 博士(理学) / 甲第24124号 / 理博第4852号 / 新制||理||1694(附属図書館) / 京都大学大学院理学研究科地球惑星科学専攻 / (主査)教授 竹見 哲也, 教授 榎本 剛, 准教授 重 尚一 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

Cold spray (CS) deposition of metals is a process involving deposition of materials in the solid or semi-solid state. It also has lower operating temperatures, and oxidation is greatly reduced in the process. The process is beneficial for refractory metals, such as tantalum, which are tough and difficult to machine. The interface between the CS powder and the substrate is the most important region for the study of mechanical properties as it is where the bonding process occurs first; studying mechanical properties at the nanoscale will give us a better idea of the mechanical properties of the coated surface. The present work investigates multiple-sprayed conventional and low-hydrogen treated tantalum powders on stainless steel substrates and also single-sprayed nitrogen-treated tantalum powders on aluminum substrate using Atomic force microscopy (AFM). It also discusses the effects of topography on the local changes in modulus. AFM is an instrument that measures the site-specific property of the sample. In this work, the local Young's modulus is studied using force-distance curves. Calibration of the AFM cantilever and the photodetector used to measure the cantilever, is a vital step before the actual process. The conventional method of calibration can cause damage to the tip as it arbitrarily penetrates into the sample creating a cantilever deflection vs. tip penetration curve, giving the sensitivity of the photodetector. AFM is highly dependent on topographical features as the cantilever tip-sample interaction can vary, causing variations in the property mapped. This work, however uses a non-contact method of calibration which saves the cantilever tip from potential damages, saving the results from the detrimental effects of tip topography. The work also discusses the effects of local sample deformation and volume of tip-surface contact on local changes in Young's modulus at the interface of coating and substrate. This work uses Electron micro-probe analysis (EPMA) to show the presence of oxides at the interface. The presence of oxides changes the bond energy as compared to a pure tantalum bond, ultimately affecting the local modulus mapped using AFM. The effect of oxides on the local modulus at the coating-substrate interface is theoretically discussed.

Aim; This study looks at the effect of orthokeratology on a number of biometric parameters and refractive error in an adult population. Method; Forty three myopic subjects were recruited to a twelve month study into the effects of orthokeratology on ocular biometry and refractive error. Two different back surface lens designs were applied right eye) pentacurve and left eye) aspheric. The aspheric design was chosen to more closely mimic the cornea¿s natural shape. Anterior and posterior apical radii and p-values; corneal thickness and anterior chamber depth were measured using the Orbscan IIz; together with ocular biometry by IOL Master and a standard clinical refraction. All measurements were repeated at one night, one week, one, three, six and twelve months. Refractive changes were analysed against biometric changes. Results; Twenty seven participants completed one month of lens wear. Twelve subjects completed twelve months of lens wear. Subjects with myopia ¿ -4.00DS were successfully treated with orthokeratology. Both anterior and posterior apical radii and p values were altered by orthokeratology. Corneal thickness changes were in agreement with previously published studies. Axial length and anterior chamber depth were unaffected by the treatment. Conclusion; Orthokeratology should be available as an alternative to laser refractive surgery. It is best restricted to myopes of up to -4.00DS with low levels of with the rule corneal astigmatism. The use of an aspheric back design contact lens did not produce a significant benefit over that of a pentacurve.

<p> Using gold as seed particles, the vapour-liquid-solid (VLS) growth of GaAs nanowires by molecular beam epitaxy on GaAs (100) substrates was investigated with a view to understanding and controlling the growth directions of nanowires. The crystallographic orientation as well as surface density of nanowires was found to be significantly affected by surface topography resulting from surface preparation prior to nanowire growth. Elongated pits of varying dimensions and orientation were formed on GaAs (100) substrates depending on the interaction of GaAs with gold or surface oxide. An in-depth analysis was carried out regarding the formation of pits as well as chemical composition of the oxide layer during the seed particle formation process. </p> <p> By analyzing the orientation-dependent structural properties of nanowires at different stages of growth, the origin of multi-directionality of nanowires on GaAs (100) substrates has been explored, and it has been shown that the growth directionality of nanowires can be significantly triggered to either the <011> or <111> direction by optimizing the growth rate as well as size of seed particles. Crystallographic properties of nanowires have also been discussed with reference to their growth directions.</p> / Thesis / Doctor of Philosophy (PhD)

