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Generation of high-peak power, microwave ultra-short pulses (USPs) is desirable for ultra-wideband communications and remote sensing. A variety of microwave USP generators exist today, or are described in the literature, and have benefits and limitations depending on application. A new class of pulse compressors for generating USPs using electromagnetic time reversal (TR) techniques have been developed in the last decade, and are the topic of this dissertation. This dissertation presents a compact TR microwave pulse-compression cavity that has ultra-wide bandwidth (5 GHz – 18 GHz), and employs waveguide feeds for high-peak power output over the entire band. The system uses a time-reversal-based pulse compression scheme with one-bit processing (OBTR) to achieve high compression gain. Results from full-wave simulations are presented as well as measurements showing compression gain exceeding 21.2 dB, 22% efficiency, and measured instantaneous peak output powers reaching 39.2 kW. These are all record results for this type of pulse compressor. Additionally presented is new analysis of variation in compression gain due to impulse response recording time and bandwidth variation, new experimental work on the effect of mode stirrer position on compression gain, and a novel RF switch-based technique for reducing time-sidelobes while using OBTR. Finally, a new technique is presented that uses a reverberant cavity with only one feed connected to an ultra-wideband circulator (6.5 GHz to 17 GHz) to perform TRPC. Prior to this work, TRPC has only been demonstrated in electromagnetics using two or more feeds and a reverberant cavity acting as the time-reversal mirror. This new 1-port technique is demonstrated in both simulation and measurement. The proposed system achieves up to a measured 3 dB increase in compression gain and increased efficiency. Also, a novel application of the random coupling model (RCM) to calculate compression gain is presented. The cavity eigenfrequencies are modeled after eigenvalues of random matrices satisfying the Gaussian orthogonal ensembles (GOE) condition. Cavity transfer functions are generated using Monte Carlo simulations, and used to compute the compression gains for many different cavity realizations. / Doctor of Philosophy / Generation of high-peak power, microwave ultra-short pulses (USPs) is desirable for ultra-wideband communications and remote sensing. A variety of microwave USP generators exist today, or are described in the literature, and have benefits and limitations depending on application. A new class of pulse compressors for generating USPs using electromagnetic time reversal (TR) techniques have been developed in the last decade, and are the topic of this dissertation. This dissertation presents a compact TR-based microwave pulse-compression cavity that has unique features that make it optimal for high-power operations, with results from simulations as well as measurements showing improved performance over other similar cavities published in the literature with a record demonstrated peak output power of 39.2 kW. Additionally, new analysis on the operation and optimization of this cavity for increased performance is also presented. Finally, a new technique is presented that uses a cavity with only one feed that acts as both the input and output. This 1-port technique is demonstrated in both simulation and measurement. The proposed system achieves a two-times increase in compression gain over its 2-port counterpart. In conjunction with these measurements and simulations, a novel technique for predicting the performance of these cavities using Monte Carlo simulation is also presented.

Master of Science / Department of Physics / Brian R. Washburn / This thesis reports our attempt towards achieving a phase stabilized free-space nonlinear polarization rotation (NPR) mode locked erbium doped fiber laser frequency comb system. Optical frequency combs generated by mode-locked femtosecond fiber lasers are vital tools for ultra-precision frequency metrology and molecular spectroscopy. However, the comb bandwidth and average output power become the two main limiting elements in the application of femtosecond optical frequency combs. We have specifically investigated the free-space mode locking dynamics of erbium-doped fiber (EDF) mode-locked ultrafast lasers via nonlinear polarization rotation (NPR) in the normal dispersion regime. To do so, we built a passively mode-locked fiber laser based on NPR with a repetition rate of 89 MHz producing an octave-spanning spectrum due to supercontinuum (SC) generation in highly nonlinear fiber (HNLF). Most significantly, we have achieved highly stable self-starting NPR mode-locked femtosecond fiber laser based frequency comb which has been running mode locked for the past one year without any need to redo the mode locking. By using the free-space NPR comb scheme, we have not only shortened the cavity length, but also have obtained 5 to 10 times higher output power (more than 30 mW at central wavelength of 1570 nm) and much broader spectral comb bandwidth (about 54 nm) compared to conventional all-fiber cavity structure with less than 1 mW average output power and only 10 nm spectral bandwidth. The pulse output from the NPR comb is amplified through a 1 m long EDF, then compressed by a length of anomalous dispersion fiber to a near transform limited pulse duration. The amplified transform limited pulse, with an average power of 180 mW and pulse duration of 70 fs, is used to generate a supercontinuum of 140 mW. SC generation via propagation in HNLF is optimized for specific polling period and heating temperature of PPLN crystal for SHG around 1030 nm. At last, we will also discuss the attempt of second harmonic generation (SHG) by quasi phase matching in the periodically polled lithium niobate (PPLN) crystal due to nonlinear effect corresponding to different polling period and heating temperature.

