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Étude pétrographique et géochimique des granites du district uranifère de Vendée : liaisons entre l'évolution minéralogique et le comportement de l'uranium, conséquences pour la prospection.Renard, Jean-Paul, January 1900 (has links)
Thèse--Sc. nat.--Nancy 1, 1971. / Bibliogr. f. 172-189.
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Variacao da razao estequiometrica O/U durante a estocagem do combustivel nuclear UOsub2FERRARI, KATIA R. 09 October 2014 (has links)
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Purificacao de hexafluoreto de uranioARAUJO, ENEAS F. de 09 October 2014 (has links)
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Variacao da razao estequiometrica O/U durante a estocagem do combustivel nuclear UOsub2FERRARI, KATIA R. 09 October 2014 (has links)
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Purificacao de hexafluoreto de uranioARAUJO, ENEAS F. de 09 October 2014 (has links)
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Purification de l'hexafluorure d'uranium / Uranium hexafluoride purificationHiltbrunner, Jean-Michel 10 March 2017 (has links)
L’hexafluorure d’uranium, de formule chimique UF 6 , est un composé clé du cycle du combustible car il est utilisé pour l’étape d’enrichissement isotopique. Toutefois, des impuretés présentes et mélangées à l’UF 6 sont à éliminer afin de garantir un uranium de pureté nucléaire. Dans ce manuscrit, les réactions chimiques entre les polluants et les filtres chimiques retenus pour la purification sont étudiées. Par ailleurs, l’étude de la réactivité en milieu liquide est réalisée afin de se rapprocher des conditions industrielles. Une voie de recyclage des filtres chimiques est également investiguée afin de réutiliser les adsorbants sur plusieurs cycles de purification. L’ensemble des performances (taux de sorption des polluants, décontamination lors du recyclage) sont évaluées avant la mise au point du pilote à l’échelle industrielle. / Uranium hexafluoride, which chemical formula is UF 6 , is a key compound of nuclear fuel cycle due to its use during isotopic enrichment process. Nethertheless, pollutants melted with UF 6 have to be removed in order to ensure a nuclear purity fuel. In this manuscript, the reactions occurring between pollutants and chemical filters selected for this application are studied. Then, the reactivity in liquid UF 6 is also examined with the aim of being close to the industrial process. The regeneration of adsorbents is investigated so that chemical filter can be used for several purification cycles. The performances (sorption rate of pollutants, purifying during recycling step) are evaluated before simulations at industrial scale.
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Origin of Uranium Mineralization at Coles Hill Virginia (USA) and its Natural Attenuation within an Oxidizing Rock-Soil-Ground Water SystemJerden, James L. 04 October 2001 (has links)
Development of a scientific basis for management of uranium bearing wastes and contaminants requires information from natural geologic systems. The following study of the Coles Hill uranium deposit and associated weathered zone constrains processes leading to the natural attenuation of uranium within an oxidizing, fluid rich environment typical of the eastern US. At the Coles Hill deposit fracture hosted, primary U(IV) bearing mineral assemblages formed during hydrothermal activity associated with Mesozoic faulting. The most abundant ore assemblage consists of coffinite and apatite, but uraninite-zeolite and uraninite-calcite assemblages are also present. Within the shallow bedrock there is a uranium redox transition where alteration of U(IV) minerals has produced secondary uranium minerals. Geochemical data suggests that the volume of rock containing this U(IV)/U(VI) transition is acting as a closed system with respect to uranium mass transport during oxidation. The dominant mechanism of uranium fixation within the oxidizing zone is the precipitation of Ba-U(VI) phosphates (meta-autunite group). Speciation and mineral stability calculations indicate that ground waters from the Coles Hill weathered zone are saturated with respect to Ba-meta-autunite and that this mineral is capable of buffering dissolved uranium concentrations to values lower than 20 parts per billion. U(VI) phosphates of the meta-autunite group are not stable in the vadose zone (soil pH ~ 4.5) at the Coles Hill site. In this zone uranium is associated with (Ba, Ca, Sr) aluminum phosphate of the crandallite group as well as with phosphate sorbed to iron oxy-hydroxide mineral coatings. Uranium leached from the vadose zone is reprecipitated as new meta-autunite minerals below the water table due to higher pH conditions of ~6.0 and relatively high activity ratios of dissolved phosphate to carbonate (e.g. log [H2PO4-/HCO3-] > -3). It is estimated that the U(VI) phosphates responsible for the natural attenuation of uranium at this site persist within the weathering zone for hundreds of thousands of years. Thus, the Coles Hill deposit represents an excellent natural laboratory for the study of uranium attenuation with potential applications for the design and implementation of cost effective remediation and containment strategies, such as soil amendments techniques and in-situ reactive barriers technologies. / Ph. D.
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Radioactive occurences in the Start area, South Devon, EnglandIbrahim, H. J. January 1983 (has links)
No description available.
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Sputtering processes in UO2̲ and UF4̲Lama, F. January 1986 (has links)
No description available.
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Phase transformations in binary uranium alloysBeverini, Gianluca January 1991 (has links)
No description available.
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