We investigate chaotic ionization of highly excited hydrogen atom in crossed electric and magnetic fields (Rydberg atom) and intra-molecular relaxation in planar carbonyl sulfide (OCS) molecule. The underlying theoretical framework of our studies is dynamical systems theory and periodic orbit theory. These theories offer formulae to compute expectation values of observables in chaotic systems with best accuracy available in given circumstances, however they require to have a good control and reliable numerical tools to compute unstable periodic orbits. We have developed such methods of computation and partitioning of the phase space of hydrogen atom in crossed at right angles electric and magnetic fields, represented by a two degree of freedom (dof) Hamiltonian system. We discuss extensions to a 3-dof setting by developing the methodology to compute unstable invariant tori, and applying it to the planar OCS, represented by a 3-dof Hamiltonian. We find such tori important in explaining anomalous relaxation rates in chemical reactions. Their potential application in Transition State Theory is discussed.
| Identifer | oai:union.ndltd.org:GATECH/oai:smartech.gatech.edu:1853/19809 |
| Date | 20 November 2007 |
| Creators | Paskauskas, Rytis |
| Publisher | Georgia Institute of Technology |
| Source Sets | Georgia Tech Electronic Thesis and Dissertation Archive |
| Detected Language | English |
| Type | Dissertation |
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