The deteriorating water quality in South Africa and changing legislation requiring the industrial implementation of waste minimisation and pollution prevention technologies has highlighted the need for the investigation of new effluent treatment technologies such as advanced oxidation processes. This investigation details the evaluation of ultrasound, an emerging advanced oxidation process, to degrade organic compounds during water treatment. The objectives of the investigation included the design of a suitable ultrasonic laboratory reactor to investigate ultrasound chemistry and the sub-processes occurring during sonication. Atrazine was used as a model compound to compare the performance of ultrasound with that of ozone and hydrogen peroxide, already established advanced oxidation processes. Recommendations have also been made for the scale-up of ultrasonic processes. A 500 mL ultrasonic cell containing an ultrasonic horn as an energy source was designed and constructed. The measurement of hydrogen peroxide concentration was used as a tool to indicate the process conditions under which the formation of free radical reactions during sonication are enhanced. These include the application of oxygen and air sparging or the addition of a commercial source of hydrogen peroxide. It was found that oxygen sparging and a high acoustic power input should be used in ultrasonic processes with a short retention time, and conversely, that air sparging and a lower acoustic energy source should be used in processes with a long retention time. A flow loop system should be considered to maximise oxidation both within and beyond the sonicated zone, gas sparging should only occur within the sonication zone else the degradation of hydrogen peroxide is encouraged. Ultrasound is most effectively applied in water treatment as a pretreatment stage in combination with other technologies and not as a stand-alone process. Atrazine was used. as a model compound to compare the performance of ultrasound with ozone because of its persistence in the environment and resistance to degradation. Atrazine was degraded during sonication and ozonation. degradation increased wim the addition of hydrogen peroxide. Ozone decomposition (and hence free radical reactions) was enhanced when ozone was combined with ultrasound or hydrogen peroxide. Enhanced ozone decomposition during ozonation combined with sonication is due to the conditions (high temperatures and pressures) as well as the free radical reactions occurring within the collapsing cavitation bubbles and at the gas-liquid interface. The enhancing effect of combining ultrasound with ozone was greatest at the low ozone concentrations typically applied during water treatment. Atrazine degradation during sonication and ozonation is predominantly due to the reaction with hydroxyl radicals. Atrazine degradation products identified using gas chromatography and mass spectrometry were deethylatrazine. hydroxyatrazine and deethyldeisopropylatrazine (tentatively identified). / Thesis (Ph.D.)-University of Natal, Durban, 2001.

Globally, water turbidity remains a crucial parameter in determining water quality. South Africa is largely regarded as arid and is often characterised by limited but high intensity rainfall. This characteristic renders most of the country’s water bodies turbid. Consequently, the use of turbidity as a measure of water quality is of great relevance in a South African context. Generally, turbidity alters biological and ecological characteristics of water bodies by inducing changes in among others temperature, oxygen levels and light penetration. These changes may affect aquatic life, ecosystem functioning and available water for industrial and domestic use. Siltation, a direct function of turbidity also impacts on the physical storage of dams and shortens their useful life. To date, determination of water turbidity relies on the tradition laboratory based methods that are often time consuming, expensive and labour intensive. This has increased the need for more cost effective means of determining water turbidity. In the recent past, the use of remote sensing techniques has emerged as a viable option in water quality assessment. Hyperspectral remote sensing characterizes numerous contiguous narrow bands that have great potential in water turbidity measurement. This study explored the applicability of hyperspectral data in water turbidity detection. It explored the visible and near-infrared region to select the optimal bands and indices for turbidity measurement. Using the Analytical Spectral Device (ASD) field spectroradiometer and a 2100Q portable turbidimeter, spectral reflectance and laboratory based turbidity measurements were taken from prepared turbid solutions of predetermined concentrations (i.e. 10g/l to 150g/l), respectively. The Pearson’s coefficient of correlation and R2 values were employed to select optimal spectral bands and indices. The findings showed a positive linear relationship between reflectance, the amount of soil in water and turbidity values. The strongest relationships came from bands 528, 489, 657, 1000 and 983, reporting adjusted R2 values of 0.7062, 0.7004, 0.6864, 0.7120 and 0.6961, respectively. The highest coefficient came from band 1000nm. The strongest indices were 625/440 and (770-1000)/(770+1000), with adjusted R2 values of 0.6822 and 0.6973 respectively. The use of hyperspectral data in turbidity detection is ideal for optimal band interrogation. Although good results were generated from this study, further investigations are needed in the near-infrared region. / Thesis (M.Env.Dev.)-University of KwaZulu-Natal, Pietermaritzburg, 2013.

