This thesis is focused around improving soil moisture estimates of spatial variability and mean at the field scale, which are useful for many different applications. The objectives were: (1) examine soil moisture spatial patterns and variability within field scale, and (2) compare field-scale soil moisture determination methods. An observational study was conducted, in which soil moisture was monitored over a 500 m by 500 m area during two and a half growing seasons at a prairie pasture in central Saskatchewan. Analysis of the spatial patterns of root-zone soil moisture revealed two distinct spatial patterns representing wet (spring) and dry (fall) periods. The relationship between spatial variability and mean soil moisture was found to follow an unusual concave trend, where variability was smallest at mid-range moisture contents. These spatial variability characteristics are a result of differences in participation level. Some locations were non-participating having only small moisture changes over the growing season, while others were dynamic having large changes. At the pasture site, these participation differences are a result of high soil heterogeneity, which may be characteristic of Solonetzic soils. In the second part of this thesis, methods to determine mean field-scale root-zone soil moisture were evaluated. The cosmic-ray neutron probe has the most potential for providing field-scale measurements. However, these measurements are only representative of moisture in the top 20 cm of soil, and need to be scaled up in order to represent the entire root-zone (0–110 cm). The three scaling methods applied to obtain lower root-zone soil moisture were: (1) a single time stable location, (2) representative landscape unit, where a single monitoring profile for each vegetation type was used, and (3) modeling by exponential filter. The representative landscape unit approach estimated soil moisture changes well, but not volumetric water content. The time stability method performed the best, followed by the exponential filter. However, the exponential filter has more potential, as the time stability method is difficult to apply to other field sites; particularly those without existing soil moisture instrumentation, due to its calibration requirements. The findings of this thesis make a contribution to the large body of existing literature on soil moisture variability and scaling. Suggestions for future research are provided.

Thesis ((MEng)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: When constructing a submarine pipeline, construction teams must work in the hostile environment in the ocean known as the surf zone. The surf zone is the area along a shoreline stretching between the first evident point of wave breaking and the beach line. In order to ensure that the pipeline is shielded from the imposing forces within the surf zone, engineers use a burial technique which leaves the pipeline length in the surf zone buried underneath the active seabed once construction is finished. Thus a temporary surf zone trench is dredged and protected by an open-ended cofferdam built using iron sheet piles. As a result of the incoming wave climate and the surf zone currents created by this wave climate, sedimentation in and around the trench becomes problematic. In this study alternative geometric layouts for the open-ended cofferdam protecting the surf zone trench are investigated, attempting to minimize the sediment build-up in and around the trench. This was done by using both a 3D qualitative physical model conducted at the CSIR in Stellenbosch, and numerical model using MIKE developed by DHI. However, this study only considers sediment build-up and not structural integrity and constructability of the cofferdam designs. Combining the observations of both the physical- and numerical models, a conclusion was drawn that a structure built perpendicular to the shoreline with a 45oextended arm built from the upstream edge of the cofferdam wall, is the most effective. No dimensions are given as the cofferdam design will change depending on the site specific characteristics. Also an increase in structure length will result in the mouth of the structure being located outside the active sediment zone, which leads to a longer period of time before the pipeline pathway is compromised by sediment. / AFRIKAANSE OPSOMMING: Tydens die konstruksie van 'n onderwaterse pyplyn, moet konstruksie spanne in 'n gevaarlike gedeelte van die see werk naamlik die brandersone. Die brandersone kan gedefinieer word as die area tussen die eerste punt waar branders breek en die strandlyn. Om die pyplyn te beskerm teen die kragte wat branders op dit uitoefen, gebruik ingenieurs 'n installasietegniek waar hul die brandersone seksie van die pyplyn onder die aktiewe seebodem begrawe. Om die tegniek te bewerkstellig, grawe kontrakteurs 'n sloot deur die brandersone en beskerm dit met 'n tydelike struktuur bekend as 'n kofferdam. As gevolg van die inkomende branders en die strome wat deur die branders aangedryf word, kan die opbou van sediment in, en rondom die sloot in die brandersone problematies word. Hierdie studie ondersoek alternatiewe uitlegte vir die tydelike kofferdam struktuur met die oog daarop om die opbou van sediment in, en rondom die struktuur te verminder. Die doel was nagestreef deur gebruik te maak van beide 'n 3-dimensionele fisiese model, gebou en gebruik by die WNNR in Stellenbosch, en 'n numeriese model wat op MIKE, ontwikkel deur DHI gedoen was. Let wel die studie het slegs die sediment beweging in die nabye area van die tydelike kofferdam struktuur in ag geneem en nie die praktiese implimentering en strukturele integriteit van die struktuur nie. Deur die observasies van beide die fisiese- en numeriese modelering in ag te neem, is die volgende gevolgtrekkings gemaak. 'n Struktuur wat loodreg met die strandlyn gebou is en met 'n 45o arm wat na die stroom-op kant toe uitstrek, was die mees effektiewe een. Geen dimensies is deurgegee nie aangesien die ontwerp sal verskil afhangende van die spesifieke area waar die projek aangepak word. Daar is ook gesien dat indien die struktuur langer gemaak word, sal die kontrakteur langer tyd h^e voordat daar sediment probleme in die brander sone sloot ondervind sal word.

