Organic and molecular electronics is a promising field for many applications, particularly flexible electronics, since it allows for the processing of electronic circuits at low temperatures on a variety of different substrates, including flexible sheets. Despite continuous improvements in the charge carrier mobility of both n- and p-type thin-film transistors, the performance of these devices is not yet attractive for commercial applications. A substantial hurdle to the realization of effective organic-based digital circuits is the lack of scalable, reproducible high-charge carrier-mobility organic semiconductors with a low contact resistance and controllable threshold voltage in transistors.
The threshold voltage control is required to optimize the performance of digital circuits. Previous approaches used doping or self-assembled monolayers to provide threshold voltage control in organic field-effect transistors (OFETs). However, neither of these methods offers a proper fine-tuning of the threshold voltage or a substantial on/off ratio. Both of these problems have been successfully solved in inorganic electronics by using the concept of remote doping. This doping results in a so-called modulation-doped field-effect transistor (MODFET).
Thus, in the first part of this work, we present the concept of remote doping for controlling and fine-tuning the threshold voltage without compromising charge carrier mobility by using a hole-type conduction architecture at the junction between two organic semiconductors.
The second part of this work is dedicated to developing, fabricating, and characterizing high-mobility single and polycrystalline rubrene OFETs by using scalable growth methods.
Finally, in the last part, we apply the knowledge gained from the first two parts and design digital circuits of rubrene OFETs aiming for high-frequency applications.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:81177 |
| Date | 10 October 2022 |
| Creators | Lashkov, Ilia A. |
| Contributors | Leo, Karl, Mannsfeld, Stefan C. B., Technische Universität Dresden |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:doctoralThesis, info:eu-repo/semantics/doctoralThesis, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
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