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Formation mechanism of plateau, rapid fall and tail in phosphorus diffusion profile in silicon based on the pair diffusion models of vacancy mechanism and interstitial mechanism

P diffuses predominantly by the interstitial mechanism in Si. Assuming that there is a strong binding energy between P and I, therefore, the basic process of P diffusion is the diffusion of (PI), where I and (PI) represent self-interstitials and P-I pairs, respectively. In the high-P-concentration region, excess I is generated by the dissociation of (PI) and the limiting process of P diffusion depends on whether or not excess I is controlled. That is, if the concentration of excess I decreases relatively to the equilibrium I concentration due to the effect of the decrease in quasi self-interstitial formation energy, or if excess I is removed by the recombination with vacancies, P diffuses fast and the plateau is
formed; if not, P diffuses slowly and the rapid fall is formed. In the tail region, the P concentration is low and the limiting process of P diffusion is the basic process of P diffusion, that is, the diffusion of (PI). Excess I generated in the high-P-concentration region diffuses into the low-P-concentration region, and I is supersaturated there. Therefore, the concentration of (PI) increases, resulting in the fast diffusion of P and the formation of the tail.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:15-qucosa-197759
Date17 February 2016
CreatorsYoshida, Masayuki, Morooka, Masami, Tanaka, Shuji, Takahashi, Manabu
ContributorsYoshida Semiconductor Laboratory,, Fukuoka Institute of Technology,, Universität Leipzig, Fakultät für Physik und Geowissenschaften
PublisherUniversitätsbibliothek Leipzig
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article
Formatapplication/pdf
SourceDiffusion fundamentals 1 (2005) 3, S. 1-17

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