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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
11

The genesis of ‘giant’ copper-zinc-gold-silver volcanogenic massive sulphide deposits at Tambogrande, Perú : age, tectonic setting, paleomorphology, lithogeochemistry, and radiogenic isotopes

Winter, Lawrence Stephen 11 1900 (has links)
The ‘giant’ Tambogrande volcanogenic massive sulphide (VMS) deposits within the Cretaceous Lancones basin of northwestern Perú are some of the largest Cu-Zn-Au-Ag-bearing massive sulphide deposits known. Limited research has been done on these deposits, hence the ore forming setting in which they developed and the key criteria that permitted such anomalous accumulation of base-metal sulphides are not understood. Based on field relationships in the host volcanic rocks and U-Pb geochronology, the deposits formed during the early stages of arc development in the latest Early Cretaceous and were related to an extensional and arc-rift phase (~105-100 Ma, phase 1). During this time, bimodal, primitive basalt-dominant volcanic rocks were erupted in a relatively deep marginal basin. Phase 1 rhyolite is tholeiitic, M-type, and considered to have formed from relatively high temperature, small batch magmas. The high heat flow and extensional setting extant during the initial stages of arc development were essential components for forming a VMS hydrothermal system. The subsequent phase 2 (~99-91 Ma) volcanic sequence comprises more evolved mafic rocks and similar, but more depleted, felsic rocks erupted in a relatively shallow marine setting. Phase 2 is interpreted to represent late-stage arc volcanism during a waning extensional regime and marked the transition to contractional tectonism. The Tambogrande deposits are particularly unusual amongst the ‘giant’ class of VMS deposits in that deposition largely occurred as seafloor mound-type and not by replacement of existing strata. Paleomorphology of the local depositional setting was defined by seafloor depressions controlled by syn-volcanic faults and rhyolitic volcanism. The depressions were the main controls on distribution and geometry of the deposits and, due to inherently confined hydrothermal venting, enhanced the efficiency of sulphide deposition. Geochemical and radiogenic isotope data indicate that the rhyolites in the VMS deposits were high temperature partial melts of the juvenile arc crust that had inherited the isotopic signatures of continental crust. Moreover, Pb isotope data suggest the metal budget was sourced almost wholly from mafic volcanic strata. Therefore, unlike the implications of many conventional models, the felsic volcanic rocks at Tambogrande are interpreted to have only played a passive role in VMS formation.
12

The genesis of ‘giant’ copper-zinc-gold-silver volcanogenic massive sulphide deposits at Tambogrande, Perú : age, tectonic setting, paleomorphology, lithogeochemistry, and radiogenic isotopes

Winter, Lawrence Stephen 11 1900 (has links)
The ‘giant’ Tambogrande volcanogenic massive sulphide (VMS) deposits within the Cretaceous Lancones basin of northwestern Perú are some of the largest Cu-Zn-Au-Ag-bearing massive sulphide deposits known. Limited research has been done on these deposits, hence the ore forming setting in which they developed and the key criteria that permitted such anomalous accumulation of base-metal sulphides are not understood. Based on field relationships in the host volcanic rocks and U-Pb geochronology, the deposits formed during the early stages of arc development in the latest Early Cretaceous and were related to an extensional and arc-rift phase (~105-100 Ma, phase 1). During this time, bimodal, primitive basalt-dominant volcanic rocks were erupted in a relatively deep marginal basin. Phase 1 rhyolite is tholeiitic, M-type, and considered to have formed from relatively high temperature, small batch magmas. The high heat flow and extensional setting extant during the initial stages of arc development were essential components for forming a VMS hydrothermal system. The subsequent phase 2 (~99-91 Ma) volcanic sequence comprises more evolved mafic rocks and similar, but more depleted, felsic rocks erupted in a relatively shallow marine setting. Phase 2 is interpreted to represent late-stage arc volcanism during a waning extensional regime and marked the transition to contractional tectonism. The Tambogrande deposits are particularly unusual amongst the ‘giant’ class of VMS deposits in that deposition largely occurred as seafloor mound-type and not by replacement of existing strata. Paleomorphology of the local depositional setting was defined by seafloor depressions controlled by syn-volcanic faults and rhyolitic volcanism. The depressions were the main controls on distribution and geometry of the deposits and, due to inherently confined hydrothermal venting, enhanced the efficiency of sulphide deposition. Geochemical and radiogenic isotope data indicate that the rhyolites in the VMS deposits were high temperature partial melts of the juvenile arc crust that had inherited the isotopic signatures of continental crust. Moreover, Pb isotope data suggest the metal budget was sourced almost wholly from mafic volcanic strata. Therefore, unlike the implications of many conventional models, the felsic volcanic rocks at Tambogrande are interpreted to have only played a passive role in VMS formation.
13

The genesis of ‘giant’ copper-zinc-gold-silver volcanogenic massive sulphide deposits at Tambogrande, Perú : age, tectonic setting, paleomorphology, lithogeochemistry, and radiogenic isotopes