The Mississippi Sound is underlain by late Pleistocene aged sediments of the Biloxi, Prairie, and Gulfport Formations topped by an erosional unconformity, which was an exposed land surface during the sea level low-stand of the last glacial maximum. During that period, rivers and streams draining upland watersheds cut across the exposed coastal plain incising a network of distributary fluvial channels. Subsequent sea level rise covered the incised drainage network with a relatively thin (10-20 m) layer of reworked Holocene aged sediments. Here, an extensive database of archived and newly collected seismic reflection profile data, as well as archived core data, is analyzed to map the paleotopography and the paleo-drainage network of the Pleistocene-Holocene unconformity surface beneath the western Mississippi Sound. Approximately 255 km of seismic data was acquired with a 2-16 kHz chirp sub-bottom profiling sonar. Additionally, 978 km of seismic data was accessed through a United States Geological Survey archive along with over 20 historical cores. Results indicate that the Pleistocene-Holocene unconformity under the western Mississippi Sound is gently dipping to the southeast (<0.05°) and contains a complex network of incised paleofluvial channels with relief ranging from 5-10 m and widths ranging from 0.3–2 km. A conceptual model for paleo-channel incision and infilling as well as modern analogue depositional environments are presented.

Droplet evaporation and condensation are two important topics of interest, since these two phase-change phenomena not only occur in the cycle of global water, e.g., the formation of rain, fog, dew, and snow in nature, but also play a critical role in a variety of applications including phase-change heat transfer enhancement, surface chemistry and energy system optimization. Especially, in the past two decades, the rapid development of the nature-inspired non-wetting surfaces has promoted the applications of droplet-based phase change phenomena in various scenarios. However, most previous studies focused on the sessile droplets on one flat surface in the open space, and the effects of surface topography, i.e., surface curvature or configurations, on droplet evaporation and dropwise condensation are still elusive. This dissertation aims to explore droplet-based evaporation and condensation in more complex spaces and to elucidate how the surface topography affects the evaporating or coalescing droplet dynamics during these phase-change processes. The coalescence-induced jumping of nanodroplet on curved superhydrophobic surface is modeled via molecular dynamic simulations. As the surface curvature increases from 0 to 2, the corresponding energy conversion efficiency of jumping droplet during the coalescence process could be significantly improved about 20 times. To explain this curvature-enhanced jumping effect, the contact line dissipation, i.e., an important source of energy dissipation in nanoscale, is considered in our scaling energy analysis. And this energy-effective jumping of coalesced droplet could be mainly attributed to the reduction of contact line dissipation due to the decrease of contact line length and contact time on curved surface. As the droplets are confined between two parallel or non-parallel low-energy surfaces, i.e., hydrophobic or superhydrophobic surfaces, with a narrow gap, the total evaporation time of the squeezed droplets would be dramatically prolonged about two times. An ellipsoidal segment diffusion-driven model is established to successfully predict the evolution of contact radius and volume of the squeezed droplets during the evaporation process and to clarify it is the vapor enrichment inside the confined space giving rise to the mitigated evaporation. If two hydrophobic surfaces are configured as non-parallel, the confined droplet inside the V-shaped grooves would be self-transported towards the cusp/corner during the evaporation. Based on our energy and force analyses, the asymmetrically confined droplet would move towards an equilibrium location le, where the Laplace pressure induced force is balanced with normal adhesion force, to minimize its Gibbs surface energy. As le decreases during the evaporation, this equilibrium location would directionally shift towards the cusp, which could be regarded as the origin of this evaporation-triggered unidirectional motion. For the first time, the solvent transport and colloidal extraction could be accurately controlled in a combined manner. / Doctor of Philosophy / Droplet evaporation and condensation are two important topics of interest, since these two phase-change phenomena not only occur in the global cycle of water including the formation of rain, fog, dew, and snow in nature, but also play a critical role in a variety of applications including heat transfer enhancement, surface chemistry, and the energy system optimization. Generally, the droplets in these scenarios are deposited on one flat surface opened to the atmosphere. and the effects of surface topography on droplet evaporation and dropwise condensation are still elusive. This dissertation aims to explore droplet-based evaporation and condensation in more complex spaces and to clarify how the surface curvature or configurations affects evaporating or condensing droplet dynamics accompanying these phase change processes. As the coalesced droplet jumps off the curved superhydrophobic surfaces during dropwise condensation, the corresponding energy conversion efficiency would be significantly improved about 20 times due to the increases of curvature. It is demonstrated that the decrease of contact line length and contact time would give rise to the reduction of contact line dissipation, which should be the main factor driving this energy-effective jumping of the coalesced droplets. As the droplets are confined between two parallel or non-parallel low-energy surfaces, i.e., hydrophobic or superhydrophobic surfaces, with a narrow gap, the total evaporation time of the squeezed droplets would be dramatically prolonged about two times in the small space. An ellipsoidal segment diffusion-driven model is established to successfully predict the evolution of contact radius and volume of the squeezed droplets during the evaporation and to clarify it is the vapor enrichment in the confined space giving rise to the mitigated evaporation. If two hydrophobic surfaces are configured as non-parallel, the confined droplet inside the V-shaped grooves would be self-transported towards the cusp/corner of the structure during evaporation. Based on our energy and force analyses, the asymmetrically confined droplet would move towards an equilibrium location le, where the Laplace pressure induced force is balanced with normal adhesion force, to minimize its Gibbs surface energy. As le decreases in the scale of during the evaporation, this equilibrium location would directionally shift towards the cusp, which could be regarded as the origin of this evaporation-triggered unidirectional motion.

