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Previous issue date: 2012-10-25 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / In general, among the corrosion inhibitors surfactants are the most commonly used compounds, because they are significantly effective by forming protective films on anodic and cathodic areas. In this study, microemulsions containing he biodegradable saponified coconut oil as surfactant (SME-OCS) was used as green corrosion inhibitors. With this purpose, methanolic extracts of Ixora coccinea Linn (IC) and a polar fraction rich in alkaloids (FA) obtained from Croton cajucara Benth solubilized in the SME-OCS system were examined in the presence of AISI 1020 carbon steel, in saline solution (NaCl 3,5 %). The efficiency of corrosion inhibition of IC and FA were evaluated in the following microemulsions: SME-OCS-IC and SME-OCS-FA. The microemulsion system SME-OCS in the presence and absence of IC and FA was assessed by measurements of weight loss and the electrochemical method of polarization resistance, with variation in the concentration of IC and FA (50 - 400 ppm), showing significant results of corrosion inhibition (83,6 % SME-OCS; 92,2 % SME-OCS-FA; and 95,3 % SME-OCS-IC) / Em linhas gerais, dentre os inibidores de corros?o mais utilizados se encontram os tensoativos, que s?o significantemente eficazes por formarem pel?culas protetoras sobre ?reas an?dicas e cat?dicas. No presente trabalho, utilizou-se o tensoativo biodegrad?vel ?leo de coco saponificado microemulsionado (SME-OCS) para aplicabilidade como inibidor verde de corros?o. Para tanto, o extrato metan?lico de Ixora coccinea Linn (IC) e uma fra??o polar rica em alcaloides (FA) obtida de Croton cajucara Benth, solubilizados no sistema SME-OCS, foram avaliados na presen?a do a?o carbono AISI 1020, em meio salino (NaCl 3,5 %). Desta forma, as efici?ncias de inibi??es ? corros?o de IC e FA foram avaliadas nas seguintes microemuls?es: SME-OCS-IC e SME-OCS-FA. O sistema microemulsionado SME-OCS na presen?a e na aus?ncia de IC e FA foi avaliado por medidas de perda de massa e pelo m?todo eletroqu?mico de resist?ncia ? polariza??o, com varia??o da concentra??o dos vegetais IC e FA (50 400 ppm), tendo sido obtidos resultados significativos de inibi??es ? corros?o (83,6 % SME-OCS, 92,2 % SME-OCS-FA e 95,3 % SME-OCS-IC)
Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/12760 |
Date | 25 October 2012 |
Creators | Almeida, C?ssia Carvalho de |
Contributors | CPF:06117988320, http://lattes.cnpq.br/3318871716111536, Gurgel, Alexandre, CPF:59721421472, http://lattes.cnpq.br/5266735277153768, Rossi, C?tia Guaraciara Fernandes Teixeira, CPF:77044568491, http://lattes.cnpq.br/0103853142184734, Maciel, Maria Aparecida Medeiros, CPF:37320165449, http://lattes.cnpq.br/5360188002708095, Melo, Dulce Maria de Ara?jo |
Publisher | Universidade Federal do Rio Grande do Norte, Programa de P?s-Gradua??o em Ci?ncia e Engenharia de Materiais, UFRN, BR, Processamento de Materiais a partir do P?; Pol?meros e Comp?sitos; Processamento de Materiais a part |
Source Sets | IBICT Brazilian ETDs |
Language | Portuguese |
Detected Language | English |
Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
Format | application/pdf |
Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
Rights | info:eu-repo/semantics/openAccess |
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