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The concentrations of trace elements in 30 Saanich Peninsula agricultural soil samples were determined by acid digestion and inductively coupled plasma - optical emission spectroscopy (ICP-OES). A comparison of the results obtained to a 1995 BC Ministry of Environment data indicated that As, Cu, Mo, Sb, Se and Sn concentrations had increased whereas the concentrations of Ba, Be, Cd, Cr, Co, Mn, Ni, Pb, V and Zn had decreased. The principal sources of the trace elements were anthropogenic sources including fertilizer and manure application, weathering of rocks and atmospheric deposition. The concentrations changes were largely influenced by the individual properties of the elements, soil texture, soil organic matter and clay content. The mobility of the trace elements in the soils was mainly controlled by clay content and followed the order Cd> B >Mo> Cr> V> Zn> Se> Co> Cr> As> Ba> Sb> Mn> Ag, Be, Hg, Ni, Pb.

A variety of extractants were used to fractionate the trace metals Cd, Cu, Mn, Ni, Pb, and Zn in contaminated urban soils. The metals were mostly held in soil solid phases but not in soluble and exchangeable forms. Except for Mn, extractability of metals by selective chemicals was mainly a function of the contamination level. The speciation of these elements in water, 0.01 M CaCl2, and pH-adjusted water extra was calculated using the chemical equilibrium model MINEQL+. The free ions of Cd, Ni, and Zn were the predominant species in most of the water and 0.01 M CaCl2 extracts while PbCO30 was the main form of Pb. Organically complexed Cu accounted for over of the total dissolved Cu. The solubility of trace metals increased as solution pH was decreased. Metals Cd, Ni, Pb and Zn combined with Cl- at low pH (<5). Organically complexed Cu was shifted to Cu2+ when pH was decreased. / Except for Mn, the activities of the other metals in water, 0.01 M CaCl 2 extracts, and pH-adjusted water extracts were undersaturated with respect to established minerals in soils. MnHPO4 seems to be controlling the solubility of Mn in these extracts.

The work in this thesis demonstrates whether resins are better than conventional soil extractants at predicting plant metal concentrations, and whether low-cost soil treatments can effectively reduce metal content and concentrations in lettuce leaves. / Researchers have shown that ion exchange resins can simulate root metal uptake behaviour by acting as ion sinks. Chemical extractants on the other hand, generally do not behave in this manner. Thus, we would expect resins (in either bead or membrane form) to predict plant metal concentrations better than conventional extractants. For the first study, a procedure using anion exchange resin membranes (AEM) treated with either EDTA or DTPA chelators was chosen, since previous studies showed this method to be effective at predicting plant metal uptake, and practical for routine laboratory use. In addition, several conventional extractants were selected for comparison. / For the second part of the thesis, a study was undertaken to test the effectiveness of various food processing byproducts to stabilize metal contaminants in soils, and compare the results with those of a Na-based aluminosilicate (zeolite). (Abstract shortened by UMI.)

As a result of rapid growth in technology, efforts to remove pollutants from the natural environment have not been able to keep pace with the increasing amount of waste materials and a growing population that further aggravates the situation. This has resulted in the transformation of lakes and ponds into pollution depots. A pilot study for monitoring certain selected trace elements entering and leaving YorkPrairie Creek Pond, situated inside the campus of Ball State University, was undertaken with the view to establishing whether or not this pond has been polluted, like many lakes and ponds, by metal corrosion, engine exhaust gases, and runoff from fertilizers and streets.This investigation involved sampling pond waters at two sites, viz., Influx surface and Effluent surface. Samples were collected once daily at the same time over a total time period of 23 days. Each sample was analyzed, in duplicate, for the heavy metal cations iron, lead, and cadmium, and for the inorganic anions nitrate, orthophosphate, and chloride. Metals were analyzed by atomic absorption spectrophotometry (A. A. S.), while titrimetric and cotorimetric procedures were utilized for the anion analyses.Results have indicated that iron and chloride are the most abundant of all analytes. Precipitation tends to Increase concentrations of analytes in general, possibly due to increased runoff and the lowering of the pH of these waters; leading to increased elemental release into solution. The relative responses of the analyzed ion levels in pond influx and effluent waters have been shown to be similar although their levels were significantly different.Analyte levels were found to be generally higher in effluent than in Influx waters; only chloride was found to depart from this general behavior. This finding led to the conclusion that the selected Ions, with the exception of chloride, tend not to accumulate in the waters of the pond but rather to escape with its effluent. This conclusion is subject to modification by future researchers, to whom the author has recommended a more expanded sampling program that would include the surface and sediment of the pond's interior since the nature of the results (especially for Pb and Cd) would seem to indicate not only that the pond does not exhibit thorough mixing of its constituents (homogeneity) but also the presence of an active remobilization process within its interior.