No description available.

Mineralised shear zones in Otago are often truncated by regional low-angle faults, which juxtapose schist of different metamorphic grade. The Footwall Fault and the Hyde-Macraes Shear Zone are one example for this kind of tectonic setting, and are the subject to this study. Although, the mechanisms for the development of the mineralised thrust-origin shear zones are well studied, the relationship to the truncating faults is still poorly understood. Currently, the truncating low-angle faults are assumed to be related to crustal extension, starting in the early Cretaceous after the schist passed the ductile-brittle transition. This study presents new kinematic data for the Footwall Fault, suggesting development of normal sense movement under ductile conditions due to an abundant shear band cleavage in the footwall, which dynamically recrystallises quartz grains. However, brittle high-angle normal faults truncating these shear bands indicate either reactivation of normal sense movement after passing the ductile-brittle transition or continuous normal sense movement during the transition. Furthermore, this study presents a model, which suggests a regional scale rolling hinge development, consisting of an array of individual low-angle normal faults along the boundary of the textural zone change from TZ IV to TZIII, and strike-parallel high-angle faults at the NE margin of the Otago schist.

A continuum of rhyolite compositions has been observed throughout the Taupo Volcanic Zone (TVZ) over the past 550 kyr. reflecting changes in the ƒH2O, ƒO₂, and P-T conditions in a lower crustal 'hot-zone' (10-30 km) where these evolved melts are generated by crystal fractionation of successively intruded basaltic magmas. The rhyolite compositional continuum is bound by two distinct end-member types: R1 is characterized by hydrous minerals (hornblende ± biotite), low FeO*/MgO (calc-alkaline series), low MREE, Y, and Zr, and high Sr; and R2 is characterized by anhydrous minerals (orthopyroxene ± clinopyroxene), high FeO*/MgO (tholeiitic series), high MREE, Y, and Zr, and low Sr. Slab-derived aqueous fluid components (Ba, Cl) correlate well with oxygen fugacity, and other well defined characteristics of silicic magmas in the Taupo Volcanic Zone (TVZ) between a cold-wet-oxidizing magma type (R1: amphibole ± biotite; high Sr, low Zr and FeO*/MgO, depleted MREE) and a hot-dry-reducing magma type (R2: orthopyroxene ± clinopyroxene; low Sr, high Zr, and FeO*/MgO, less depleted MREE). Oxygen fugacity was obtained from analysis of Fe-Ti oxides and ranges between -0.039 to +2.054 log units (ΔQFM; where QFM = quartz + fayalite + magnetite buffer) and is positively correlated with the bulk-rock Ba/La ratio, indicating that slab-derived fluid is the oxidizing agent in the rhyolites. Chlorine contents in hornblende also correlate with the bulk-rock Ba/La ratio. Hence, high fluid-flux typically correlates with the R1 and low fluid-flux with R2 rhyolite magma types. A geochemical evolution and distribution can be tracked in time and space throughout the central region of the TVZ from 550 ka to present and has revealed two distinct magmatic cycles that vary in length. The first cycle included widespread R1 type magmatism across the central TVZ beginning ca. 550 ka and was directly associated with previously unreported dome-building and ignimbrite-forming volcanism, and led to a voluminous (>3000 km³) ignimbrite 'flare-up' between ca. 340 and 240 ka. These magmas also display the highest K₂O and Pb isotopic compositions compared to those erupted more recently, and is consistent with a peak in slab-derived sediment input. The second cycle began roughly 180 ka, erupting ca. 800 km³ of magma, and continues to the present. The duration, rate, and composition of melt production within these cycles appears to be governed by the flux of fluid/sediment released from the subducting slab, while the distribution of melts may be governed more by extension along the central rift axis. The Matahina Ignimbrite (~160 km³ rhyolite magma; 330 ka) was deposited during a caldera-forming eruption from the Okataina Volcanic Centre, TVZ. The outflow sheet is distributed primarily from the northeast to southeast and consists of a basal plinian fall member and three ash-flow members. Pumice clasts are separated into three groups defined by differences in bulk geochemistry and mineral contents: high CaO, MgO, Fe₂O₃T, TiO₂, and low Al₂O₃, +hornblende (A2), low CaO, MgO, Fe2O3T, TiO2, ±hornblende (A1), and a subset to A1, which has high-K, +biotite (B). Two types of crystal-rich mafic clasts were also deposited during the final stages of the eruption. The distinct A and B rhyolite magma types are petrogenetically related to corresponding type A and B andesitic magma by up to 50% crystal fractionation under varying ƒO₂-ƒH₂O conditions. Further variations in the low- to high-silica rhyolites can be