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New cylindrical near-field electrospun PVDF fibers

In this study, a cylindrical near-field electrospining (CNFES) process will be used to fabricate permanent piezoelectricity of polyvinylidene fluoride (PVDF) piezoelectric fibers, and a piezoelectric fiber harvesting device with parallel electrode was fabricated to capture ambient energy. First, the PVDF powder was mixed in acetone solution uniformly and the dimethyl sulfoxide (DMSO) was mixed with fluorosurfactant to prepare PVDF macromolecular solution. The PVDF macromolecular solution was filled in a metals needle injector and contacted a high power supply, after the PVDF drops in the needle was subjected to high electric field, the drops became a Taylor cone and overcame surface tension of the solution itself, extremely fine PVDF fiber was formed and jetted out. The fibers were collected numerous and quickly by homemade cylindrical collector and the diameter of fiber could be controlled easily by adjusting the rotating speed of the cylinder and the electric field. From the observation of XRD (X-ray diffraction), it reveals a high diffraction peak at 2£c=20.7¢X of piezoelectric crystal £]-phase structure by adjusting PVDF concentrations and DC voltage. By providing 7Hz shake and 0.23% strain, the piezoelectric fiber harvesting device with parallel electrode could generate 76mV; by providing 7Hz shake and 0.14% strain, the device could generate 1.1nA.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0813112-141632
Date13 August 2012
CreatorsOu, Zong-Yu
ContributorsM. L. Wu, C. T. Pan, J. C. Huang, S. C. Huang
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0813112-141632
Rightsuser_define, Copyright information available at source archive

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