This thesis describes the application of macro, micro, ultra-microelectrodes and microelectrode arrays to the measurement of trace concentrations of nickel and cobalt in sediment and natural waters by adsorptive cathodic stripping voltammetric methods. In addition the measurement of tin by adsorptive cathodic stripping voltammetry in sediment and natural waters is discussed. Also, the application of macroelectrodes and microelectrode arrays to the measurement of lead, cadmium and zinc in sediment and natural waters by anodic stripping voltammetry is considered. In all cases the determination of the six metals was optimised by investigating the influence of various significant parameters, such as in-situ mercury plating, complexing agent concentration, scan rate, pulse height, accumulation time and potential, buffer concentration and pH. The results obtained for these investigations are discussed in this thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:ADTP/235090 |
| Date | January 1999 |
| Creators | Hadjichari, Andrew Michael, University of Western Sydney, School of Civic Engineering and Environment |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Source | THESIS_XXXX_CEE_Hadjichari_A.xml |
Page generated in 0.0082 seconds