The removal of phenols from the waste waters of wood preserving plants has always presented problems. The purpose of this paper is to investigate the possibility of employing a biological system to reduce the phenol content of effluent from these plants.

The efficacy of biodiesel as a co-solvent for copper naphthenate wood preservative treating solutions was evaluated using two fungal decay methodologies (AWPA E10-09, British Standard Method EN113). Four fungal species (Gloeophyllum trabeum, Trametes versicolor, Poria xantha, Postia placenta) and three wood species (Douglas fir, Southern yellow pine, Western red cedar) with six replicates were utilized in both studies. Two levels of biodiesel: diesel (30:70 and 50:50) were compared to diesel-only solvent systems for copper naphthenate treating systems and treated to AWPA recommended retentions. No differences in decay efficacy between the biodiesel blends and diesel-only treatment in either the AWPA or the EN113 decay studies were detected for either standard method. Copper distribution was evaluated using SEM-EDX and no differences were noted with either solvent system. It was determined that the presence of biodiesel did not have a negative impact upon the efficacy of copper naphthenate as a wood preservative.

This research investigates interacting biological, chemical, and physical factors affecting the efficiency of microbiological wastewater treatment at the W. J. Smith Wood- Preserving Company in Denison, Texas. The treatment process consisted of collecting exhaust boiler water containing unidentified boiler treatment compounds, steam condensate contaminated with preservatives and wood extracts, plant process waters, and rainfall runoff from plant grounds. With a 5-minute residence time, wastewater was passed over 2 oxidation towers in series, each containing approximately 47,000 square feet of surface area. Suspended solids were removed from the wastewater before discharge. Various amino acids such as serine, aspartate, cysteine, phenylalanine, alanine, proline, glycine, histidine, and tyrosine significantly stimulated phenol degradation in the laboratory. The plant wastewater contained approximately 0.1 mg/l of several of the stimulatory amino acids. It was assumed that these concentrations provided maximal stimulation in the field situation. The plant wastewater also contained sufficient nitrogen to permit the organisms to degrade up to 100 mg phenol/1 of water examined. Amino acids in the wastewater probably serve as a source of microbial nutrition. Toxicity of the wastewater to fish was not caused by the presence of phenol, phenol degradation products, or traces of pentachlorophenol. The wastewater was rendered non-toxic by diluting with between 4 to 9 volumes of stream water. Toxicity could also be removed by chemical coagulation followed by activated carbon adsorption. As a result of biological treatment, the plant now discharges the treated wastewater into the municipal sewage treatment facility.