Das Ziel der vorliegenden Arbeit ist es, nanokristalline und laserpuls-strukturierte Elektroden für die alkalische Wasserelektrolyse zu untersuchten und hinsichtlich ihrer elektrokatalytischen Eigenschaft zu bewerten. Dabei besteht die Hauptaufgabe in der Aufklärung der Zusammenhänge zwischen der elektrokatalytischen Aktivität und der Struktur der Elektroden. Es soll der Effekt der nanokristallinen Kristallstruktur auf die Elektrodenaktivität aufgeklärt werden. Zudem stellt die elektrokatalytische Wirkung von Mo in Ni-Elektroden für die Wasserstoffentwicklungsreaktion eine zentrale Untersuchung in der vorliegenden Arbeit dar. Für die Sauerstoffentwicklungsreaktion soll der Einfluss von Fe in nanokristallinen Ni-Materialien näher analysiert und unter industriell relevanten Betriebsbedingungen bewertet werden. Zum anderen richtet sich der Fokus auf die Nutzung eines Ultrakurzpulslasers zur Strukturierung von Ni-Elektrodenoberflächen. Besonderes Augenmerk wird auf die Korrelation zwischen den individuellen Strukturmerkmalen, der erzielten Oberflächenvergrößerung und der elektrokatalytischen Aktivität bezüglich der Wasserstoffentwicklung gelegt. Zudem werden Langzeituntersuchungen bei Stromdichten von bis 1 A/cm² durchgeführt, um die Stabilität zu bewerten und Degradationsmechanismen aufzuklären.

Dans cette thèse, nous étudions expérimentalement la génération d'impulsions carrées très énergétiques et accordable à l’échelle nanosecondes et d'impulsions ultracourtes à haute puissance moyenne de sortie dans les lasers à fibre utilisant les nanomatériaux comme absorbant saturable. Tout d'abord, puisque la dynamique des impulsions est dominée par l'interaction de la non linéarité et de la dispersion chromatique cubique de la fibre avec un mécanisme de discrimination d'intensité appelé absorbant saturable, la stabilité d'une distribution harmonique en mode verrouillé est étudiée par injection externe d'une onde continue.Enfin, nous avons utilisés des absorbant saturable à base de nanomatériaux déposés sur des tapers optiques dans les lasers à fibre pour générer des impulsions ultracourtes avec une puissance de sortie moyenne élevée. / In this thesis, we investigate experimentally the generation of high energy nanosecond tunable square pulses and high output power ultrashort pulses in fiber lasers. First, since pulse dynamics are dominated by the interaction of the fiber's cubic Kerr nonlinearity and chromatic dispersion with an intensity-discriminating mechanism referred to as a saturable absorber, the stability of a harmonic mode-locked distribution is studied by external injection of a continuous wave. Finally, we implemented nanomaterial based saturable absorbers in fiber laser configuration to generate ultrashort pulses with high average output power. Different techniques of achieving such components are explicitly detailed: ultrashort pulse generation in ring cavities where graphene and topological insulators are deposited on optical tapers to form a saturable absorber.

