[Truncated abstract] The Collie River drainage basin is an important water resource catchment in southwestern Australia. Salinisation of a major water supply within the catchment, the Wellington Reservoir, has arisen due to changes in the water and salt balance in response to land clearing over saprolite aquifers. Paired catchment studies, the Collie Experimental Catchments (CECs), established in the early 1970’s in high and low rainfall areas increased our understanding of water and salt (predominantly chloride) movement in these aquifers through the collection and analysis of high resolution spatio-temporal data. However, the conceptual models developed from this work take little account of landscape heterogeneity, and this has caused problems in subsequent modelling studies, where success in calibrating stream flow has been countered by difficulties in predicting salt loads. The challenge remains to better describe variability in the Collie landscape and understand the influence of climate, vegetation, geology and geomorphology on observed water and salt fluxes. The release of salt from the lower saprolite aquifer and the role of the surficial aquifer in buffering groundwater discharge were investigated. The acquisition, analysis and interpretation of new regolith and geophysical data in 2001-2003 from the CECs, together with data from a high resolution digital elevation model, and existing drilling information, were used to construct a geologicalgeomorphological compartment framework, to observe changes in aquifer behaviour ... Significant differences in the salt flux from compartments have been noted at a range of scales, with implications for both water resource and land management. The approach developed to identify compartments and assess their efficiency could be simplified, using catchment critical parameters determined from geological and geomorphological characteristics. As a consequence, the implementation of a compartment framework in catchments with saprolite aquifers should allow for more informed decisions to be made in the selection of sites for revegetation strategies or the development of engineering works. This is particularly important in the Collie Catchment where reclamation scenarios are currently being discussed. Consideration of the catchment as a compartmentalised system would help manage salt loads in the Collie River and return the Wellington Reservoir to a functional water resource.

Includes bibliographical references (leaves 112-115) Towed DC Resistivity and Transient Electromagnetic arrays have been trialled for suitability in monitoring salt-loads on the Murray River at Waikerie, South Australia.

The Kat River is an agricultural catchment that drains salt rich geology. Potential salinity impacts on ecological condition of the river were investigated. Monthly salt concentrations and flow discharges were monitored at ten sites along the Kat River below the Kat Dam. Monthly salt loads were computed to relate salinity to land use and ionic data used to assess the toxicity of major salts using the TIMS model. Concentration duration curves for sodium chloride were derived from flow concentration relationships, representing sodium chloride concentrations to which the aquatic ecosystem had been exposed. The ecological condition was assessed at nineteen sites using SASS5 biotic index over four seasons. Finally, the modelled instream salt concentrations and bioasessments were evaluated in terms of the modelled level of species protection afforded at different salt concentrations. Species Sensitivity Distributions (SSDs) were used for this exercise. There was a general downstream increase in salinity with the minimum concentrations recorded at the Fairbain tributary (84 mg/L) and maximum levels at the sewage outfall in Fort Beaufort (1222 mg/L). There was evidence that citrus irrigation upstream of Fort Beaufort increased salinisation. Sodium chloride, and to a lesser extent magnesium sulphate, were the dominant salts in the Kat River catchment, with the latter being more toxic. However these had little or no impact on the aquatic ecosystem. Flow-derived sodium chloride concentrations showed that both the Balfour and Blinkwater tributaries were in a fair/ poor condition. However with regard to ecological condition, it was demonstrated that the river is generally in a good state except for the Blinkwater River and the lower catchment. Degraded habitat condition at the Blinkwater was responsible for poor ecological condition. Integrating SSD derived classes, sodium chloride classes and ecological condition indicated that sodium chloride is a driver of ecological condition at the sewage treatment works and the subsequent site (only two of nineteen biomonitoring sites).