This master thesis describes the co-firing concept, benefits and opportunities of pretreated biomass in pulverized coal boilers for industrial use. Burning fossil fuels, i.e. coal is under immense political pressure as European Union (EU) and other countries are trying to bring down the CO2 emission. Biomass combustion is already a proven technology and it plays a greater role in reducing CO2 emission. The main objective of this thesis is the brief study of computational fluid dynamics (CFD) modelling to examine the co-firing of greater amount of pretreated biomass and pulverized coal in a 200MWe pulverized coal boiler. Here, we exchange around 50 % of existing fuel in pulverized coal boiler with torrefied biomass. Torrefied biomass aids to increase the efficiency of existing coal boiler and cut down the CO2 emission. In this work, two cases of co-firing of pretreated biomass and coal have been investigated by CFD. Firstly, an experimental work was done in a laboratory scale to have few different types of torrefied biomass with different degrees of torrefaction. The devolatilization kinetics and char oxidation kinetics were also determined by experiments and other parameters have been calculated. One important aspect of this work has been to evaluate the performance of torrefaction based co-firing. Therefore, co-firing case has been compared to the 100 % coal feed case to understand the performance of torrefaction based co-firing. Furthermore, fluid flow, particles trajectories, heat transfer, and different emission behaviors have been studied. In addition, mechanisms of corrosion during co-firing have been studied and a guideline has been provided for corrosion model for analyzing the characteristics of alkali metals and their effects in co-firing coal boiler. The outcome from the CFD simulation indicated that boiler efficiency increases and the net CO2 emission reduced with increasing the biomass percentage in the co-firing system.

The steel industry is aiming to reduce CO2 emissions by different means; in the short-term, by replacing fossil coal with highly reactive carbonaceous material like bio-coal (pretreated biomass) and, in the longer term, by using hydrogen. The use of bio-coal as part of top charged briquettes also containing iron oxide has the potential to lower the thermal reserve zone temperature of the Blast furnace (BF) and, due to improved gas efficiency, thereby give a high replacement ratio to coke. In order to select a suitable bio-coal to be contained in agglomerates with iron oxide, the current study aims at investigating the devolatilization behavior and related kinetics of different types of bio-coals. In addition, the aim is to investigate the self-reduction behavior of bio-coal-containing iron ore composite under inert condition and simulated blast furnace thermal profile. In the BF the temperature of the top-charged material will increase rather quickly during the descent in the upper part. Ideally, all the carbon and hydrogen contained in the top-charged bio-coal should contribute to the reduction. The devolatilization of bio-coal is thus important to understand and to compare between different types of bio-coal. To explore the devolatilization behavior for different materials, a thermogravimetric analyzer equipped with a quadrupole mass spectrometer was used to monitor the weight loss and off-gases during non-isothermal tests for bio-coals having different contents of volatile matter. The samples were heated in an inert atmosphere up to 1200°C at three different heating rates: 5, 10 and 15°C/min. The thermogravimetric data were evaluated by using the Kissinger–Akahira–Sonuse (KAS) iso-conversational model and the activation energy was determined as a function of the conversion degree. Bio-coals with both low and high content of volatile matter can produce reducing gases that can contribute to the reduction of iron oxide in bio-agglomerates. Bio-coals containing a higher content of catalyzing components such as CaO and K2O will enhance the devolatilization and release of volatile matter at a lower temperature.  The self–reduction of composites was investigated by thermogravimetric analyses in argon atmosphere up to 1100°C and evolved gases were monitored by means of quadrupole mass spectroscopy. Composites with and without 10% bio-coal and sufficient coke breeze to keep the C/O molar ratio equal to one were mixed and Portland cement was used as a binder. To explore the effect of added bio-coals, interrupted vertical tube furnace tests were conducted in a nitrogen atmosphere at temperatures selected based on thermogravimetric results, using a similar thermal profile as for the thermogravimetric analyzer. The variation between fixed carbon, volatile matter contents and ash composition for different types of bio-coal influences the reduction of iron oxide. The results showed that the self-reduction proceeds more rapidly in the bio-coal-containing composite and that the volatile matter could have contributed to the reduction. The self-reduction of bio-coal-containing composites started at 500°C, while it started at 740°C with coke as the only carbon source. The hematite was successfully reduced to metallic iron at 850°C with bio-coal present as a reducing agent, but not until 1100°C when using coke. Use of bio-coal with high content of volatile matter but low content of catalyzing elements as potassium, sodium and calcium in bio-agglomerates for the BF can be recommended because it enhances the self-reduction of iron oxide, e.g., wustite was detected by XRD analysis in samples treated up to 680°C. Bio-coal with low content of volatile matter, low alkalis, low phosphorous and high content of fixed carbon will also be suitable to use in the BF.