Doctor of Philosophy / Department of Agronomy / Phillip W. Stahlman / Saflufenacil is an experimental herbicide for control of broadleaf weeds in various crops including several herbicide resistant weed biotypes. Wheat is highly tolerant to preplant and preemergence applications of saflufenacil, but winter wheat growers prefer to apply herbicides postemergence (POST) in early spring. Objectives of this research were to (1) evaluate winter wheat and four common broadleaf weed species response to POST treatments of saflufenacil applied alone and in combination with bentazon or auxin herbicides at various rates both with and without adjuvants, and to (2) determine the possible mechanism(s) responsible for crop safening observed when saflufenacil is applied with 2,4-D amine or bentazon in winter wheat. Growth chamber, greenhouse, and field studies showed saflufenacil at a minimum rate of 25 g/ha controlled blue mustard and flixweed >85% when saflufenacil was applied alone or mixed with dicamba, 2,4-D amine, 2,4-D ester, or MCPA ester. Also, mixtures of bentazon with 13 g/ha of saflufenacil resulted in death of kochia, but increasingly higher rates of 2,4-D amine were needed to achieve 90% growth reduction when saflufenacil rates were decreased from 50 to 25 to 13 g/ha. In general, most of the saflufenacil combinations tested controlled henbit <85%. Leaf necrosis and stunting of winter wheat were reduced by tank mixing saflufenacil with dicamba, 2,4-D amine, or bentazon, but not with MCPA ester or 2,4-D ester. Including nonionic surfactant (NIS) in mixtures of saflufenacil plus 2,4-D amine resulted in significant wheat injury similar or greater than injury caused by saflufenacil plus NIS. Finally, 2,4-D amine enhanced saflufenacil absorption into winter wheat plants, whereas bentazon reduced absorption of saflufenacil. No more than 11% of applied saflufenacil translocated out of treated leaves to other plant parts when applied alone or when saflufenacil was mixed with 2,4-D amine or bentazon. Metabolism of saflufenacil by wheat plants was not affected by tank mixing with bentazon, but saflufenacil metabolism was slowed by mixing with 2,4-D amine. Overall, these studies indicate saflufenacil can potentially be used POST in wheat at an optimum rate of 25 g/ha plus 2,4-D amine or dicamba to effectively control blue mustard and flixweed.

Doctor of Philosophy / Department of Agronomy / Dorivar Ruiz Diaz / Winter annual weeds (WAW) could affect nitrogen supply for corn production. The objectives of first study were to determine the diversity and abundance of WAW and to evaluate the effect of delaying herbicide applications on nitrogen supply and no-till corn response. Research was conducted in 2010 and 2011 at 14 sites in eastern Kansas. A factorial arrangement of three herbicide application dates (Nov.-Mar., April, and May) and five N rates were used. The three most abundant WAW across sites were henbit, purslane speedwell, and horseweed. Delaying herbicide application until April significantly reduced early corn N uptake by 52 mg N plant-1, chlorophyll meter readings at silking by 3.4%, and grain yield by 0.48 Mg ha-1 across sites. An additional 16 to 17 kg N ha-1 was needed to maintain yield if herbicide application was delayed until April. Starter and foliar micronutrient fertilization can potentially increase corn and soybean yield. The objectives of the second study were to evaluate crop response from combinations of starter and foliar fertilizers that contain N-P-K mixtures with and without a blend of micronutrients at four sites for each crop under irrigated conditions. No early corn growth or yield increase was attributed to application of micronutrients (Fe, Mn, Zn, Cu, and B) beyond what was achieved with N-P-K starter fertilization. There was an increase in soybean height (8 cm) and yield (293 kg ha-1) with starter fertilizer containing N-P-K plus micronutrients over the control. No increase in corn or soybean yield was obtained with foliar fertilization. The objective of the third study was to compare soil mobility and changes in soybean nutrient concentration in the leaf and seed from Mn and Zn sources (EDTA and oxysulfate) at two sites. Zinc sources were more mobile in the soil. Both Zn sources increased seed Zn concentration. Manganese oxysulfate increased seed Mn concentration. However, soybean trifoliolate leaf and seed Mn concentration decreased with soil-applied Na2EDTA and MnEDTA. This response was attributed to formation of FeEDTA and increased Fe supply that reduced root Mn absorption. Manganese EDTA is not recommended for soil application.