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Previous issue date: 2017-07-10 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior (CAPES) / Com a descoberta dos nanotubos de carbono de parede simples (NTCPS) por Sumio Iijima, em 1991, os pesquisadores interessaram-se em sintetizar NTC em larga escala, com qualidade e baixo custo. Este trabalho prop?e uma nova metodologia e ecologicamente correta para a s?ntese de NTC por pir?lise da lignina extra?da do mesocarpo do dend? (Elaeis guineensis). Para a obten??o da amostra, a lignina foi pirolisada em um forno tubular a 1.000?C com uma determinada taxa de aquecimento 10?C/min e os experimentos foram realizados em diferentes intervalos de temperatura e sob fluxo de g?s arg?nio. Ap?s o processo de s?ntese, foi verificada a forma??o de nanomateriais de carbono. Os NTC?s foram submetidos a funcionaliza??o em solu??o (3:1) de ?cido sulf?rico (H2SO4) e ?cido n?trico (HNO3), sob agita??o, adicionado hidr?xido de am?nia (NH4OH) e lavado em seguida, neutralizado. Os nanotubos tamb?m foram funcionalizados com quitosana. O material final foi caracterizado a ?rea superficial, estrutural e propriedades f?sico-qu?micas, por meio de Difra??o de Raios X (DRX), An?lise T?rmica (TGA/DTA), Espectroscopia Raman, Microscopia Eletr?nica de Transmiss?o (MET), Espectroscopia na regi?o do Infravermelho com Transformada de Fourier com reflect?ncia difusa atenuada (FTIR/ATR) e Eletroan?lise do atrav?s de Voltametria C?clica e Imped?ncia. Os resultados demonstraram que o processo de pirolise sob fluxo de arg?nio obteve nanotubos com di?metros m?dios de 7 nm com potencial aplica??o. / With the discovery of Carbon single-wall nanotubes (SWNT?s) by Sumio Iijima in 1991, the researchers were interested in synthesizing CNT?s on a large scale, with quality and low cost. This work proposes a new methodology and ecologically correct for the synthesis of CNT?s by lignin pyrolysis extracted from the mesocarp of palm oil (Elaeis guineensis). To obtain the sample, the lignin was pyrolyzed in a tubular furnace 1.000?C with a given heating rate 10?C/min and the experiments were performed at different temperature ranges and under argon gas flow. After the synthesis process, the formation of carbon nanomaterials were verified. The CNT?s were subjected to functionalization in solution (3:1) of sulfuric acid (H2SO4) and nitric acid (HNO3) under stirring, added ammonia hydroxide (NH4OH) and washed, then neutralized. The nanotubes were also functionalized with chitosan. The final material was characterized by the surface area, structural and physical-chemical properties, using X-ray Diffraction (XRD), Thermal Analysis (TGA/DTA), Raman Spectroscopy, Transmission Electron Microscopy (TEM), Fourier Transform Infrared (FTIR) Attenuated Total Reflection (ATR) spectroscopy and Electroanalysis through Cyclic Voltammetry and Impedance. The results showed that the pyrolysis process under argon flux obtained nanotubes with mean diameters of 7 nm with potential application. / 2018-10-10
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/24837 |
| Date | 10 July 2017 |
| Creators | Te?filo, Alessandra Luzirene Costa |
| Contributors | 18222161415, Nascimento, Jos? Heriberto Oliveira do, 02452573493, Santos, Elaine Cristina Martins de Moura, 97143936472, Souza Filho, Men de S? Moreira de, 16931700359, Andrade, S?nia Maria Bel?sio de, 93807830430, Ladchumananandasivam, Rasiah |
| Publisher | PROGRAMA DE P?S-GRADUA??O EM ENGENHARIA MEC?NICA, UFRN, Brasil |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/embargoedAccess |
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