This thesis presents a new developed method for first intermolecular aldehyde/ketone cross benzoin coupling. Protected & / #945 / -keto tertiary alcohols are synthesized starting from easily available acyl phosphonates and ketones via Brook rearrangement in the presence of catalytic amount of cyanide ion. The scopes and the limitations of the methods for the synthesis of tertiary alcohols with & / #945 / -keto group are discovered.
| Identifer | oai:union.ndltd.org:METU/oai:etd.lib.metu.edu.tr:http://etd.lib.metu.edu.tr/upload/3/12609441/index.pdf |
| Date | 01 April 2008 |
| Creators | Esiringu, Ilker |
| Contributors | Demir, Ayhan Sidki |
| Publisher | METU |
| Source Sets | Middle East Technical Univ. |
| Language | English |
| Detected Language | English |
| Type | M.S. Thesis |
| Format | text/pdf |
| Rights | To liberate the content for public access |
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