The (2+2) cycloaddition of ketenes and trimethylsilyl enol ethers was found to proceed in good yield to give trimethylsiloxycyclobutanones of unique and interesting regiochemistry and stereochemistry. As electron-rich activated olefins, the trimethylsilyl enol ethers readily reacted with the electron-deficient ketenes.
Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc332660 |
Date | 12 1900 |
Creators | Lloyd, Robert Michael |
Contributors | Brady, William Thomas, Norton, S. J., Jones, Paul R., Desiderato, Robert |
Publisher | North Texas State University |
Source Sets | University of North Texas |
Language | English |
Detected Language | English |
Type | Thesis or Dissertation |
Format | Text |
Rights | Public, Lloyd, Robert Michael, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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