accounted for by up to 25% crystal fractionation, again under distinct ƒO₂-ƒH₂O conditions. Reconstruction of the P-T-ƒO₂-ƒ’H₂O conditions of the andesite to rhyolite magmas are consistent with the existence of a compositional and thermal gradient prior to the eruption. Magma mingling/mixing between the basalt to andesite and main compositionally zoned rhyolitic magma occurred during caldera-collapse, modifying the least-evolved rhyolite at the bottom of the reservoir and effectively destroying the pre-eruptive gradients. A detailed examination of the diverse range of calcic-amphibole compositions from the ca. 330 ka Matahina eruption (ca. 160 km³ rhyolitic magma) of the Okataina Volcanic Complex, Taupo Volcanic Zone, including crystal-rich basalt to dacite pumice from post-collapse deposits, reveals several pre- and syn-eruption magmatic processes. (1) Amphibole phenocrysts in the basaltic-andesite and andesite crystallized at the highest pressures and temperatures (P: up to 0.6±0.06 GPa and T: up to 950°C), equivalent to mid-crustal depths (13-22 km). Inter- and intra-crystalline compositions range from Ti-magnesiohornblende → Ti-tschermakite → tschermakite → magnesiohornblende and some display gradual decreases in T from core to rim, both consistent with magma differentiation by cooling at depth. (2) The largest amphibole crystals from the basaltic-andesite to andesite display several core to rim increases in T (up to 70°C), indicating new hotter magma periodically fluxed the crystal mush. (3) The dominant population of amphibole (magnesiohornblende) from the rhyolite is small and bladed and crystallized at low P-T conditions (P: 0.3 GPa, T: 765°C), equivalent to the eruptive P-T conditions. Amphibole (tschermakite-magnesiohornblende) from the dacitic and low-silica rhyolitic pumice form two distinct populations, which nucleated at two different T (High: 820°C and Low: 750°C). These compositional variations, governed primarily by differences in T conditions during crystal growth, record the mixing of two distinct amphibole populations that approached a thermal equilibrium at the eruptive T. Therefore, the diversity in amphibole compositions can be reconciled as an exchange of crystals+liquid between the basaltic-andesite to dacite from the mid-crust and rhyolite from the upper-crust, which quenched against one another, modifying the dacite to low-silica rhyolite compositions as the eruption progressed.

The magnitude of contaminant mass flux reduction associated with a specific amount of contaminant mass removed is a key consideration for evaluating the effectiveness of a source-zone remediation effort. Thus, there is great interest in characterizing, estimating and predicting relationships between mass flux reduction and mass removal. Intermediate-scale flow- cell experiments and published data for several field studies were examined to evaluate factors controlling the mass-flux-reduction/mass-removal relationship. Flow-cell experiments evaluated the impact of source-zone architecture and flow-field heterogeneity on mass-flux-reduction/mass-removal behavior. Significant reductions in mass flux occurred for systems wherein immiscible-liquid mass was present at both residual saturation and in high saturation pools. For a system with immiscible liquid present in multiple zones of different permeability, an increase in mass flux was observed for late stages of mass removal. Image analysis confirmed that the late stage increase in mass flux was attributed to changes in relative permeability. Early reductions in mass flux were also observed for systems wherein immiscible-liquid mass was poorly accessible to flowing water. End-point analysis, based on comparing masses and mass fluxes measured before and after a source-zone remediation effort, conducted for 21 field remediation projects ranged from slightly less than to slightly greater than one-to-one. Time-continuous analysis, based on continuous monitoring of mass removal and mass flux, performed for two sites illustrated the dependence of the mass-flux-reduction/mass-removal relationship on source-zone architecture and mass-transfer processes. Minimal mass flux reduction was observed for a system wherein mass removal was relatively efficient. Conversely, a significant degree of mass flux reduction was observed for a site wherein mass removal was inefficient. A simple mass-removal function was used to evaluate the measured data at both the intermediate and field scales. This function was unable to capture the complex behavior observed for some of the systems unless specific measurable system parameters were incorporated into the function. Finally, mathematical models of varying complexity used to simulate immiscible liquid dissolution illustrated the dependence of the calibrated dissolution rate coefficient on implicit and explicit consideration of larger-scale factors influencing immiscible liquid dissolution.

