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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Physical controls on water migration in above ground elemental sulphur blocks

Bonstrom, Kristie 25 April 2007
Elemental sulphur (S0) is produced from processing bitumen from the oil sands region, Alberta. Long term storage of this S0 is under consideration. The objective of the current study was to determine the controls on water migration in variably saturated S0 blocks. Based on visual observations of S0 blocks, they were characterized as a hydrophobic fractured porous media. Thus, measurements of the hydraulic characteristics, including porosity (n) and hydraulic conductivity (K) of the matrix and the fractured media, were undertaken. These data were used to create characteristic relationships of unsaturated K (Kunsat) and volumetric moisture content (è) change with change in positive injection pressure (Ø).<p>Analyses showed that the mean total matrix n (nm) was 0.094 ± 0.035 (n = 280), the mean n available for water migration (na) was 0.065 ± 0.044 (n = 8) and the mean (geometric) K for the matrix was 2.0 x 10-6 ± 2.1 x 10-6 ms-1. In the case of vertical fractures, the aperture frequencies were measured to be 2.5, 10.0 and 21.0 m-1 for fractures with apertures > 1.4, 1.4 to 0.6 and < 0.6 mm respectively while the frequency of horizontal fractures, were measured to be 1.7 and 3.7 m-1 for with apertures > 1.4, and < 1.4 mm respectively. The fracture n (nf) was determined to be 0.0135. è Ø relationships were determined for both the fractured and non fractured media. From these plots, water entry values of 9 mm and 1 m were determined for the fracture pore space and the matrix pore space, respectively.<p>Simulations of packer tests resulted in a bulk saturated K (Kb) values ranging from 8.5 x 10-5 to 2 x 10-4 ms-1 above 9 m depth and 3 x 10-6 to 1.5 x 10-5 ms-1 below 9 m depth. Coupled Kunsat Ø and è Ø relationships were used to conceptually describe water migration in S0 blocks under different precipitation and mounding conditions. These plots also showed that the Kb is dominated by the fractures.
2

Physical controls on water migration in above ground elemental sulphur blocks

Bonstrom, Kristie 25 April 2007 (has links)
Elemental sulphur (S0) is produced from processing bitumen from the oil sands region, Alberta. Long term storage of this S0 is under consideration. The objective of the current study was to determine the controls on water migration in variably saturated S0 blocks. Based on visual observations of S0 blocks, they were characterized as a hydrophobic fractured porous media. Thus, measurements of the hydraulic characteristics, including porosity (n) and hydraulic conductivity (K) of the matrix and the fractured media, were undertaken. These data were used to create characteristic relationships of unsaturated K (Kunsat) and volumetric moisture content (è) change with change in positive injection pressure (Ø).<p>Analyses showed that the mean total matrix n (nm) was 0.094 ± 0.035 (n = 280), the mean n available for water migration (na) was 0.065 ± 0.044 (n = 8) and the mean (geometric) K for the matrix was 2.0 x 10-6 ± 2.1 x 10-6 ms-1. In the case of vertical fractures, the aperture frequencies were measured to be 2.5, 10.0 and 21.0 m-1 for fractures with apertures > 1.4, 1.4 to 0.6 and < 0.6 mm respectively while the frequency of horizontal fractures, were measured to be 1.7 and 3.7 m-1 for with apertures > 1.4, and < 1.4 mm respectively. The fracture n (nf) was determined to be 0.0135. è Ø relationships were determined for both the fractured and non fractured media. From these plots, water entry values of 9 mm and 1 m were determined for the fracture pore space and the matrix pore space, respectively.<p>Simulations of packer tests resulted in a bulk saturated K (Kb) values ranging from 8.5 x 10-5 to 2 x 10-4 ms-1 above 9 m depth and 3 x 10-6 to 1.5 x 10-5 ms-1 below 9 m depth. Coupled Kunsat Ø and è Ø relationships were used to conceptually describe water migration in S0 blocks under different precipitation and mounding conditions. These plots also showed that the Kb is dominated by the fractures.

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