In this work we report the application of a recently developed experimental protocol using Pulsed Field Gradient (PFG) Nuclear Magnetic Resonance (NMR) techniques to simultaneously assess bulk pore and surface diffusion coefficients in liquid saturated
porous catalysts. This method has been developed to study solvent effects on the diffusion of methyl ethyl ketone (MEK) in mesoporous 1 wt% Pd/Al2O3 catalyst trilobes. The selection of solvents used in this work is known to have a complex effect on reaction rates and hence catalyst performance in heterogeneous liquid phase catalysis. Here, we report the bulk pore and surface diffusion characteristics of MEK, water and isopropyl alcohol (IPA) in 1 wt% Pd/Al2O3 catalyst trilobes. The results show that the physicochemical interactions of molecules in the porous catalyst matrix are very different for the different molecules. We also find that the mobility of water appears to be affected strongest by the catalyst surface.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:14094 |
| Date | January 2009 |
| Creators | Weber, Daniel, Mantle, Michael D., Sederman, Andrew J., Gladden, Lynn F. |
| Contributors | University of Cambridge, Universität Leipzig |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
| Source | Diffusion fundamentals 10 (2009) 5, S. 1-3 |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | urn:nbn:de:bsz:15-qucosa-179075, qucosa:13505 |
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