Geomorphologists have long observed the influence of lithology on landscape form and evolution. However, the specific mechanisms by which this is accomplished are not well characterized. Here, I investigate the role of lithology in landscape evolution processes across spatial and temporal scales and geomorphic domains, to progress our understanding of the basic controls on the processes which shape Earth's surface. These investigations were carried out within the Valley and Ridge province of the Appalachian Mountains, where contrasts in strength of underlying lithologies (juxtaposed by Alleghanian deformation) exert a clear, dominant control on the fabric of the landscape, providing an excellent opportunity to study the influence of lithology on a variety of landscape evolution processes. First, I assess the geomorphic function of boulders found on hillslopes and channels in the Valley and Ridge province of the Appalachians, which are sourced from resistant lithologies capping ridgelines. High-resolution UAV surveys and field mapping of boulder distributions and characteristics reveal that boulders are abundant on hillslopes and highly concentrated in channels, often trap sediment upslope, and appear to be long-lived. These observations suggest that boulders act as armor for hillslopes and channels, shielding weaker underlying units from erosion and inhibiting fluvial incision, and therefore play an important role in preserving topography in the Valley and Ridge landscape, highlighting a specific mechanism by which lithology exerts an influence on topography in this setting. Second, I investigate the relative importance of rock strength and discontinuity spacing in setting fluvial bedrock erodibility by comparing knickpoint and non-knickpoint bedrock, which correspond to end-member erodibility cases, and assess how lithology impacts knickpoint expression. Detailed field surveys of 21 lithologic knickpoints, surrounding non-knickpoint reaches, and corresponding bedrock properties reveal three key outcomes: 1) discontinuity spacing is a stronger predictor of knickpoint occurrence, and therefore more significant in setting bedrock erodibility in this setting, confirming quantitatively the hypothesis that discontinuities exert a dominant control on fluvial erodibility, 2) knickpoint expression is a function of the unique combination of characteristics within a given stratigraphic interval, and therefore highly complex and specific to local conditions, implying that knickpoint morphology should be interpreted with extreme caution, and 3) because all 21 study knickpoints occur within the same unit, inter-unit heterogeneity must be accounted for before lithologic influence on channel profile convexities can be ruled out, rather than comparing to geologic map contacts. These findings represent an important contribution towards a more functional understanding of the influence of lithology on fluvial bedrock incision processes. / Doctor of Philosophy / It has long been observed that underlying geology has a strong impact on the shape of the surrounding landscape and influences the erosional processes that act within that landscape. However, though the importance of rock type in shaping landscapes is recognized, the specific mechanisms by which this is accomplished are not well understood. The work presented here investigates the role of rock type and rock properties in landscape evolution processes in both hillslope and river environments within the Valley and Ridge Province of the Appalachian Mountains. This setting is ideally suited for investigating the role of rock type on landscape evolution processes because of the wide variation in rock types present in this setting, which exert a strong influence on local topography (e.g., strong rocks form ridges while weak rocks underlie valleys). First, I mapped the distribution of large boulders on local Valley and Ridge slopes and mountain streams to assess the potential for these boulders to play a role in preserving local topography. Results show that boulders are sourced from resistant rock types found along ridgelines, and are abundant on hillslopes and highly concentrated in channels. Boulders also trap sediment upslope and appear to remain in place for long periods of time. These observations suggest boulders play an important role in slowing erosion of weaker rock types underlying hillslopes and channels, and therefore aid in preserving topography in this setting. Second, I conducted detailed surveys of local small-scale waterfalls and surrounding flat river reaches and compared properties of the bedrock between these locations to better understand how bedrock properties influence erodibility. In this setting, waterfalls often signify strong underlying bedrock relative to the rock beneath flat river reaches, so comparing bedrock properties between these areas should give insight into how properties like rock strength and bed thickness impact how erodible the bedrock is. Results show that bed thickness is the most important variable impacting bedrock erodibility in this setting, and that waterfall appearance is a product of the unique combination of bedrock properties within a given area. These results are important for improving our ability to model natural landscapes and erosional processes, and for developing a more complete understanding for the relationships between rock type and river morphology.