Winter, Lawrence Stephen 11 1900 (has links)
The ‘giant’ Tambogrande volcanogenic massive sulphide (VMS) deposits within the Cretaceous Lancones basin of northwestern Perú are some of the largest Cu-Zn-Au-Ag-bearing massive sulphide deposits known. Limited research has been done on these deposits, hence the ore forming setting in which they developed and the key criteria that permitted such anomalous accumulation of base-metal sulphides are not understood. Based on field relationships in the host volcanic rocks and U-Pb geochronology, the deposits formed during the early stages of arc development in the latest Early Cretaceous and were related to an extensional and arc-rift phase (~105-100 Ma, phase 1). During this time, bimodal, primitive basalt-dominant volcanic rocks were erupted in a relatively deep marginal basin. Phase 1 rhyolite is tholeiitic, M-type, and considered to have formed from relatively high temperature, small batch magmas. The high heat flow and extensional setting extant during the initial stages of arc development were essential components for forming a VMS hydrothermal system. The subsequent phase 2 (~99-91 Ma) volcanic sequence comprises more evolved mafic rocks and similar, but more depleted, felsic rocks erupted in a relatively shallow marine setting. Phase 2 is interpreted to represent late-stage arc volcanism during a waning extensional regime and marked the transition to contractional tectonism. The Tambogrande deposits are particularly unusual amongst the ‘giant’ class of VMS deposits in that deposition largely occurred as seafloor mound-type and not by replacement of existing strata. Paleomorphology of the local depositional setting was defined by seafloor depressions controlled by syn-volcanic faults and rhyolitic volcanism. The depressions were the main controls on distribution and geometry of the deposits and, due to inherently confined hydrothermal venting, enhanced the efficiency of sulphide deposition. Geochemical and radiogenic isotope data indicate that the rhyolites in the VMS deposits were high temperature partial melts of the juvenile arc crust that had inherited the isotopic signatures of continental crust. Moreover, Pb isotope data suggest the metal budget was sourced almost wholly from mafic volcanic strata. Therefore, unlike the implications of many conventional models, the felsic volcanic rocks at Tambogrande are interpreted to have only played a passive role in VMS formation. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate
14

The magmatic-hydrothermal architecture of the Archean Volcanic Massive Sulfide (VMS) System at Panorama, Pilbara, Western Australia

Drieberg, Susan L. January 2003 (has links)
[Truncated abstract. Formulae and special characters can only be approximated here. Please see the pdf version of this abstract for an accurate representation.] The 3.24 Ga Panorama VMS District, located in the Pilbara Craton of Western Australia, is exposed as a cross-section through subvolcanic granite intrusions and a coeval submarine volcanic sequence that hosts Zn-Cu mineralization. The near-complete exposure across the district, the very low metamorphic grade, and the remarkable preservation of primary igneous and volcanic textures provides an unparalleled opportunity to examine the P-T-X-source evolution of a VMS ore-forming system and to assess the role of the subvolcanic intrusions as heat sources and/or metal contributors to the overlying VMS hydrothermal system. Detailed mapping of the Panorama VMS District has revealed seven major vein types related to the VMS hydrothermal system or to the subvolcanic intrusions. (1) Quartz-chalcopyrite veins, hosted in granophyric granite immediately beneath the granite-volcanic contact, formed prior to main stage VMS hydrothermal convection, and were precipitated from mixed H2OCO 2-NaCl-KCl fluids with variable salinities (2.5 to 8.5 wt% NaCl equiv). (2) Quartz-sericite veins, ubiquitous across the top 50m of the volcanic sequence, were formed from an Archean seawater with a salinity of 9.7 to 11.2 wt% NaCl equiv at temperatures of 90° to 135°C. These veins formed synchronous with the regional feldspar-sericite-quartz-ankerite alteration during seawater recharge into the main stage VMS hydrothermal convection cells. (3) Quartz-pyrite veins hosted in granophyric granite, and (4) quartz-carbonate-pyrite veins hosted in andesitebasalt, also formed from relatively unevolved Archean seawater (5.5 to 10.1 wt% NaCl equiv; 150° to 225°C), but during the collapse of the VMS hydrothermal system when cool, unmodified seawater invaded the top of the subvolcanic intrusions. (5) Quartz-topaz-muscovite greisen, (6) quartz-chlorite-chalcopyrite vein greisen, and (7) hydrothermal Cu-Zn-Sn veins are hosted in the subvolcanic intrusions. Primary H2O-NaCl-CaCl2 fluid inclusions in the vein greisens were complex high temperature hypersaline inclusions (up to 590°C and up to 56 wt% NaCl equiv). The H2O-CO2-NaCl fluid inclusions in the Cu-Zn-Sn veins have variable salinities, ranging from 4.9 to 14.1 wt% NaCl equiv, and homogenization temperatures ranging from 160° to 325°C. The hydrothermal quartz veins and magmatic metasomatic phases in the subvolcanic intrusions were formed from a magmatic-hydrothermal fluid that had evolved through wallrock reactions, cooling, and finally mixing with seawater-derived VMS hydrothermal fluids.

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