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Estudo dos parametros de processo da reducao do tricarbonato de amonio e uranilo a dioxido de uranio em forno de leito fluidizadoLEITAO JUNIOR, CLAUDIO B. 09 October 2014 (has links)
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Estudos de purificacao de uranio por saturacao seletiva do cloreto de uranilo em resina anionica forteGOCHNARG, ISRAEL 09 October 2014 (has links)
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Estudo da determinacao de uranio por analise por ativacao com neutrons epitermicosATALLA, LAURA T. 09 October 2014 (has links)
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Desenvolvimento do processo de producao de pos de UO2, a partir de nitrato de uranilo, via atomizacaoLAINETTI, PAULO E. de O. 09 October 2014 (has links)
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A review of unconformity-type uranium depositsDabrowski, F A 02 April 2013 (has links)
Intense interest in uranium in the past decade has led to the discovery of new kinds of deposits of which the so-called unconformity-type are economically the most important. Presently known occurrences are restricted to Australia and Canada where they are characterized chiefly by their spatial relationship to Lower-Middle Proterozoic unconformities. Other common features include similar host-rock assemblages, structural controls, alteration, mineralogy, age relationships and fluid-inclusion data. Similar characteristics in other vein-type deposits, including those of the Beaverlodge district in Canada, deposits in France and Portugal, and the Schwartzwalder mine in the United States, suggest that they may also be of the unconformity-type. Various interpretations of the geological relationships of unconformity-type deposits have resulted in a number of genetic hypotheses, which require different exploration philosophies. Nearsurface supergene processes are considered to be most important although other mechanisms may have played contributing roles in the concentration of uranium. There is considerable potential for further discoveries of unconformity-type uranium deposits throughout the world. No such deposits are yet known in southern Africa although several favourable Precambrian unconformities are present.
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Radionuclide interactions with materials relevant to a geological disposal facilityPreedy, Oliver D. January 2017 (has links)
Materials representative of those found in a Geological Disposal Facility (GDF) for the long-term storage of nuclear waste have been investigated for their ability to retard the movement of ionic species found in nuclear waste. Fe1-xO, Fe2O3, Fe3O4 (from steel corrosion) and sandstone (bedrock) used as physical barriers in the GDF have been treated using solutions of pH 7-13 which are representative of the leachate expected from concrete encapsulation of waste in contact with ground water. A mimic of portlandite cement, Ca(OH)2 was also prepared carbonate-free via a sacharate method for use in these leachate experiments. Materials have been characterised using a mixture of techniques such as Powder X-ray Diffraction (PXRD) and Infra-red Spectroscopy which focus on the bulk, short range techniques such as Extended X-ray Absorption Fine Structure (EXAFS), Scanning Electron Microscopy(SEM) and Nuclear Magnetic Resonance(NMR) and physical measurements such as diffusion experiments and fluorescence spectroscopy. Characterisation of the bulk materials before and after treatment using PXRD and SEM indicates that high purity iron oxides are affected differently by the solutions of varying pH. While not detectable by bulk techniques, SEM analysis evidence of the surface of the materials showed that Fe1-xO was deleteriously affected by solutions with pH > 7 more than the more oxidised materials. Initially needle-like crystals formed on the surface of Fe1-xO that are characteristic of goethite which at long aging times up to 168 h, showed transformation to crystal morphologies characteristic of Fe2O3. As the alkalinity increased, the transformation of Fe1-xO to Fe2O3 slowed. Dissolution of the iron surfaces in the solutions of pH 7-13 were determined by measuring the concentration of dissolved iron using ICPMS. While Fe1-xO and Fe3O4 followed first order kinetics, the dissolution kinetics for Fe2O3 appeared more complex. As the alkalinity increased, the rate constant for dissolution decreased in all cases indicating that higher pH is better for containment due to the formation of a passivated surface layer evidenced by SEM. The sorption of uranium to the iron oxide surfaces was investigated as a function of pH (7-13). In all cases, there was evidence of uranium sorption. The greatest sorption was evidenced when Ca(OH)2 was present which is most likely due to the precipitation of the known phase, calcium uranate. In the absence of calcium hydroxide, the sorption of uranium to the iron oxide surfaces decreased as the pH increased, reflecting the increase in formation of the anionic uranium species. In the presence of carbonate, the sorption of uranium onto the surfaces also decreases reflecting the formation of the soluble uranyl carbonate species. NMR spectroscopy of uranyl species in solution indicates that the chemical shift is strongly affected by pH shifting from 163 ppm to 175 ppm as the pH changes from 7 to 13 and allowing the uranium speciation to be used as a pH probe. A much -2- smaller shift in respect of temperature of less than 0.5 ppm was observed in the temperature range studied between 25 and 50°C. The quality of fluorescence spectra has been shown to be strongly affected by complexing species present in solution, the best spectra achieved with non-complexing species such as perchlorate. Migration experiments of the radionuclides uranium, thorium and technetium has been investigated by placing sandstone cores in alkaline solution and analysing both the water itself and the core to examine retention and transport. The results determined that the technetium diffused readily through the sandstone matrix. The uranium and throrium did not achieve breakthrough. This was attributed to the low solubilities and the formation of stable precipitates.
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Uranium Isotope Fractionation During Coprecipitation with Aragonite and CalciteJanuary 2015 (has links)
abstract: Natural variations in 238U/235U of marine carbonates might provide a useful way of constraining redox conditions of ancient environments. In order to evaluate the reliability of this proxy, we conducted aragonite and calcite coprecipitation experiments at pH ~7.5 and ~ 8.5 to study possible U isotope fractionation during incorporation into these minerals.
Small but significant U isotope fractionation was observed in aragonite experiments at pH ~ 8.5, with heavier U in the solid phase. 238U/235U of dissolved U in these experiments can be fit by Rayleigh fractionation curves with fractionation factors of 1.00007+0.00002/-0.00003, 1.00005 ± 0.00001, and 1.00003 ± 0.00001. In contrast, no resolvable U isotope fractionation was observed in an aragonite experiment at pH ~7.5 or in calcite experiments at either pH. Equilibrium isotope fractionation among different aqueous U species is the most likely explanation for these findings. Certain charged U species are preferentially incorporated into calcium carbonate relative to the uncharged U species Ca2UO2(CO3)3(aq), which we hypothesize has a lighter equilibrium U isotope composition than most of the charged species. According to this hypothesis, the magnitude of U isotope fractionation should scale with the fraction of dissolved U that is present as Ca2UO2(CO3)3 (aq). This expectation is confirmed by equilibrium speciation modeling of our experiments. Theoretical calculation of the U isotope fractionation factors between different U species could further test this hypothesis and our proposed fractionation mechanism.
These findings suggest that U isotope variations in ancient carbonates could be controlled by changes in the aqueous speciation of seawater U, particularly changes in seawater pH, PCO2, [Ca], or [Mg] concentrations. In general, these effects are likely to be small (<0.13 ‰), but are nevertheless potentially significant because of the small natural range of variation of 238U/235U. / Dissertation/Thesis / Masters Thesis Chemistry 2015
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Corrosao de placas combustiveis tipo MTR contendo nucleos de cermets U3O3-AlDURAZZO, MICHELANGELO 09 October 2014 (has links)
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Unidade piloto de obtencao do tricarbonato de amonio e uraniloSANTOS, LAURO R. dos 09 October 2014 (has links)
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Otimizacao da emissao termoionica e determinacao de uranio ao nivel de tracos em rochas pela tecnica de espectrometria de massa diluicao isotopicaKAKAZU, MAURICIO H. 09 October 2014 (has links)
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