This thesis explores the mechanics of single molecule machines on a surface, aiming to understand the principles underlying synthetic single molecular machines. The study utilizes scanning tunneling microscopy (STM) at ultra-low temperatures and high vacuum conditions to investigate individual small molecules adsorbed on a substrate. In the first part, the transmission of rotation between single molecule-gears is examined, employing a star-shaped pentaphenylcyclopentadiene molecule manipulated by STM. The second part focuses on a zwitterionic and chiral molecule's dual functionality as a molecule-rotor or a molecule-vehicle (nanocar), with motion driven by tunneling electrons. The third part explores the origin of unidirectional rotation in a single molecule-rotor, analyzing the effects of thermal and electronic excitations on rotation dynamics. Overall, this work contributes to the fundamental understanding of nanoscale mechanical molecular devices and their potential applications.

This master thesis investigates the possibilities for performance improvements of synchronous machines with unidirectional application.The literature review part presents theories and applications of asymmetrical machine. Four categories regarding asymmetrical machine, namely mixed pole, saturation mitigation, pole shifting and asymmetrical pole shaping, are summarized. It is shown that asymmetrical concept offers characteristic improvement in one or both rotational directions. A field winding synchronous model was used in FEM simulation (FLUX 2D). Armature reaction effecton this machine is investigated. It is found that armature reaction has different effects with varying current angle.Two ideas regarding asymmetrical pole shaping are investigated. First of all, pole shoe cutting idea is investigated. It leads to increased airgap length and less output torque. Secondly, progressive airgap idea shows reduced armature reaction effect and improved power factor, but higher torque ripple.Furthermore, an improved idea is suggested to reduce the torque ripple. Performance improvement by assisted permanent magnet is also studied. Four ideas of this field are investigated. It is found that permanent magnet can be used to reduce saturation, improve power factor and output torque. The reasons for limited improvements are analyzed.