Novel bifunctional metal-loaded polymer–silica composite (PSC) catalysts were investigated
in the hydrodeoxygenation (HDO) of 4-(2-furyl)-3-buten-2-one (FAc) as a model substance for
furfural–acetone aldol condensation products. PSC catalysts were synthesized via a sol–gel method
with different polymer contents and subsequently doped with different noble metals. The product
composition of the HDO of FAc could be tuned by using catalysts with different polymer (i.e., acidic
properties) and metal content (i.e., redox properties), showing the great potential of metal-loaded PSC
materials as tunable catalysts in biomass conversions with complex reaction networks. Furthermore,
high yields (>90%) of the fully hydrodeoxygenated product (n-octane) could be obtained using noble
metal-loaded PSC catalysts in only 8 h of reaction time.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:84607 |
| Date | 06 April 2023 |
| Creators | Goepel, Michael, Ramos, Ruben, Gläser, Roger, Kubiˇcka, David |
| Publisher | MDPI |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | 2076-3417, 2438 |
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