Following the renewed interest in the volatile inventory of the Moon witnessed in the last decade, from both sample studies and data from orbital missions, it is timely to reassess the distribution and likely source(s) of light element volatiles (C, N, He, Ne, and Ar) in a diverse suite of lunar mare basalts and soils, providing new insights about volatiles indigenous to the lunar interior, volatiles produced <i>in situ</i> at the lunar surface, and volatiles delivered to and implanted into the lunar surface. Simultaneous static-mode mass spectrometric measurements of these key volatiles, extracted from the same aliquot of sample by high-resolution stepped combustion, enable a more detailed identification of the different volatile components present by comparing their varying release patterns across a range of temperature steps. Taken in context with other studies of different volatile elements, this new data contributes towards a greater understanding of the Earth-Moon system, with additional implications for future <i>in situ</i> resource utilisation at the lunar surface. With an average δ<sup>15</sup>N value of +0.93 ± 9.39 ‰, the indigenous N component measured in mare basalts is most compatible with a CO carbonaceous chondrite source for nitrogen in the lunar interior, although some caveats exist. Variations in abundance and isotopic composition of indigenous nitrogen imply a heterogeneous lunar mantle. Assuming up to ~50 % loss of solar wind <sup>36</sup>Ar from lunar soils, nitrogen trapped in soils can be reconciled with up to 87 % being contributed from a non-solar source with an isotopic composition of between +87 ‰ and +160 ‰. Noble gases in soils are dominated by solar wind components, with only minor amounts of cosmogenic neon being released at the highest temperature steps. In mare basalts, noble gases are a mixture of trapped, radiogenic, and cosmogenic components (from which cosmogenic production rates can be calculated) and exposure ages for previously undated samples suggested.
Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:722513 |
Date | January 2016 |
Creators | Mortimer, James |
Publisher | Open University |
Source Sets | Ethos UK |
Detected Language | English |
Type | Electronic Thesis or Dissertation |
Source | http://oro.open.ac.uk/50419/ |
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