Due to entropy and Van der Waals¡¦ interaction, carbon nanotubes tend to aggregate degrading their excellent opto-electronic properties and limiting their applications. Chemical derivatizations were applied to the multi-wall carbon nanotube (MWCNT) by esterificating with different lengths of aliphatic pendants (COOC4H9, COOC10H21, and COOC18H37) to decrease the MWCNT aspect ratio to facilitate its dispersion, and to observe its percolation behavior. FTIR analysis revealed the more relevant absorption peaks of C-H at 2917 cm-1, 2846 cm-1 and C=O at 1733 cm-1 from the derivatization. H1-NMR showed that the aliphatic pendant functionalized MWCNT from the signals of OCH2 at £_ = 3.64 ppm, CH2 at £_ = 1.25 ppm, and CH3 at £_ = 0.88 ppm. Raman scattering indicated that esterification caused the ID/IG absorption peak area ratio to decrease.
In applications, the electric conductivity was measured on thin-films of MWCNT:Poly-(3-hexylthiophene) (P3HT) as a function of nanotube content. Accompanied with nanotube doping concentration increased, the electric conductivity parallel to film surface (£m||) could range from an undoped value 1.4¡Ñ10-6 S/cm up to 1.2¡Ñ10-2 S/cm. The conductivity percolation threshold concentration decreased as the MWCNT aspect ratio increased due to the average distance between the nanotubes becoming sufficiently small for charges to hopping through P3HT. By incorporating [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM), bulk heterojunction photovoltaic (PV) cells of ITO/PEDOT:PSS/MWCNT:[PC61BM:P3HT]/LiF/Al were fabricated. By varying the ratio of MWCNT to the PC61BM:P3HT (0.8:1) mixtures, the PV cells showed the maximum power conversion efficiency (£bp) close to 4 % with MWCNT-COOC4H9 at a doping concentration of 0.01 wt. %.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0624110-124519 |
| Date | 24 June 2010 |
| Creators | Chen, Ying-ren |
| Contributors | M. Chen, S. J. Bai, S. W. Kuo, B. H. Tseng |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0624110-124519 |
| Rights | campus_withheld, Copyright information available at source archive |
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