A new POCOP pincer-type ligand was synthesized and characterized. This new ligand gave rise to the first POCOP pyridylidene pincer-type ruthenium and iridium complexes. Investigations into structural and electronic parameters of these newly generated compounds were conducted. Furthermore, we prepared ruthenium dihydrogen and bis-dihydrogen complexes and studied them via deuterium labelling and low temperature NMR spectroscopy. These complexes were screened for catalysis in C-C coupling, C-H bond activation and ketone hydrogenation reactions.
| Identifer | oai:union.ndltd.org:WATERLOO/oai:uwspace.uwaterloo.ca:10012/4651 |
| Date | 19 August 2009 |
| Creators | Athanasopoulos, Aristidis Pantelis Telly |
| Source Sets | University of Waterloo Electronic Theses Repository |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
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