La génération d'harmoniques d'ordre élevé en milieu gazeux est un phénomène habituellement décrit par un modèle à trois étapes : sous l'effet d'un champ laser intense, un atome (ou une molécule) est ionisé par effet tunnel. L'électron éjecté est accéléré dans le champ laser, puis il se recombine sur son ion parent en émettant un photon XUV. Ce rayonnement XUV, émis sous la forme d'impulsions attosecondes (1 as = 10-18 s), est un outil idéal pour sonder la structure électronique des atomes ou des molécules, avec une résolution temporelle de l'ordre de l'attoseconde. Néanmoins, l'intensité de ce rayonnement n'est en général pas suffisante pour induire des effets non-linéaires (transitions à deux photons).Au cours des travaux réalisés pendant cette thèse, nous avons développé une source harmonique capable de produire un rayonnement XUV intense qui doit permettre d'accéder à la physique non-linéaire dans cette gamme de longueur d'onde. Pour parvenir à ces résultats, un travail important sur les impulsions infrarouges génératrices a été nécessaire, aussi bien dans le domaine spatial que dans le domaine temporel. Une technique de mise en forme spatiale de faisceaux laser intenses a donc été développée, ainsi qu'une technique de post compression adaptée aux impulsions laser intenses. Ce travail de thèse se divise donc en trois étapes : - Le développement de la source harmonique haute énergie et des diagnostics associés. Cette source est basée sur l'utilisation d'une chaîne laser Titane-Saphir qui délivre des impulsions de 150 mJ pour des durées de 40 fs à une cadence de 10 Hz. De bonnes conditions d'optimisation ont été obtenues, donnant lieu à des impulsions XUV dont l'énergie est de l'ordre du µJ lors de la génération dans l'argon.- Le développement d'une technique de mise en forme spatiale adaptée aux faisceaux laser intenses et à la génération d'harmoniques. Le dispositif est basé sur une optique en réflexion et sur les interférences à deux faisceaux. Il permet de produire, dans la région focale, des faisceaux dont le profil d'intensité est radialement constant (faisceaux flat top) et ainsi d'apporter un contrôle supplémentaire sur la génération d'harmoniques d'ordre élevé.- Le développement d'une technique de post compression en propagation guidée basée sur l'élargissement spectral induit par ionisation. Cette technique est adaptée pour des impulsions intenses (3.5 TW) et permet de produire des impulsions de puissance crête supérieure au Térawatt dans le domaine sub-10 fs. Cette technique fournit donc une source unique pour la génération d'harmoniques d'ordre élevé.Ces deux approches ont été testées et validées pour la génération d'harmoniques d'ordre élevé, et les résultats obtenus ouvrent d'intéressantes perspectives telles que la génération d'impulsions attosecondes isolées de haute énergie (> 100 nJ). / The generation of high order harmonics in a gaseous medium is a phenomenon conveniently described by a three steps model : subject to a strong laser field irradiation, an atom (or molecule) can undergo a tunneling ionization. The ejected electron is accelerated in the laser field and recombine on its parent ion leading to the emission of an XUV photon. The XUV radiation can be emitted as attosecond pulses (1 as = 10-18 s), and it is then an ideal tool to probe the electronic structure of atoms or molecules which require the highest time resolution. However, the intensity of this radiation is usually not sufficient to induce non-linear processes (two-photon transitions).In the frame of this work, we have developed a harmonic source capable of producing an intense XUV radiation to access non-linear physics in this wavelength domain.To achieve these results, significant work on the infrared generating pulses was necessary, both in the spatial and temporal domain. We have developed a technique for spatial shaping of intense laser beams, and a post compression technique fitted to high energy pulses.This thesis is therefore divided into three parts:- The development of an high energy harmonic source and related diagnostics. We use a Ti: sapphire laser system for this source which delivers 40-fs pulses up to an energy of 150 mJ at 10 Hz repetition rate. Good optimization conditions were obtained, leading to XUV pulse energies of the order of μJ in the case of generation in argon.- The development of a spatial shaping technique adapted to intense laser beams and to harmonic generation. The device is based on reflection optics and the interferences of two beams. It can produce, in the focal region, beams with a radially constant intensity over a large volume (flat top beams) and thus provide additional control of the harmonics generating process.- The development of a post compression technique in guided geometry based on the ionization induced spectral broadening. This technique is suitable for intense pulses (3.5 TW) and produces pulses above the terawatt level in the 10-fs range. This technique therefore provides a unique source for harmonic generation.These two approaches have been tested and validated for high order harmonics generation, and the results open interesting perspectives such as the generation of isolated attosecond pulses of high energy (> 100 nJ).