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Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery

Two new mesoporous metal–organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal–organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm³ gˉ¹ and a specific BET surface area of 4081 and 6344 m² gˉ¹, respectively, and high gas uptake at room temperature and high pressure.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:36046
Date19 December 2019
CreatorsStoeck, Ulrich, Senkoska, Irena, Bon, Volodymyr, Krause, Simon, Kaskel, Stefan
PublisherRoyal Society of Chemistry
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Rightsinfo:eu-repo/semantics/openAccess
Relation1364-548X, 10.1039/c4cc07920e

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