Yes / Dehydroabietic acid (DAA) promotes palladium(0)‐catalysed cyclisations of arene‐tethered 1,7‐enynols and 1,m‐enynoates (m=6,7) to give fused carbocyclic dienes. 6,6,6,5‐Tetracyclic lactones are accessible by one‐pot cycloisomerisation/Diels–Alder reaction/lactonisation from 1,7‐enynols. Furthermore, asymmetric counteranion‐directed catalysis has been developed, which afforded an indene derivative with an all‐carbon quaternary stereogenic center. / NSFC. Grant Number: 21462004 State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources. Grant Number: CMEMR2014A04 2015 GXNSFBA. Grant Number: 139032 GXNU
| Identifer | oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/17845 |
| Date | 26 May 2020 |
| Creators | Wu, Na (Anna), Li, R., Cui, F., Pan, Y. |
| Source Sets | Bradford Scholars |
| Language | English |
| Detected Language | English |
| Type | Article, Accepted Manuscript |
| Rights | © 2017 Wiley This is the peer reviewed version of the following article: Wu N, Li R, Cui F et al (2017) Application of dehydroabietic acid in palladium-catalysed enyne cycloisomerisation. Advanced Synthesis & Catalysis. 359(14): 2442-2447, which has been published in final form at https://doi.org/10.1002/adsc.201700061. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. |
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