Source water quality plays a critical role in maintaining the quality and supply of drinking water, yet it can be negatively affected by human activities. In Pennsylvania, coal mining and treatment of conventional oil and gas drilling produced wastewaters have affected source water quality for over 100 years. The recent unconventional natural gas development in the Marcellus Shale formation produces significant volumes of wastewater containing bromide and has the potential to affect source water quality and downstream drinking water quality. Wastewater from coal-fired power plants also contains bromide that may be released into source water. Increasing source water bromide presents a challenge as even small amounts of bromide in source water can lead to carcinogenic disinfection by-products (DBPs) in chlorinated finished drinking water. However, bromide is not regulated in source water and is not removed by conventional drinking water treatment processes. The objective of this work is to evaluate the safe bromide concentration in source water to minimize the cancer risk of trihalomethanes - a group of DBPs - in treated drinking water. By evaluating three years of water sampling data from the Monongahela River in Southwestern Pennsylvania, the present analysis reached three conclusions. First, bromide monitoring for source water quality should be taken at drinking water intake points. Water sample types (river water samples vs drinking water intake samples) can lead to different water quality conclusions and thus affect regulatory compliance decision-making. Second, bromide monitoring at drinking water intake points can serve as a predictor for changes in heavily brominated trihalomethanes concentrations in finished water. Increasing bromide in source water can serve as an early warning sign of increasing formation of heavily brominated trihalomethanes and their associated cancer risks in drinking water. Finally, this work developed a statistical simulation model to evaluate the effect of source water bromide on trihalomethane formation and speciation and to analyze the changing cancer risks in water associated with these changing bromide concentrations in the Monongahela River. The statistical simulation method proposed in this work leads to the conclusion that the bromide concentration in source water must be very low to prevent the adverse health effects associated with brominated trihalomethanes in chlorinated drinking water. This method can be used by water utilities to determine the bromide concentration in their source water that might indicate a need for process changes or by regulatory agencies to evaluate source water bromide issues.

The Lesotho Highlands Development Authority routinely uses the South African Scoring System version 4 (SASS4) in conjunction with water chemistry to monitor water quality of rivers in the Lesotho Highlands Water Project areas. The objective of this study was to test the efficiency of SASS4 in these areas.

<p>The Eerste River is a river system which has, over the years, been subjected to human interference. The purpose of this study was to investigatge temporal and spatial trends in the water quality of the Eerste River between 1990 and 2005. The study results revealed that the major trends in the water quality of the Eerste River are more spatial than temporal.</p>

Corrigenda pasted onto front end paper. / One folded col. map in pocket on back endpaper. / Bibliography: leaves 348-368. / xx, 368 leaves : ill. (some col.), maps (some col.) ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Develops a framework balancing water quality costs resulting from waterborne disease, disinfection by-product exposure and aesthetic concerns, against hydraulic costs, which include pipes, pumps and tanks. The genetic algorithms developed, successfully obtained the current optimal hydraulic solution, before adapting the model to incorporate water quality issues. / Thesis (Ph.D.)--University of Adelaide, Dept. of Civil and Environmental Engineering, 2000

Thesis (M.S.)--Humboldt State University, 2007. / Includes bibliographical references (leaves 25-27). Also available via Humboldt Digital Scholar.

Thesis (M.Env.Sc.-Res.)--University of Wollongong, 2007. / Typescript. Includes bibliographical references: leaf 99-104.

Major Paper (M.U.R.P.)--Virginia Polytechnic Institute and State University, 1993. / Abstract. Includes bibliographical references (leaves 68-71). Also available via the Internet.

Thesis (M.L.A.)--Mississippi State University. Department of Landscape Architecture. / Title from title screen. Includes bibliographical references.