Trace metal contamination of the air-soil-tree system was examined in southern Quebec, where acid deposition and tree dieback have been recorded in high elevation forests. Mn pollution was emphasized due to its large emission from gasoline combustion in Canada. Airborne Cu, Mn, V, and Zn showed higher concentrations than those reported for other remote locations. Significant fluctuation in Mn concentrations during the winter-spring season was explored by air mass back trajectory analysis. The study suggested that high Mn concentrations resulted from the atmospheric long-range transport from Canadian industrialized and metropolitan regions. Metal concentrations in podzolic topsoils were generally higher than their world-wide average values. Concentrations of trace metals in balsam fir (Abies balsamea (L.) Mill) needles were below their suggested potential phytotoxic levels, except for Mn, which also increased with elevation. The scanning of needles with micro-PIXE showed no significant correlation between metal accumulation and epistomatal distribution on foliar surfaces. / Pathways of trace metals deposited in the soil-tree system were elucidated through application of $ sp{54}$Mn and $ sp{65}$Zn on shoot, bark, and soil surfaces in growth-chamber experiments with balsam fir seedlings. Uptake and accumulation by seedlings 70 days after application on the shoot surface was about 25-30% of the remaining activities for $ sp{54}$Mn and $ sp{65}$Zn. Less than 1% of absorbed isotopes was translocated from the bark surface to other plant organs, whereas more than 50% of the radioisotopes absorbed at the shoot moved to the rest of the seedling. Acidic wetness facilitated the metal absorption through tree surfaces. Downward movement of the radioisotopes in podzolic soils was documented, and accumulation in seedlings by root uptake was 5% of the remaining activity for $ sp{54}$Mn and 3% for $ sp{65}$Zn 70 days after application. No appreciable elemental migration from internal tissues to epicuticular wax layers was found, and the leaching ratio was below 0.5 and 1.0% for $ sp{54}$Mn and $ sp{65}$Zn, respectively. This study helps to understand the links between atmospheric deposition and the elevated levels of Mn in trees, and potential effects of acid deposition on the bioaccumulation of toxic metal pollutants in high elevation forests in southern Quebec.

Thesis (M.A.)--University of Hawaii at Manoa, 2005. / Includes bibliographical references (leaves 146-156). / Also available by subscription via World Wide Web / xxi, 156 leaves, bound ill., maps 29 cm

One of the first concerns for forensic anthropologists in dealing with skeletal remains in the Australian context is the determination of whether the remains are of anthropological, historical or archaeological interest. If fewer than 75 years have elapsed since death, remains are classified as anthropological and of forensic interest. However, an accurate and reliable method for estimating time since death (TSD) from human skeletal remains has thus far eluded forensic anthropologists. This study investigates the application in an Australian context of a novel approach proposed by Swift (2001) to dating skeletal remains from their contained levels of radioisotopes 210Po, 238U and 226Ra and trace elements. Radionuclide activity concentrations were determined using alpha and gamma spectrometry. Trace element concentrations were measured on three separate occasions using inductively coupled plasma mass spectrometry (ICP-MS). Discriminant analysis of the combination of activity concentration values for 210Po, 238U and 226Ra indicated the possibility of separation of bones derived from individuals who had died in the three eras of interest. Additionally, variations in the concentration levels of specific trace elements and certain inter-element relationships between elements also showed significant correlations with TSD. The study could not be exhaustive as access to human skeletal material was limited and additionally, the archaeological material had a different origin and post-death history to material from the more recent past. However, trend lines for inter-relationships between specific metals and for radionuclides indicated that all material fitted the same generally projected trends and as such, inferences with respect to variations of trace elements and radionuclides could be made with confidence. Bone radionuclide activity and calcium concentrations were all significantly higher in bones from the archaeological era than those from more recent eras, while trace lead concentrations contained in samples from the more recent historical era were significantly higher than those from other eras. Barium, lanthanum, rubidium, strontium, cerium and neodymium concentrations were all significantly correlated with one another and with radionuclide activity concentrations. Differences were found between the patterns of radionuclide activity and trace element concentrations between the skull and femur. The results of this study lend support to suggestions that multivariate analysis of trace element concentrations and radionuclide activity levels could aid in the estimation of time since death from skeletal remains in Australia. Although this study made use of only a limited amount of material, results clearly indicated the need to take into account variations arising from lifetime activities, diagenesis and bone type in applying the techniques to estimations of time since death. It highlights the need for a large-scale study using bone of known ages that systematically examines these influences on the estimation of time since death.

Mounted ill. / Offprint of the author's journal article in pocket / Includes bibliographies / xiii, 248 leaves, [50] leaves of plates, [3] folded leaves : ill. (some col.) ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, 1985

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2002. / Härtill 4 uppsatser.