A primary goal of paleoclimatology is to extend the instrumental record to capture a wider range of natural variability, documenting the climate system's response to past changes that have no analog in the historical record. Sediment archives of the recent geologic past, both marine and lacustrine, offer the opportunity to study how climate responds to a range of forcings and changing boundary conditions on timescales ranging from years to millennia. In this dissertation I use lacustrine and marine sediment to investigate changes late Quaternary climate, with particular focus on the Last Interglacial period (LIG). First, I use multiple approaches to reconstruct long-term changes in the West African Monsoon by investigating centennial-scale hydrologic variability recorded in Lake Bosumtwi sediments over the past 530,000 years. Over this interval, hydrology in the region is driven by a complex interplay of orbital forcing and glacial-interglacial boundary conditions. Lake level was generally much lower between 50 and 300 ka, likely due to the redistribution of rainfall from the tropics to the subtropics, driven by eccentricity's amplification of precession. Consequently, the Holocene highstand at the lake was both larger and longer lived than the maximum highstand during the LIG.Annual layers were continuously deposited through the LIG in Lake Bosumtwi, and I also present a new, 12,100 year-long, varve record spanning the interval from 128.6 to 116.5 ka. Over the course of the LIG, lake level generally tracks sea surface temperatures (SST) in Gulf of Guinea, including an abrupt drop in lake level that lasted about 500 years ca. 118 ka, coincident with cool SSTs in the North Atlantic and severe aridity in Europe. I find that the despite the generally drier conditions, hydrology varied on similar timescales as the late Holocene, with pronounced multidecadal to centennial-scale variability with non-stationary periodicities. I also investigate the contribution of ocean thermal expansion to sea level rise during the LIG, using a synthesis of paleoceanographic data and a climate model simulation. Globally, LIG SSTs were similar to, or slightly cooler than late Holocene SSTs, with the exception of the North Atlantic, which was several degrees warmer. Consequently, thermal expansion was likely a minor component of sea level rise during the interval, explaining between -0.3 and 0.4 m. of the 6 to 8 m highstand. Lastly, I tested the potential of Raman spectroscopy as a new, non-destructive technique to rapidly measure oxygen isotopic ratios in carbonates at extremely high resolution. Analyses on a suite a synthetic calcites indicate that ¹⁸O/¹⁶O ratios can be measured directly from the Raman spectra and have a 1:1 correspondence with traditional mass-spectrometry measurements. At present, the technique does not have the precision necessary to record natural variability, although there is considerable potential for improving the precision of the technique.

No description available.

No description available.

A study was made of the feasibility of putting hazardous area classification (HAC) on a more quantitative basis. A review of current HAC practice showed that the widespread policy of setting fixed zone distances around sources of hazard was subjective and sometimes led to inconsistencies between different codes of practice when applied to the same situation. Fatality and injury statistics were used to show that there is a significant risk to workers from the ignition of flammable atmospheres. which should be reduced. Data were researched and compiled to fit into a proposed framework for the quantification of HAC. These included information concerning leak source inventory: source leak frequency: and source leak size distribution. Mathematical models were collected which could be used to describe the emission and dispersion of flammable releases. Example calculations were performed for typical leak scenarios to illustrate the variation in hazard distances. Estimates were made of the ignition and explosion probabilities of flammable leaks. which depended princi pally on emission size. To compensate for uncertainties in the researched data. a fire and explosion model was devised to estimate the ignition frequency on a typical process plant. The model was applied to a "standard" plant which was formulated from researched data. By iteratively checking the estimated ignition frequencies against historical data it was concluded that reasonable agreement was achieved with some adjustment of the input data. The special problems of HAC of indoor plants were also addressed. It was concluded that the results of this study provided a basic framework for the quantification of HAC. although the quality of currently available data necessary for quantification is generally poor. The acquisition of better quality leak and ignition data should provide a platform from which the current work may progress. Further work should include the further refinement of the basic fire and explosion model to account for ignitions which HAC cannot protect against such as autoignitions. It was also noted that the behaviour of indoor releases requires clarification. together with the concept of a minimum flammable inventory below which there is negligible risk of ignition.