The turbidimetric method for the determination of lead ion developed in this work is not intended as a replacement for standard analytical procedures, but is presented solely as a laboratory exercise for courses in elementary instructional analysis.

Accurately predicting sediment delivery has been a long-standing problem in the field of water resource management. Many different watershed equations and models have been developed such as the Universal Soil Loss Equation (USLE), the Geo-spatial interface for the Water Erosion Prediction Program (GeoWEPP) and many more, however, these models have not always been able to reliably predict in-stream sediment loads. In this study, two scales, watershed and site level, are used to understand where sediment transported in-stream is being produced. At the watershed scale, USLE was used to estimate sediment yield and then different factors such as connectivity topographic indices were applied as discount factors in an attempt to improve these estimates. The different parameters were then compared to turbidity to determine the level of accuracy of each method. It was found that USLE is not able to predict in-stream turbidity levels in the study area watersheds in Virginia and North Carolina. An implicit assumption of USLE is that runoff is produced on steeper slopes and that sediment production occurs on these hillslopes. However, it was found that flatter-sloped areas were highly correlated with in-stream turbidity. It was also found that in-channel and site-specific parameters such as bank height/slope and level of confinement at higher flows were more accurate predictors of in-stream sediment levels. Overall, turbidity and in-stream sediment levels are not well predicted by models that employ USLE. The distribution of runoff source areas, and channel/bank properties appear to be good predictors of sediment production at the watershed scale. These results indicate that sediment production and transport, as conceptualized by common models and equations, often associate sediment source areas with geomorphic and hydrologic processes in ways that are not consistent with the results of this study. Our results show that sediment is most likely being sourced from the channels and in stream areas. / Master of Science / Predicting how sediment moves through a watershed has been a long-standing problem in the field of water resource management. There are many equations and models that have been developed to calculated the amount of sediment that exits a watershed; such as the Universal Soil Loss Equation (USLE), the Geo-spatial interface for the Water Erosion Prediction Program (GeoWEPP) and many more. However, these models have not always been reliable or accurate in their predictions. In this study, two scales, watershed and site level, are used to understand where sediment transported within streams is being produced. At the watershed scale, USLE was used to estimate sediment leaving a system and then different factors, with different approaches to the understanding of sediment movement, were applied as discount factors in an attempt to improve these estimates. The different values that were calculated were then compared to turbidity to determine the level of accuracy of each parameter. It was found that USLE is not able to predict in-stream turbidity levels in the study area watersheds in Virginia and North Carolina. An assumption of USLE is that runoff is produced on steeper slopes and that sediment erosion occurs on these steeper sloped areas. However, it was found that flatter-sloped areas were highly correlated with turbidity. It was also found that in-channel and site-specific parameters such as bank height/slope and the level of confinement at higher flows were more accurate predictors of turbidity. Overall, USLE and models that used USLE were not able to predict turbidity. The distribution of runoff source areas and channel/bank properties appear to be good predictors of turbidity at the watershed scale. These results indicate that sediment movement, as conceptualized by common models and equations, often associate sediment source areas with watershed level morphology and hydrology in ways that are not consistent with the results of this study. Our results show that sediment is most likely being produced from the channels and in stream areas.

Interactions of progesterone with zwitterionic dipalmitoyl phosphotidylcholine (DPPC) multilamellar liposomes (MLVs) were investigated as a function of temperature and progesterone concentration by using three non-invasive techniques of Fourier transform infrared (FTIR) spectroscopy, turbidity at 440 nm and differential scanning calorimetry (DSC). The results show that 1mol% of progesterone does not induce a significant change in the shape of thermotropic profile of DPPC. However as progesterone concentration increases, the main transition temperature decreases and phase transition curve broadens. Higher concentrations (12, 18 and 24mol%) also decreased the transition temperature but not as significantly as lower concentrations. The characteristic pretransition of DPPC was completely disappeared upon the addition of progesterone. Progesterone disorders the phospholipid membranes in a concentration dependent manner. Furthermore, low concentrations of progesterone (3, 6 and 9mol%) increase the fluidity of the system but high concentrations (12, 18 and 24mol%) stabilize the membranes by decreasing the mobility of the acyl chains. The opposite effect of progesterone on membrane dynamics of low and high concentrations was also supported by turbidity studies at 440 nm. DSC peaks broaden and shift to lower temperature degrees with increasing concentrations up to 9mol% of progesterone. At 6 and 12mol% of progesterone, the curve contains more than one peak. This indicates the existence of phase separation. The pretransition of liposomes was eliminated for all samples containing progesterone. Analysis of C=O stretching bond in FTIR spectroscopy showed that progesterone does not make any hydrogen bonds with the interfacial region of DPPC liposomes, instead it induces free carbonyl groups in the system. Ester groups were found to be disordered by the addition of progesterone and the effect is profound with 6 and 9mol% concentrations. The head group of liposomes were found to make hydrogen bonding in the vicinity of 3mol% of progesterone in both phases and of 6mol% of progesterone in liquid crystalline phase by infrared spectroscopy of PO- 2 stretching mode. This hydrogen bonding is made either with the hydroxyl group of progesterone or with the water molecules around the head group. With other concentrations of progesterone, there is no evidence of hydrogen bond formation.

The extinction of solar radiation by atmospheric aerosols influences the Ultraviolet (UV) flux at the surface, which in turn has implications on both human and environmental health. In this study we present measurements of aerosol optical depth ( and #964;a) in the UV at Boulder, Colorado and Atlanta, Georgia using direct measurements of solar UV radiation. The wavelength dependence of and #964;a and the single scattering albedo ( and #969;o) are determined from the measured values of and #964;a. Daily averages of and #964;a range between 0.09 and 0.52 at Boulder and between 0.23 and 2.09 for Atlanta between the wavelengths of 332 and 340 nm. The average ngstrm exponent ( and #945;) is 0.83 at Boulder and 1.43 in Atlanta. Results clearly show that aerosols have a significant effect on the UV Index. Day-to-day changes in the UV index during the one month measurement period in Atlanta range between 2-3 UV Index units at solar noon. It is estimated that when changes in and #964;a and and #969;o occur simultaneously, the UV Index can change up to 6 units from one day to the next at solar noon in the Atlanta area. The single scattering albedo ( and #969;o) was estimated to range between 0.8 and 0.99 for Atlanta. The results suggest an increasing trend in and #969;o with increases in and #964;a. In addition, a new synthetic current UV Index is developed which expands to nearly 10,000 cities the number of current UV Index reports that can be distributed to the public in the United States. Right now, current UV Index values are limited to specific UV measuring sites, constrained by the difficulties of maintaining accurate calibration within the network of UV instruments. The distribution of UV Index values to more cities will increase the publics awareness of the harmful effects of the sun. This new UV Index can be accessed through The Weather Channel website.

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Thesis (M.S.)--Oregon State University, 1993. / Typescript (photography). Includes bibliographical references (leaves 111-114). Also available on the World Wide Web.

Thesis (PhD) - Faculty of Life and Social Sciences, Swinburne University of Technology, 2009. / Submitted in full requirement for the degree of Doctor of Philosophy, Faculty of Life and Social Sciences, Swinburne University of Technology - 2009. Typescript. Includes bibliographical references (p. 137-160)

Dissertation (PhD)--University of Stellenbosch, 2008. / Bibliography. Also available via the Internet.

Thesis (M.S.)--Naval Postgraduate School, 1974. / Includes bibliographical references (leaves 149-152).