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Master of Science

This study investigated the use of activated carbon and ion exchange for the removal of color and dissolved solids from pulp and paper wastewater generated by the Union Camp Corporation mill in Franklin, Virginia. The objective of the treatment was to provide a high quality effluent suitable for direct recycling. This advanced treatment followed pretreatment by lime, alum, or ferric chloride. Required effluent quality was defined as being 5 Pt-Co units color and 75 mg/L chloride. Granular and powdered carbons, manufactured by the Westvaco Corporation, were utilized in the study. The ion exchange resin investigated was Amberlite IRA-68, manufactured by Rohm and Haas. Carbon treatment consisted of batch and column operation; ion exchange column treatment was used. The results of the study indicated that the required effluent quality was achieved by activated carbon and ion exchange treatment of wastewater that had been chemically pretreated. The most successful treatment schemes for the biotreated effluent were pretreatment with 500 mg/L alum or 2500 mg/L lime, followed by carbon column treatment for color polishing and ion exchange for chloride removal. The lime pretreated sample produced an effluent containing less than 5 Pt-Co units color as necessary for reuse, while the alum pretreated sample would require dilution with make-up water or additional treatment (i.e. ion exchange) to obtain recycle quality. The use of ion exchange for chloride removal is not practical due to the preferential exchange for sulfates. Until such time as sulfate can be eliminated from the wastewater source, other methods of dissolved solids removal should be investigated. / M. Eng.

no abstract provided by author / Master of Science

Ultrafiltration studies were conducted to determine a treatment approach to remove color and organic carbon from the pulp and paper wastewaters at the Union Camp Corporation, Franklin, VA. Analysis of data collected during this research indicate that ultrafiltration can produce an effluent with less than 5 color units and less than 5 mg/L TOC (99% and 97% removal respectively). The data also indicate that biotreatment of the wastes prior to ultrafiltration removes the smaller molecular weight organic compounds, making ultrafiltration more effective. Pretreatment by pH adjustment and alum coagulation were not effective in improving ultrafiltration performance. Concentration studies indicate that volume reductions up to 95% may be accomplished without excessive membrane fouling. Membrane cleaning with caustic, hypochlorite and detergent produced identical results. It is expected that ultrafiltration would be a more cost effective method of color and TOC removal than coagulation, and would not require sludge disposal. / M.S.