A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins

Description

Yes / A highly enantioselective rhodium catalysed asymmetric arylation
(RCAA) of nitroolefins with arylboronic acids is presented using
a newly developed, C1-symmetric, non-covalent interacted,
phellandrene derived, nordehydroabietyl amide-containing chiral
diene under mild conditions. Stereoelectronic effects were
studied, suggesting an activation of the bound substrate through
the secondary amide as a hydrogen-bond donor.

Links & Downloads

1. Li R, Wen Z and Wu N (2016) A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins. Organic and Biomolecular Chemistry. 14(47): 11080-11084.
2. http://hdl.handle.net/10454/17848
3. https://doi.org/10.1039/C6OB02202B

Tags

Nordehydroabietyl amide

Chiral diene

RCAA

Rhodium-catalysed asymmetric arylation

Additional Fields

Identifer	oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/17848
Date	02 June 2020
Creators	Li, R., Wen, Z., Wu, Na (Anna)
Source Sets	Bradford Scholars
Language	English
Detected Language	English
Type	Article, Accepted manuscript
Rights	(c) 2016 RSC. Full-text reproduced in accordance with the publisher's self-archiving policy., Unspecified