Yes / Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1. / University of Bath; Royal Society of Chemistry; Engineering and Physical Sciences Research Council
Identifer | oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/8493 |
Date | 17 May 2016 |
Creators | Naeem, Ayesha, Ting, V.P., Hintermair, U., Tian, M., Telford, Richard, Halim, Saaiba, Nowell, H., Holynska, M., Teat, S.J., Scowen, Ian J., Nayak, Sanjit |
Source Sets | Bradford Scholars |
Language | English |
Detected Language | English |
Type | Article, Published version |
Rights | © 2016 The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
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