This thesis investigates how architecture engages with the natural landscape through iterative designs of exhibition space. Proposals of architecture adjacent to Smith Mountain Lake as well as along the Cascade Falls Trail in Virginia were considered. The design proposals led to a resolution that particular considerations are critical in relating architecture and nature, specifically a building's spatial organization and orientation, its materiality and tectonic assembly, and the bounding thresholds differentiating between inside and outside. / Master of Architecture / The central idea of my exploration is to engage with nature and create a building that relates to the Virginian landscape consisting of mountain, forest and water. The design exploration began with a site at Smith Mountain Lake and then a site at Cascade Falls Trail. To make the architecture, many aspects were considered - how to place the architecture in the landscape, the choice of the building's materials, how the building is constructed, the use of walls versus windows, and finally, not only creating a relationship between architecture and landscape, but also determining nuanced ways to connect the two.

Anterior cruciate ligament (ACL) ruptures and tears are significant orthopedic problems that result in discomfort and limited mobility. Fully functional tissue engineered ligament replacements are promising alternatives to current graft choices for repair of ACL disruptions. The cell-based approach to construct engineered ligament grafts presented herein involves the culture of mesenchymal stem cells (MSC) on biodegradable, fibrous polymeric scaffolds to promote tissue formation. Multipotent MSCs are advantageous because of their in vitro proliferative capacity and ease of harvest; however; the promotion of MSC differentiation into mature fibroblasts and subsequent extracellular matrix (ECM) development is unknown. The proposed studies utilized three complementary methods to promote differentiation of MSCs: scaffold architecture, mechanical stretch and over-expression of the transcription factor, scleraxis. First, elastomeric scaffolds were fabricated by electrospinning a segmented poly(esterurethane urea) with variations in fiber diameter and fiber alignment. Primary mesenchymal stem cells and the mesenchymal stem cell line, C3H10T1/2, were seeded on these scaffolds and assumed spindle-shaped morphologies and oriented with the direction of fiber alignment. Fiber diameter affected cellular responses, including the expression of ECM genes (e.g. collagen type 1 and decorin) which were elevated on smaller mean fiber diameter scaffolds initially. However, scleraxis gene expression was greatest on larger mean fiber diameter scaffolds at the end of two weeks. Second, cyclic stretch was applied to C3H10T1/2 cells on semi-aligned scaffolds using a novel bioreactor. Cell attachment was verified during and after the application of mechanical stress by confocal microscopy. Cyclic stretch induced cells to assume a highly elongated morphology; however ECM gene expression changes were moderate. Third, forced constitutive expression of scleraxis was accomplished by nucleofection of C3H10T1/2 cells. Transient mRNA expression, accumulation of the gene product in the cell nucleus, and cell death were observed. Future work will seek to refine the experimental methods, including the development and testing of an inducible scleraxis transgene and the application of longer periods of mechanical stimulation. Finally, these complementary approaches may be combined to further extend this work in pursuit of directed differentiation of stem cells and the ensuing generation of a robust tissue graft. / Ph. D.

