Structural determinations and electrochemical properties in the series of multinuclear ferrocenyl-ethynyl complexes with formula [(£b5-C5(CH3)5)(P2)MII-C¡ÝC-(fc)n-C¡ÝC-MII(P2)(£b5-C5(CH3)5)] (fc = ferrocenyl; M = Fe(II), Ru(II), Os(II); R = H, CH3; P2 = Ph2PCH2CH2PPh2 (dppe)) are reported. Complexes with more electron-rich ligand environment, were prepared with regard to the understanding of electronic coupling mechanism. These complexes undergo sequential reversible oxidation events from -0.2 V to 1.0 V referred to the Ag/AgCl electrode in
anhydrous CH2Cl2 solution and the low-pontential waves have been assigned to the end-capped metallic centers. The magnitude of the electronic coupling between two terminal metallic centers in the series of complexes was estimated by electrochemical technique. Based on the
correlation between the £GE1/2 values and the second redox potentials of the end-capping metallic centers in the series of complexes, a qualitative explanation for the different magnitude of the electronic coupling is
given.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0817109-103935 |
| Date | 17 August 2009 |
| Creators | Kuo, Chun-Ting |
| Contributors | Lan-Chang Liang, Teng-Yuan Dong, Chin-Hsing Chou |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0817109-103935 |
| Rights | unrestricted, Copyright information available at source archive |
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