Thesis (MEng)--University of South Australia, 1995

Thesis (MEng)--University of South Australia, 1995

Thesis (PhD in Metallurgical Engineering)--University of South Australia, 1996

The thesis presents a Finite Element Analysis (FEA) based wear modelling algorithm devised in the course of the reported research activity. FEA is used as a tool to calculate nodal pressures at the contact region for small sliding steps. These pressures are then inputted to a customised wear calculating routine. The routine uses averaged wear coefficients (wear rates) obtained from custom designed experiments. The FEA contact geometry is modified after each sliding step to account for the contact height decay, thus determining the volume loss due to wear over usage time, thus predicting the worn geometry. Consequently, the designer gains invaluable insight into the extent of wear-caused component deformation along with the number of usage cycles lapsed prior to such deformation.

Doctor of Philosophy / The drastic improvements in stiffness and strength even with the addition of small percentage of clay to a polymer are commonly traded-off with significant reductions in fracture toughness. It is believed that the presence of a stiff nano-filler will restrict the mobility of the surrounding matrix chains, and thus limit its ability to undergo plastic deformation, thereby decreasing their fracture toughness. To understand the role of rigid nano-fillers, like clay and their constraint effect on the surrounding polymer matrix, the effects of preferentially organized polyamide 6 lamellae in the vicinity of organoclay layers on the toughening processes are studied and compared with polyamide 6 filled with an elastomeric additive (POE-g-MA). It is suggested that to impart high toughness to polymer/organoclay nanocomposites, full debonding at the polymer-organoclay interface is necessary so that shear yielding of large volumes of matrix material can be enhanced. However, due to the strong tethering junctions between the individual organoclay layers and the matrix, full-scale debonding at the polymer-organoclay interface is rarely observed under stress conditions indicating that the constraint on the polymer adjacent to the clay is not relieved. Therefore, this has led to the development of ternary nanocomposites by adding a soft elastomeric dispersed phase to polymer/clay systems to obtain well-balanced mechanical properties. Polyamide 66/SEBS-g-MA/organoclay nanocomposites are prepared with four different blending protocols to understand the effect of blending protocol on the microstructure, mechanical properties and fracture mechanisms of the ternary nanocomposites so as to obtain new insights for producing better toughened polymer nanocomposites. In general, it is found that the level of enhancement of fracture toughness of ternary nanocomposites depends on: (i) the location and extent of dispersion of organoclay and (ii) the internal cavitation of rubber particles leading to effective relief of crack-tip tri-axial constraint and thus activating the matrix plastic deformation. Based on the wear/scratch damage studies on different polymer nanocomposite systems, it is suggested that elastic modulus and toughness of polymer nanocomposites are not the predominant factors controlling the material removal or friction coefficient and cannot be the sole indicators to compare and rank candidate materials. It is also found that nano-fillers by themselves, even if uniformly dispersed with good interfacial interaction with the matrix, do not irrevocably improve the wear (and friction) properties. Although it is important to consider these factors, it is necessary to thoroughly understand all microstructural parameters and their response to wear/scratch damage. Other important factors that should be considered are the formation of a uniform and stable transfer film on the counterface slider and the role of excessive organic surfactants or other modifiers added to disperse nanoparticles in a polymer matrix. It is also emphasized that the mechanisms of removal of materials during the wearing/scratching process should be studied meticulously with the use of high resolution microscopic and other analytical tools as this knowledge is critical to understand the surface integrity of polymer nanocomposites.

Thesis (PhD (Metallurgical Engineering))--University of South Australia, 1997

Thesis (M.S.)--Oregon Graduate Institute of Science and Technology, 1989.

Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1991. / Vita. Abstract. Includes bibliographical references (leaves 109-113). Also available via the Internet.

Thesis (M. S. in Mechanical Engineering)--Vanderbilt University, May 2009. / Title from title screen. Includes bibliographical references.

Thesis (M.S.)--Ohio University, August, 1992. / Title from PDF t.p.