Atmospheric dust is the largest contributor to global aerosols from land. Dust emissions rate and properties are influenced by meteorological conditions, parent soil, and landscape, and in turn, it affects impacts on climate, ecosystems, and human societies through various pathways. This dissertation aims to explore the coupled dynamics of dust particle emissions and their essential properties in relation to topography, ecosystem, and atmospheric conditions by integrating information across multiple scales. Specifically, three research projects are pursued. First, the modulation of dust emissions by non-photosynthetic vegetation (NPV) is evaluated by implementing a satellite-based total vegetation dataset, which includes NPV, into a regional atmospheric chemistry model. Simulations of the entire year 2016 over the conterminous United States demonstrate that NPV reduces dust emissions by 10-70% from most dust sources in the southwest, particularly in spring. Second, the relationship between topographic wind conditions (i.e., speed and direction with respect to surface slope) and dust particle size distribution is investigated using a decade's worth of dust reanalysis data covering North Africa. Findings indicate that the fraction of coarse dust in emissions increases with wind speed and slope, particularly under uphill winds, the latter highlighting the role of topography in enhancing vertical transport for larger particles. These positive correlations weaken during the afternoon and summer events, suggesting that turbulence associated with haboob events suspends coarse particles. Finally, a series of air samples collected in Tenerife, Spain is revisited for a detailed study on the associated dust plume characteristics, which would facilitate the understanding of how environmental factors during transport influence airborne microbial assemblages. Using back trajectory analysis and dust optical depth reanalysis data, air samples impacted by African dust are identified. Seasonal variations in trajectories and associated environmental conditions reveal highly variable trans-Atlantic airflows. Elevated altitudes, higher temperatures, and lower relative humidity (RH) along summer trajectories implied the presence of Saharan Air Layer, whereas the frequent occurrence of higher RH (> 40%) and light precipitation in spring indicate more deposition of dust and associated microbes during transport. Overall, this work highlights the importance of accurately representing of various environmental elements that interact with the dust cycle, such as vegetation and topographic winds, which improves our ability to predict and manage the impacts of dust as well as other components of the Earth system. / Doctor of Philosophy / Dust particles can be lifted by strong winds from dry lands, and they are a major contributor to the amount of particles in the air. Suspended dust particles can alter temperatures and weather patterns, reduce visibility, and cause health problems. When settling back to land or oceans, they can carry nutrients and microbes that influence the growth of plants and animals. The movement and properties of dust are subject to various elements of the environment, spanning from microscopic scale to global scale. This dissertation aims to explore the interactions between dust and a few of these environmental elements that are not well understood. Specifically, we first provide information about brown vegetation, which was previously lacking, to a dust model, and find that the dust emissions in the southwestern United States is reduced by 10-70%, particularly in spring. Second, we examine how the changes of wind over slopes influence the size of dust particles in the air by analyzing data for 10 years that combine information from models and satellite observations. We find that faster winds and uphill slopes lead to more large dust particles in the atmosphere. The third study analyzes the pathways of air samples from Africa to Tenerife, Spain, to understand how the transport of dust might affect the types of bacteria that travel with it across the ocean. We find that the airflows from Africa to Tenerife vary greatly from case to case, and the environmental conditions, such as precipitation and relative humidity, varying significantly across seasons and during the dust travel. Overall, this dissertation provides a deeper understanding of the complex ways dust interacts with our world, offering insights that can help us manage its impacts on climate, ecosystems, and human society more effectively.