Yes / A highly enantioselective rhodium catalysed asymmetric arylation
(RCAA) of nitroolefins with arylboronic acids is presented using
a newly developed, C1-symmetric, non-covalent interacted,
phellandrene derived, nordehydroabietyl amide-containing chiral
diene under mild conditions. Stereoelectronic effects were
studied, suggesting an activation of the bound substrate through
the secondary amide as a hydrogen-bond donor.
| Identifer | oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/17848 |
| Date | 02 June 2020 |
| Creators | Li, R., Wen, Z., Wu, Na |
| Source Sets | Bradford Scholars |
| Language | English |
| Detected Language | English |
| Type | Article, Accepted manuscript |
| Rights | (c) 2016 RSC. Full-text reproduced in accordance with the publisher's self-archiving policy., Unspecified |
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